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摘要 对甲基卞基五羰基锰(CO)5Mn-p-CH2C6H4CH3(4a)或对甲氧基五羰基锰(CO)5Mn-p-CH2C6H4OCH3(4b)与1-2当量R3SiH的C6H6 或C6D6溶液在5oC光解,经色谱纯化后得到中等或高收率硅烷基五羰基锰(CO)5MnSiR3[SiR3 = SiMe2Ph(1b),SiMePh2(1c),SiPh3(1d),SiHPh2(1e),SiEt3(1f),SiMe2tBu(1g),和SiMe2Et(1h)]。光化学反应后,对二甲苯和对甲基苯甲醚副产物分别定量生成,并伴随少量Mn2(CO)10(<1%-6%)。色谱柱的尺寸和温度(室温至- 65 oC)的选择视初始浓度的分解,色谱柱展开期间1的稳定性(过载),以及1与Mn2(CO)10的分离难易而定。去除Mn2(CO)10后的硅烷基五羰基锰3b-3g为浅黄色油状物或无色晶体(只有3h无法分离得到纯净物)。尽管这些化合物对空气敏感对热却相对稳定。 相似文献
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各向异性介质中带衬砌的圆形结构与SH波相互作用 总被引:1,自引:0,他引:1
本文利用复变函数方法求解各向异性介质中带衬砌的圆形结构与SH波的相互作用问题。各向异性介质可以用来模拟地质条件。利用文献[5]中的方法则可决定介质中的散射波,再利用圆形结构上给出的边界条件,则可对问题进行求解,作为算例,本文给出了在一种各向异性介质中,二种不同材料组成的圆形带衬砌的结构与SH波相互作用问题的数值分析结果,并予以讨论。 相似文献
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中国人促红细胞生成素基因组的克隆及其在COS-7细胞中的表达 总被引:3,自引:0,他引:3
本文利用PCR技术,从正常人胎肝染色体DNA库中分离克隆了长度分别为506bp,465bp的中国人促红细胞生成素(EPO)基因组片段。506bp基因片段包括外显子2(信号肽),内含子2和外显子3;465bp片段包括外显子4,内含子4和外显子5。通过在引物中设置的酶切位点将两个克隆片段进行了正确的拼接,从而得到了约1.0kb的EPO次全基因组片段,它包括除信号肽中第2,3,4位氨基酸外的所有编码区及两个内含子序列。 所克隆的次全EPO基因组插入表达载体pSV2-dhfr中的不同克隆位点,构建了3种不同的转移载体质粒,分别转染导入COS-7细胞后,3种转移载体质粒转染的细胞上清液都有明显的EPO活性。本工作证明仅含有内含子2,4序列,去除负调控区和氧敏感区序列的人次全EPO基因组可以在COS-7细胞中获得表达。 相似文献
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Burgers equation is reduced into a first-order ordinary differential equation by using travelling wave transformation and it has typical bifurcation characteristics.We can obtain many exact solutions of the Burgers equation,discuss its transcritical bifurcation and control dynamical behaviours by extending the stable region.The transcritical bifurcation exists in the (2 + 1)-dimensional Burgers equation. 相似文献
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The conventional approach to analysis the buckling of rectangular laminates containing an embedded delamination subjected to the in-plane loading is to simplify the laminate as a beam-plate from which the predicted buckling load decreases as the length of the laminate increases. Two-dimensional analyses are employed in this paper by extending the one-dimensional model to take into consideration of the influence of the delamination width on the buckling performance of the laminates. The laminate is simply supported containing a through width delamination. A new parameter β defined as the ratio of delamination length to delamination width is introduced with an emphasis on the influence of the delamination size. It is found that (i) when the ratio β is greater than one snap-through buckling prevails, the buckling load is determined by the delamination size and depth only; (ii) as the ratio β continues to increase, the buckling load will approach to a constant value. Solutions are verified with the well established results and are found in good agreement with the latter. 相似文献
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