THE CRYSTAL AND MOLECULAR STRUCTURE OF CHLORO(BIS-2,2''''-DIPYRIDYL) COPPER7,7'''',8,8''''-TETRACYANOQUINODIMETHANE [Cu(bipy)_2Cl]·TCNQ_2

The crystals of title compound are prepared by the electrochemical method and its structure has been determined by X-ray diffractions method. The crystals are triclinic with space group P(?). a=7.920, b=13.140, c=19.126; a=100.77°, β=94.45° and γ=101.08° ; Z=2, Calculating of electronic structure of TCNQ and its packing mode are discussed.     

二次曲线束及其应用

二次曲线束是指具有某种共同性质的二次曲线的集合。二次曲线束方程的形式通常表现为含有一个或几个独立参数的二元二次方程。最为熟悉的例子如以a,b为参数的二次曲线束方程 x~2/a~2+y~2/b~2=1,(a>b>0)就是长短轴在坐标轴上,焦点位于x轴的一族椭圆。又如以λ为参数的方程 x~2/36-y~2/64=λ(λ≠0)     

碳管的结构和生长热力学研究 *

在nm尺度镍粉和镍片(或钛片)的催化作用下,乙炔气体高温热解形成碳管.nm尺度Ni粉的催化效果与其在H₂气中的还原温度有关,在高温(1500℃)下还原后,其催化效果十分显著,碳管的产量较高;而在低温下还原后作催化剂,碳管的产量较低,甚至形不成碳管.在约770℃还原的Ni(Ti)片作催化剂时,碳管易在Ni(Ti)片的边沿和尖端处生长;如果用酸处理过的Ni(Ti)片作催化剂,则会在催化剂的表面形成一层碳管.分析了破管的结构,研究了直形、弯曲形和螺旋形碳管的生长热力学.     

培植牛黄与天然牛黄中游离和结合胆汁酸含量的测定和比较

用薄层光密度法测定了十个生产单位的18批培植牛黄的游离和结合胆汁酸的含量,并与天然牛黄及牛胆粉比较,结果表明,培植牛黄含有与天然牛黄相同的胆汁酸成分,其中培植牛黄的游离胆汁酸比天然牛黄略高,结合胆汁酸含量多数样品与天然牛黄相当,总胆汁酸含量多数样品比天然牛黄略高。     

用电弧放电法大面积地制备离散的碳纳米管

用电弧放电法直接得到了无烧结、离散分布、大面积及高密度的碳纳米管 ,提高了碳纳米管的质量和产量 .SEM研究表明样品中离散的碳纳米管相互缠绕 ,同时在空间取向无序 .讨论了放电过程中碳纳米管的生长机理和实验中得到的形貌的形成机制.     

利用介孔材料制备碳纳米管的形貌、结构和Raman散射研究

以碳氢气体为反应物,利用化学气相沉积方法,在不同的衬底上制备了碳纳米管。研究了不同衬底对碳纳米管生长方式的影响。对碳纳米管的形貌和结构进行了观察研究,在介孔二氧化硅衬底上制备了取向生长的碳纳米管。碳纳米管具有很高的密度和纯度。研究了取向碳纳米管的Raman谱,分析了碳纳米管的Raman共振特性与其微观结构的关系。     

GEOELECTRIC RESISTIVITY ANOMALIES BEFORE EARTHQUAKES

Since geoelectric resistivity (ρ_x) measurements were started in 1967, the following phenomena have been observed before earthquakes: ⅰ) During 2-3 years before the great Tangshan earthquake, the anomaly of ρ_x propagated outwards from the epicenter with an apparent velocity of 100 km/year, and the radius of propagation reached about 150 km. (ⅱ) Before most of the earthquakes, the resistivity drops, but before a few earthquakes it may rise; all these are controlled by the stress conditions under the geoelectric station and the source mechanism of the earthquake. The relative variation of ρ_x is a magnified (up to about 1000 times) manifestation of rock strain. (ⅲ) Before an earthquake, geoelectric resistivity may exhibit both long-term and close-upon anomalies. The long-term anomaly reflects the accelerated accumulation of stress in the seismo-genotic region; its amplitude, duration and extent are logarithmically related to the earthquake magnitude. The close-upon anomaly may be a manifestation of