基于Web 2.0的边与节点同时增长网络模型

模拟了Web2.0网络的发展过程并研究其拓扑结构,分析某门户网站实际博客数据的度分布、节点度时间变化,发现与先前的无标度网络模型有所差别.根据真实网络的生长特点,提出了边与节点同时增长的网络模型,包括随机连接及近邻互联的网络构造规则.仿真研究表明,模拟的网络更接近实际,在没有优先连接过程时,模型能得到幂率的度分布;并且网络有更大的聚类系数以及正的度相关性。     

基于多分辨率色彩传递的彩色夜视方法研究

为了获得符合人眼感知的彩色夜视图像,帮助观察者获取丰富的场景信息和舒适的观察效果,提出了一种基于多分辨率色彩传递的彩色夜视处理方法.结合微光与红外图像特点,对二者进行YUV空间拮抗视觉特性的彩色融合之后,采用控向金字塔对彩色融合图像(源图像)和参考图像各颜色通道进行多分辨率分解,计算子带图像的均值和标准方差,通过参考图像与源图像在各子带的方差比调整源图像的子带系数值,再经金字塔重构,最终使微光与红外彩色夜视图像获得类似参考图像的自然感色彩.分析了lαβ、YUV和RGB颜色空间对色彩传递的影响,并确定YUV颜色空间更适于多分辨率分解的色彩传递.相比传统的线性色彩传递方法,本方法不仅使彩色夜视图像拥有更符合真实场景的色彩,还可以提高其细节信息,改善场景感知,提升融合图像目标探测能力.     

The direct ionization processes in the collisions of partially stripped carbon and oxygen ions with helium atoms at low-to-intermediate energies

The values of direct double- to-single ionization ratio R of helium atoms induced by C^q＋, O^q＋ （q = 1 -4） ions at incident energies from 0.2 to 8.5MeV are measured. Based on the existing model （Shao J X, Chen X M and Ding B W 2007 Phys. Rev. A 75 012701） the effective charge of the projectile is introduced to theoretically estimate the value of R for the partially stripped ions impacting on helium atoms. The results calculated from our ＂effective charge＂ model are in good agreement with the experimental data, and the dependence of the effective charge on the ionization energy of the projectile is also discussed qualitatively.     

可见近红外波段光谱辐射采集系统的设计与应用

针对目前卫星遥感器进行场地定标的光谱观测仪器的应用需求，设计了可见近红外波段(0.4 μm~1.0 μm)的光谱辐射采集电路系统，并结合光谱辐射采集模块进行了应用与数据分析。重点介绍了线阵探测器的选型与驱动需求，并完成了基于STM32微处理器的设计。结合辐射观测需求，在信号处理部分使用仪表放大器运放对探测器的模拟输出信号进行处理，并采用STM32内部的A/D转换器采集。分析数字信号输出的结果，该辐射测量电路系统的的采集数据达到了1 LSB的数据精度(≤0.8 mV)。探测器电路系统应用到光谱辐射采集模块中，进行了户外应用与数据分析，光谱辐照度比对结果的偏差小于5%。光谱辐照度的比对结果证明整个系统可以直接进行产品应用，满足野外辐射测量数据的可靠性获取。     

Enhancement of water self-diffusion at super-hydrophilic surface with ordered water

It has been well acknowledged that molecular water structures at the interface play an important role in the surface properties, such as wetting behavior or surface frictions. Using molecular dynamics simulation, we show that the water self-diffusion on the top of the first ordered water layer can be enhanced near a super-hydrophilic solid surface. This is attributed to the fewer number of hydrogen bonds between the first ordered water layer and water molecules above this layer, where the ordered water structures induce much slower relaxation behavior of water dipole and longer lifetime of hydrogen bonds formed within the first layer.     

α型β级Bazilevi?函数的Milin系数估计和相邻系数问题

该文讨论了α型β级Bazilevi?函数上的Milin系数和相邻系数模之差的估计,得到准确结果,推广了一些已有结论;另外,作为特例给出Milin函数的几何特征.     

