维多利亚艳蓝分光光度法测定镓

以聚乙二醇辛基苯基醚为稳定剂,在pH 2.4的磷酸-磷酸二氢钠缓冲溶液中,维多利亚艳蓝Bo与Gal4-反应生成缔合物,缔合物的最大吸收波长560 nm,表观摩尔吸光率5.53×105L·mol-1·cm-1.镓(Ⅲ)的质量浓度在1.3×10-3～7.0×10-2mg·L-1范围内遵守比耳定律.应用此方法测定了煤矸石和煤灰中痕量镓,所得结果与国家标准方法测得的结果相符.其相对标准偏差(n=8)均小于3%.测得方法的回收率97%～101%.     

717型阴离子交换树脂吸附水溶性芳香族有机污染物研究

研究了717型阴离子交换树脂对苯酚、苯甲酸和十二烷基苯磺酸钠(SDBS)等水溶性芳香族污染物吸附过程的基本化学问题.研究结果表明:717型树脂对苯酚、苯甲酸和SDBS的吸附过程均符合Lagergren二级吸附动力学方程,吸附速率均随着温度的升高而加快,吸附表观活化能Ea分别为13.2kJ/mol、59.5kJ/mol和48.1kJ/mol,吸附过程△H0和△S0均为正值,△G0均为负值,吸附能够自发进行;吸附等温模型符合Langmuir等温式;318K时,717型树脂在pH=9.1对SDBS的饱和吸附容量为360mg/g;在pH=10.2,对苯酚和苯甲酸的饱和吸附容量分别为194mg/g和286mg/g.用浓度均为0.5mol/L,体积比为5∶1的NaCl-NaOH混合溶液可快速洗脱树脂上吸附的污染物,洗脱率达98％以上.该树脂对水溶性芳香族污染物吸附容量大,易于再生和循环利用,可用于环境水体中水溶性芳香族有机污染物的吸附治理.     

基于纳米粒子的比色检测及其在化学传感及生物检测的应用

基于纳米粒子的比色检测由于其简单性、多样性而备受关注。在该体系中,目标分析物直接或间接诱发纳米粒子的聚集和分散,从而可通过溶胶的颜色改变实现分析检测。该综述介绍了纳米粒子分散及聚集过程的物理现象,简单讨论了纳米粒子间的作用力,对两种作用机制(粒子间交联和非粒子间交联来调节纳米粒子的分散和聚集)进行了介绍。并对纳米粒子在重金属离子检测、生物检测等方面的应用及方法的分析特性进行了概述,对其未来发展趋势进行了展望。     

In2O3 透明薄膜晶体管的制备及其电学性能的研究

采用磁控溅射方法在玻璃衬底上生长了In₂O₃晶体薄膜.该薄膜具有(111)晶面择优取向,晶粒尺寸达到33 nm.利用光刻工艺制作了以In₂O₃晶体薄膜为沟道层的底栅式薄膜晶体管.In₂O₃薄膜晶体管具有良好的栅压调制特性,场效应迁移率达到6.3 cm²/(V·s),开关电流比为3×10³,阈值电压为-0.9 V.结果表明,In相似文献   

应急管理关键因素的混合型识别方法研究

如何细致识别出自然灾害下应急管理的关键因素,对于开展科学有效的应急管理具有重要的现实意义。本文提出一种新的应急管理关键因素的混合型识别方法,该方法通过构建三角模糊数为基本语言集、三角区间模糊数为补充语言集的评价尺度集,建立混合型初始直接关联矩阵并将之转化为区间数直接关联矩阵,进而实现中心度和原因度的综合排序,从而据此有效的识别出应急管理的关键因素,为制订高效科学的应急管理政策提供良好的方法论支持。同时,通过一个算例表明了本方法具有良好的识别效果。本混合型识别方法突破了已有研究单一性模糊评价尺度集的局限性,具有方法论创新价值,并在关键因素识别领域具有较好的应用普适性。     

