测定液体折射率的分光计方法

测定液体折射率的分光计方法钟菊花，顾懿（华东理工大学物理实验教研室上海２００２３７）折射率和沸点、密度一样是有机化合物的重要物理常数．它不仅是液体化合物纯度的标志，同时也是定性鉴定化合物的手段．根据折射率和混合物摩尔组成间的线性关系，还可用来测定含有...     

高效液相色谱-串联质谱法测定动物血浆中罗匹尼罗的浓度

建立高效液相色谱-串联质谱(LC-MS/MS)测定动物血浆中罗匹尼罗浓度的方法。血浆经乙酸乙酯萃取后,以HPLC分离,电喷雾离子化(ESI~+)串联质谱检测。以甲醇-乙腈-0.1‰冰醋酸(36:9:55)为流动相,流速为0.2mL·min~(-1),采用Ultimate XB-C 18柱(150mm×2.1mm,3μm)分离,在三级四极杆串联质谱中经电喷雾电离源(ESI)离子化,以多反应监测(MRM)方式进行检测。盐酸罗匹尼罗、盐酸苯海拉明(内标)的扫描离子对m/Z分别为261→114和m/Z 256→167。LC-MS/MS测定血浆中罗匹尼罗线性范围为0.02—400ng·mL~(-1),范围内线性关系良好(r=0.9998);以3个浓度水平的质量控制样品求得各浓度水平日内、日间精密度(RSD)均小于15.2%。在非临床药代动力学研究中,应用此法测定了受试兔子血浆中罗匹尼罗的浓度。该法灵敏、快速、准确,操作简便,样品处理方便,线性范围宽,该方法检测快速、专一、灵敏,可满足罗匹尼罗临床前药代动力学研究和临床药动学研究的要求。     

利用非线性传输线产生高功率射频场

根据孤立子理论,分析了利用变容非线性传输线产生射频场的机理。利用电路仿真方法系统地研究了影响射频场产生的相关参数,发现电感和零压电容越小、输入电压越大,射频场的频率越高;电容的非线性率越大,射频场的峰值电压越高、高频成分越多。并在此基础上,仿真设计了能产生峰值功率为0.8 GW、主频为19.42 MHz射频场的非线性传输线。     

双脉冲高功率脉冲调制器的设计

采用螺旋线和折叠线技术相结合的方法,设计了一种基于水介质高功率脉冲调制器。该调制器采用了两个开关,通过控制两个开关的导通时刻,可以在两个负载上得到脉冲长度相等的两个脉冲。对该种折叠型传输线的波过程进行了详细分析,给出了过渡段部分阻抗等参数对负载电压的影响;用Pspice电路软件对脉冲形成线的充电电压和二极管电压、电流进行了模拟;最后利用高压同轴电缆,对该种类型调制器进行了低压情况下的验证实验,实验结果与理论分析、模拟研究一致。此种类型的调制器具有结构紧凑、可同时输出两个脉冲的优点。     

利用原子层外延方法制备的ZnS:Er3+薄膜的交流电致发光特性

采用原子层外延方法(ALE)制备了ZnS:Er3+交流电致发光(ACEL)薄膜,得到了明亮的绿色EL。发现了随Er3+离子浓度增加,对应于4F9/2→4I15/2跃迁的谱线强度增加甚至超过2H11/2→4I15/2跃迁的谱线强度。通过对EL衰减的分析,发现了绿红比随外加电压的变化关系以及EL光谱与温度的关系。在Er3+离子浓度较高时,Er3+离子之间发生明显的能量传递。提出了Er3+离子间的交叉驰豫模型并计算了交叉弛豫速率,同拟合衰减曲线得到的值相比,两者符合得较好。     

The effect of electronic orbital interactions on p-type doping tendency in ZnO series： First-principles calculations

The electronic structures and optical properties of B3 ZnO series of Znelectronic structures, optical properties, pseudopotential plane-wave method, \\ \hspace*{1.9cm} p-type doping tendency,electronic structures, optical properties, pseudopotential plane-wave method, \\ \hspace*{1.9cm} p-type doping tendencyProject supported by the National Natural Science Foundation of China (Grant No~10625416).2007-04-252007-06-18The electronic structures and optical properties of B3 ZnO series of Zn4X4-yMy（X ：O, S, Se or Te; M = N, Sb, C1 or I; y = 0 or 1） are studied by first-principles calculations using a pseudopotential plane-wave method. The results show that Zn d-X p orbital interactions play an important role in the p-type doping tendency in zinc-based Ⅱ-Ⅵ semiconductors. In ZnX, with increasing atomic number of X, Zn d-X p orbital interactions decrease and Zn s-X p orbital interactions increase. Additionally, substituting group-V elements for X will reduce the Zn d-X p orbital interactions while substituting group-VII elements for X will increase the Zn d-X p orbital interactions. The results also show that group-V-doped ZnX and group-Ⅷ-doped ZnX exhibit different optical behaviours due to their different orbital interaction effects.     

巧用教材结论 突破运算障碍——解决2023年新高考Ⅰ卷两道数列题的妙手

<正>2023年新高考Ⅰ卷着重考察了数列的基本知识及应用,其中第7题和第20题如果直接应用等差数列的定义来解答,在运算上会遭遇不小的障碍．若能灵活运用教材中关于等差数列的其它判定方法,则能轻松跨越障碍,收获巧解,彰显解题“妙手”．     

新型电感储能脉冲功率驱动源

提出了将传统单个储能电感利用传输线分隔成两部分的新型电感储能脉冲功率驱动源技术方案。理论分析表明,利用传输线电容的耦合延时作用,可有效对调制器输出脉冲波形进行整形,并且可以进一步提高能量转换效率,从而克服传统电感储能脉冲功率源输出波形质量差(类三角波波形)的缺点。基于该思想开展了实验研究,获得了电压约300 kV,电流约20 kA的电子束,并成功驱动S波段磁绝缘线振荡器获得了百MW量级的微波输出。     

Spin gapless armchair graphene nanoribbons under magnetic field and uniaxial strain

Using Green＇s function method, we investigate the spin transport properties of armchair graphene nanoribbons （AG- NRs） under magnetic field and uniaxial strain. Our results show that it is very difficult to transform narrow AGNRs directly from semiconductor to spin gapless semiconductors （SGS） by applying magnetic fields. However, as a uniaxial strain is exerted on the nanoribbons, the AGNRs can transform to SGS by a small magnetic field. The combination mode be- tween magnetic field and uniaxial strain displays a nonmonotonic arch-pattern relationship. In addition, we find that the combination mode is associated with the widths of nanoribbons, which exhibits group behaviors.     

A Ubiquitous Thermal Conductivity Formula for Liquids,Polymer Glass,and Amorphous Solids

The microscopic mechanism of thermal transport in liquids and amorphous solids has been an outstanding problem for a long time.There have been several approaches to explain the thermal conductivities in these systems, for example, Bridgman’s formula for simple liquids, the concept of the minimum thermal conductivity for amorphous solids, and the thermal resistance network model for amorphous polymers.Here, we present a ubiquitous formula to calculate the thermal conductivities of liquids and amo...