Detailed structural,mechanical,and electronic study of five structures for CaF2 under high pressure

Detailed density functional theory(DFT)calculations of the structural,mechanical,thermodynamic,and electronicproperties of crystalline CaF2 with five different structures in the pressure range of 0 GPa–150 GPa are performed byboth GGA(generalized gradient approximation)-PBE(Perdew–Burke–Ernzerhof)and LDA(local density approximation)-CAPZ(Cambridge Serial Total Energy Package).It is found that the enthalpy differences imply that the fluorite phase→PbCl2-type phase→Ni2In-type phase transition in CaF2 occurs at PGGA1=8.0 GPa,PGGA2=111.4 GPa by usingthe XC of GGA,and PLDA1=4.5 GPa,PLDA2=101.7 GPa by LDA,respectively,which is consistent with previousexperiments and theoretical conclusions.Moreover,the enthalpy differences between PbCl2-type and Ni2In-type phases inone molecular formula become very small at the pressure of about 100 GPa,indicating the possibility of coexistence of twophase at high pressures.This may be the reason why the transition pressure of the second phase transition in other reportsis so huge(68 GPa–278 GPa).The volume changed in the second phase transition are also consistent with the enthalpydifference result.Besides,the pressure dependence of mechanical and thermodynamic properties of CaF2 is studied.Itis found that the high-pressure phase of Ni2In-type structure has better stiffness in CaF2 crystal,and the hardness of thematerial has hardly changed in the second phase transition.Finally,the electronic structure of CaF2 is also analyzed withthe change of pressure.By analyzing the band gap and density of states,the large band gap indicates the CaF2 crystal isalways an insulator at 0 GPa–150 GPa.     

基于超高效液相色谱-高分辨质谱的非靶向代谢组学技术结合化学计量学对信阳茶树品种差异的研究

基于超高效液相色谱联用高分辨质谱(UHPLC-HRMS)的非靶向代谢组学技术结合化学计量学自动化数据分析策略,分析了信阳地区乌牛早、舒茶早、白毫早、平阳特早、陕茶一号共5个茶树品种的化学成分差异.采用自动化解析方法软件平台对仪器采集的原始信号直接解析,共鉴定出生物碱、儿茶素、酚酸、氨基酸、核苷及黄酮类物质等33种差异性...     

光催化选择性合成有机物

光催化反应比传统催化反应条件温和,不但能利用太阳能作为光源,同时,也避免了一些强氧化剂、危险还原剂和有毒物质的使用,极大地满足了人们对能源和环境的要求。通过优化光催化体系可以实现对目标产物的选择性合成,从而为有机合成提供一种绿色、节能的途径。本文综述了近年来光催化选择性合成有机物的催化剂类型,影响选择性因素和提高选择性的途径,重点就光催化材料的晶型、催化剂的合成与表面修饰、溶剂种类、催化条件等因素在聚合反应、芳香族的羟基化反应、胺的氧化反应、烯烃环氧化反应、羰基反应选择性合成有机物方面作一评述,并对光催化在选择性合成有机物的研究和进展进行了展望。     

一锅法合成2-羟基-9-芴酮类化合物

芴酮骨架的构建对于相关天然产物合成、药物分子结构修饰以及光电材料开发等具有重要意义。以苯环作为桥连基团,将呋喃环及炔酮片段构建在同一个分子内,设计并合成了邻呋喃芳基炔酮底物(1a)。利用化合物1a分子内呋喃环与炔键的D-A反应,在酸性条件下环氧开环,进而芳构化,一锅法合成了2-羟基-9-芴酮衍生物2a～2e,收率89%～96%,其结构经¹H NMR,¹³C NMR和HR-MS(ESI)表征。其中,化合物2a结构由X-ray单晶衍射确定。2a(CCDC:2144829)属单斜晶系,空间群P2₁/c,晶胞参数a=3.9458(10)?,b=22.4460(7)?,c=14.7092(5)?,V=1294.1300(7)?³,Dc=1.3980 Mg/m³,Z=4,F(000)=568。