高光谱图像的分布式近无损压缩

星载高光谱图像的有效压缩已经成为高光谱遥感领域亟待解决的难题。分布式信源编码具有较低的编码复杂度与良好的抗误码性,在高光谱图像压缩领域具有广阔的应用前景。提出了一种基于多元陪集码的高光谱图像分布式近无损压缩算法。根据多元陪集码的Slepian-Wolf无损编码的压缩过程,提出了面向高光谱图像分布式近无损压缩的最优量化方案,使得高光谱图像在给定目标码率条件下的失真达到最小,在此基础上对量化值进行Slepian-Wolf无损编码,从而实现了高光谱图像的分布式近无损压缩。实验结果表明,与典型的传统算法相比,该算法取得了较好的近无损压缩性能和较低的编码复杂度。     

利用ICP法测定ZnMgO薄膜的Mg组分

利用电感耦合等离子体(ICP)装置对分子束外延(MBE)法在Sapphire衬底上生长的Zn_1-xMg_xO薄膜的Mg组分进行了测试. 经理论分析，得到使用1次和2次检量式所确定的Zn_1-xMg_xO薄膜中的Mg组分的差异. 将采用1次检量式的ICP测定与EPMA测定结果进行对照，表明当Mg组分x≤0.5时二者的测试结果相当一致，由此证明ICP测试结果的正确性. 关键词： ZnMgO薄膜 Mg组分 分子束外延(MBE) 电感耦合等离子体(ICP)     

Propagation of Partially Coherent Twisted Anisotropic Gaussian—Schell Model Beams in the Spatial—Frequency Domain

The generalized Collins formula for partially coherent beams through axially non-symmetrical optical systems in the spatial-frequency domain is derived by means of the tensor method.Based on this formula,the tensor ABCD law in the spatial-frequency domain for partially coherent twisted anisotropic Gaussian-Schell model (GSM) beams is derived,which governs the transformation of the twisted anisotropic GSM beams in the spatialfrequency domain.An example of an application is provided.     

Impact of microsecond-pulsed plasma-activated water on papaya seed germination and seedling growth

The seed of Carica papaya consists of a hard shell-like testa with inhibitors in vivo causing slow, erratic and asynchronous germination. In this work, plasma-activated water prepared by microsecond-pulsed plasma jets (μPAW) was applied to treat papaya seeds. The μPAW after plasma activation of 30 min was about 40 ℃. The reactive species such as NO₂, NO₃, and H₂O₂ in the μPAW activated from deionized water were measured and correlated to the seed germination rate and the seedling growth performance. The μPAW-treated papaya seed achieved a higher germination rate of 90%, which is 26% higher than the control group using deionized water. Comparing the results with a hot water (40 ℃) reference group showed that the reactive species in μPAW played primary roles in germination improvement, with little effect caused by the heat shock. The μPAW also sterilized the treated seeds, reducing the germination stress. The morphological change in the seeds was observed by SEM, showing an effect of physical etching after treatment promoting seed imbibition. The biochemical mechanism of the seed germination was deduced with reference to the evolution of surface chemistry, functional groups, and ABA content. The accelerated seed metabolism observed was corresponded to the chemical modification pathway. Besides, early seedlings developed from treated seeds were observed to be healthy, grow more leaves, and have better root structures. The content of MDA in the treated papaya seedlings decreased along with increased SOD and higher ion concentration. The μPAW that can be prepared at atmospheric pressure for bulk production offers a low-risk and cost-effective seed priming technology that may significantly increase the production of agricultural crops.     

异质信息、异质先验信念与均衡资产价格

在卖空限制下,将信息异质和先验信念异质纳入统一的分析框架,利用贝叶斯法则推导出两类异质性共同影响下的均衡资产价格模型,进一步分析表明,两类异质性均对资产价格产生影响,但对价格波动的影响不同,异质信息投资者的增多或者先验信念异质性程度的增强会加快资产价格的涨或跌,甚至会导致暴涨或暴跌,这与Miller等仅对单异质性影响进行研究不同,研究揭示了市场中多类异质性的具体影响机制.