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近年来,水/有机两相催化已成为均相催化多相化研究的主流[1].其中,新型水溶性膦配体的合成和两相催化新体系的设计尤为引人关注[2].最近我们发现[3],聚醚型水溶性膦-铑催化剂在高温下可溶入有机相对反应进行催化,而在冷却后又重返水相和产物分离.本文通... 相似文献
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Introduction Thename“rareearth”appliestothelanthanides ,yttriumandscandium .The 15elementsoflanthanidefromlanthanumtolutetiumconstituteauniquefamilyofcloselyrelatedelements (thedifferencelyinginthenum berof 4feletrons)fromwhichregentsorcatalystswith“tunab… 相似文献
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IntroductionInrecentyears ,dihydropyrimidinethionederivativeshaveattractedconsiderableinterestduetotheirpromisingactivitiesasanticarcinogenicagents ,1cardiovasculara gents2 andcalciumchannelblockers .3Inaddition ,somederivativesofdihydropyrimidinethionewer… 相似文献
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Microstructure and properties of plastic deformed martensite induced by laser shock processing 总被引:1,自引:0,他引:1
Firstly, 45# steel was quenched by the NEL-2500A rapidly axial flow CO2 laser. The experimental parameters were the laser power of 750 W, the laser beam diameter of 4 mm, the scanning velocity of 7 mm/s. The thickness of coating layer was 0.1 mm and the width was 8 mm. Secondly, the martensite induced by laser quench was shocked by Nd:YAG laser. The parameters of laser shock processing were the wavelength of 1.06 μm, the pulse duration of 23 ns, and the output energy of 16-20 J. The laser was focused on a spot of φ7 mm. K9 optical glass was used as confinement. The sample was coated with black paint 86-1 (the thickness is about 0.025 mm). By testing and analysis of samples which were treated by laser quench and laser quench+shock with transmission electron microscope (TEM), it was discovered that the surface layer of martensite was deformed plastically by laser shock processing. In the secondary hardened zones, there were a lot of slender secondary twin crystal martensites, dislocation tangles, and cel 相似文献
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报道了一种新的双锂盐络合物的合成及其X衍射单晶结构,该络合物含有2个 Li原子、一个(i-Pr2C6H3)2-dad配体及2个DME分子[triclinic,P-1,α=1.3478(4) ,b=1.5158(3),c=1.0730(3)nm,α=100.668(3)°,β=113.416(3)°,γ=97.128(3) °,Ⅴ=1.790(1)nm^3,Dc=1.06g/cm^3,Z=2,R/Rω=0.058/0.057]。 相似文献
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Lanthanide compounds have been attracting much attention in organic synthesis.Chiral Ln-substituted BINOL have been widely studied in several asymmetric organic reactions.LnCl3 and Ln(OTf)3 have been expected to serve as Lewis acide and have been applied to many important synthetic reactions in a one-pot manner,Ln(O-i-Pr)3 exhibits some basic characters,which also can be utilized in some special organic transformation.This article deals with some lanthanides(Ⅲ)complexes promoted organic reactios,which we have recently developed. 相似文献