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Physical and chemical effects of phosphorus-containing compounds on laminar premixed flame 下载免费PDF全文
Phosphorus-containing compounds are the promising halon alternatives for flame inhibitions. However, some literatures suggested that the phosphorus-related inhibitors may behave as the unfavorable ones that will increase the burning velocity under lean-burn conditions, and this indeed posed potential threats to the fire prevention and fighting. To seek deeper insights into the reaction process, a numerical investigation was actualized to study the phosphorus-related effects on methane-air flames. By replacing a phosphorus-related inhibitor with the corresponding decomposed molecules, the detailed promoting and inhibiting effects of combustion were separated from the general chemical effect. A comparative study was carried out to identify the interaction between the two effects under different combustion conditions. It is observed that the promoting effect becomes the dominant factor during the reaction process when the equivalence ratio is smaller than 0.60. In this lean-burn condition, the exothermic reactions were faster than the others within the reaction chains due to the reduction of radical recombination in hydrocarbon oxidation. The results are believed to be useful for the further application and improvement of flame inhibitors. 相似文献
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掺Tm3+石英光纤中频率上转换产生可见光的实验研究 总被引:2,自引:2,他引:0
报道了实验研究连续锁模1053nmNd:YLF激光泵浦的掺Tm3+石英光纤中可见光区的频率上转换过程.测量了可见荧光光谱,并用Tm离子的分步三光子吸收过程解释了可见光频率上转换现象. 相似文献
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The total reaction cross sections (TRCSs) of^29S ^28Si have been measured at intermediate energies. An obvious enhancement in TRCS of ^29S is observed as compared with its neighbouring nuclei. The TRCSs of ^29S ^28Si arecal culated with the modified Glauber theory in the optical limit and few-body approaches. The different factor d as a possible measure of halo appearance is deduced from the experimental and theoretical data. It is well accepted that ^27p is a proton halo nucleus. Although not as anomalous as ^27p, the different factor d of ^29S is obviously larger than that of its neighbouring isotones of N = 13. This result indicates that a moderate proton halo may exist in ~9S nucleus. We calculate the total reaction cross sections for ~9S with the modified Glaubertheory as a function of incident energy and compare the results with those for 2rSi which is a core nucleus 0f29S.The measured TRCSs of 27Si4-2SSi can be described to be satisfactory by the modified Glauber theory of theoptical limit approach. Although a diffused nuclear density distribution is used, the theories still inadequatelypredict the experimental TRCSs of 29S4-2SSi, which further indicates the possibility of proton halo in 29S. 相似文献
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N ,O-苄基壳聚糖在浓溶液中形成胆甾液晶相 .用圆偏光二向色性谱 (CD)研究了这一聚合物的螺旋行为 ,主要包括螺距和螺旋方向 .浓度越高 ,螺距P越大 ,意味着胆甾相的扭转力随浓度增加而减弱 .CD谱图上观测到两类吸收 ,即在 5 70nm附近较宽但较强的吸收和 330nm附近较尖但较弱的吸收 .前者归属于胆甾相层片的超分子螺旋构象 ,而后者可以归属于分子链的螺旋构象 .改变浓度或溶剂性质时这两个层次的构象都会发生符号的变化 .提高浓度 (固定二氧六环为溶剂 )时两种螺旋结构先后发生反转 .以氯仿为溶剂 (固定浓度为 6 5 % )时两种螺旋结构均为左旋 (正Cotton效应 ) ,但二氧六环和四氢呋喃为溶剂时均变为右旋 (负Cotton效应 ) .溶剂的影响可能与溶剂和高分子间形成氢键的能力有关 相似文献
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应用胺类化合物与4,4'-二氟苯偶酰的亲核取代反应合成了多种对称或不对称 的4,4'-双(二烷氨基)苯偶酰。结构经元素分析,IR,~1H NMR和MS确定,其中 伯胺与4,4'-二氟苯偶酰的反应得到了一边取代、另外一边形成亚胺结构的产物, 并对此反应机理进行了探讨。 相似文献