血流控制下时间门的人体血液参数无创检测研究

为了进一步提高人体血液成分无创伤测量的精度,从而达到临床的要求,提出了人体血液成分无创伤测量的一种新方法,这种方法是在血流受阻条件下,基于动力双波长时间分辨透射测量,将先进的时间门技术和拉普拉斯变换方法结合起来,对人体血液成分进行无创伤测量。该理论模拟了利用该方法在体测量人体血液参数,模拟结果显示当p>0, 强调早期到达的光子的贡献时,能提高人体血液参数的检测灵敏度。     

金属离子与腺嘌呤异构体复合物的稳定性

在B3LYP/6-311++G**//6-31+G*基组水平上结合PCM模型系统的优化了气相和液相环境中14种腺嘌呤异构体与四种金属离子(Na+,K+,Mg2+,Ca2+)形成的132个稳定复合物。通过能量对比,得到了所有复合物异构体在气液两相中的稳定性顺序及不同金属离子与同一异构体形成的复合物的能量排序,首次给出了液相中这些不同金属离子复合物的最稳定结构。结果发现溶剂效应导致了液相中的复合物稳定性顺序与气相中的相比发生了很大变化;同一异构体与不同金属离子形成的复合物其稳定性在排序中也变化很大。对于这些变化,本文分别从金属离子与腺嘌呤的复合物在气相中的结合能(EBE)及在液相中的溶质溶剂相互作用能(Epol)能等方面进行了系统的阐述     

残余应力分析方法比较:X射线衍射法与应力释放法

残余应力分析方法主要有衍射法、应力释放法和声、光、磁等方法。其中,X射线衍射法与应力释放中的钻孔技术与理论最为成熟,应用最广。在应力均匀且数值较小时,两者可以给出相互接近的结果。然而当样品微小且微观结构复杂时,两者给出的结果会有明显的差异。本文利用上述两种方法对同一纯铜样品表面的残余应力进行分析,对比分析结果并讨论了相关的影响因素。我们对X射线衍射法与环芯法的适用性进行了讨论:前者适用于晶体材料的无损检测,而后者更能反映当前应力水平。此外,对方法的选用需要考虑应力测试的目的。     

Effects of interface roughness on photoluminescence full width at half maximum in GaN/AlGaN quantum wells

Low temperature photoluminescence(PL) measurements have been performed for a set of GaN/AlxGa1-xN quantum wells(QWs). The experimental results show that the optical full width at half maximum(FWHM) increases relatively rapidly with increasing Al composition in the AlxGa1-xN barrier, and increases only slightly with increasing GaN well width. A model considering the interface roughness is used to interpret the experimental results. In the model, the FWHM’s broadening caused by the interface roughness is calculated based on the triangle potential well approximation. We find that the calculated results accord with the experimental results well.     

火焰原子吸收光谱法测定木瓜中7种微量元素的含量

采用火焰原子吸收法测定光皮木瓜中钙,铜,铁,硒,锌,锰,镁等微量元素的含量。优化了仪器工作条件,利用标准曲线法对待测样品进行定量分析。在设定的浓度范围内,7种元素的质量浓度与吸光度呈良好的线性关系,相关系数为0.992 9～0.999 4,7种元素的检出限为0.211～9.268 mg/L。对样品进行7次重复测定,测定结果的相对标准偏差均小于3.0%,加标浓度为1.000 0～10.010 0 mg/L时,加标回收率为96.51%～104.55%。该方法具有操作简单、干扰少等优点,为木瓜的开发提供了科学依据。     

钒-棓酸配合物吸附波

在含有0.1mol/L氟化铵、6.0×10~(-5)mol/L棓酸的Britton-Robinson缓冲液溶(pH6.1)中,钒在单扫示波极谱仪上产生一灵敏的配合物吸附波。峰电位在-0.66V(vs.SCE)左右。二次导数波高与钒浓度在0.001—0.30μg/ml范围内呈线性关系。方法已应用于煤飞灰中痕量钒的测定。     

云层背景目标识别的匹配滤波器设计

提出一种利用最大平均相关高度(MACH)算法识别复杂云层背景目标的改进滤波器设计方法。在MACH滤波器设计中,通过对云层背景功率谱的统计特性分析,数据拟合得到云层背景功率谱的分布函数,用以代替传统的白噪声模型;提取飞行目标的姿态变化图像,并作阈值化处理,得到训练样本。对不同云层背景和姿态变化目标的相关识别结果表明:改进滤波器的平均峰值相关能量比为0.71%,峰值鉴别率为0.92,可以有效抑制云层背景的干扰,对姿态变化目标识别的鲁棒性较好。     

Propagation modeling of ocean-scattered low-elevation GPS signals for maritime tropospheric duct inversion

The maritime tropospheric duct is a low-altitude anomalous refractivity structure over the ocean surface,and it can significantly affect the performance of many shore-based/shipboard radar and communication systems.We propose the idea that maritime tropospheric ducts can be retrieved from ocean forward-scattered low-elevation global positioning system(GPS) signals.Retrieval is accomplished by matching the measured power patterns of the signals to those predicted by the forward propagation model as a function of the modified refractivity profile.On the basis of a parabolic equation method and bistatic radar equation,we develop such a forward model for computing the trapped propagation characteristics of an ocean forward-scattered GPS signal within a tropospheric duct.A new GPS scattering initial field is defined for this model to start the propagation modeling.A preliminary test on the performance of this model is conducted using measured data obtained from a 2009-experiment in the South China Sea.Results demonstrate that this model can predict GPS propagation characteristics within maritime tropospheric ducts and serve as a forward model for duct inversion.     

Effect of high-temperature annealing on AlN thin film grown by metalorganic chemical vapor deposition

The effect of high-temperature annealing on AlN thin film grown by metalorganic chemical vapor deposition was investigated using atomic force microscopy, Raman spectroscopy, and deep ultra-violet photoluminescence(PL) with the excitation wavelength as short as ～ 177 nm. Annealing experiments were carried out in either N2 or vacuum atmosphere with the annealing temperature ranging from 1200℃ to 1600℃. It is found that surface roughness reduced and compressive strain increased with the annealing temperature increasing in both annealing atmospheres. As to optical properties,a band-edge emission peak at 6.036 eV and a very broad emission band peaking at about 4.7 eV were observed in the photoluminescence spectrum of the as-grown sample. After annealing, the intensity of the band-edge emission peak varied with the annealing temperature and atmosphere. It is also found that a much stronger emission band ranging from 2.5 eV to 4.2 eV is superimposed on the original spectra by annealing in either N2 or vacuum atmosphere. We attribute these deep-level emission peaks to the VAL–ONcomplex in the AlN material.     

基于四极杆-飞行时间质谱的非标记蛋白定量检测方法学研究

以四极杆飞行时间质谱检测的蛋白肽段的质谱信息为基础,开发了一种简单、准确的蛋白定性、定量检测方法,并用于牛血清白蛋白的定性、定量检测。对酶解肽段的梯度洗脱条件和流速等液相色谱条件进行了优化;进行蛋白样品的酶解及质谱检测,利用MassHunter定量软件对数据进行分析;为减少假阳性结果的出现,实验优化了数据处理软件中的设置参数,并对方法的重现性进行了考察。结果显示,重复检测的8个肽段峰面积的RSD均在3.0%以下。该方法对牛血清白蛋白的检出限为100 ng。实验发现,样品中蛋白的含量与检测到的肽段匹配率呈对数关系,并从检测到的丰度较高的8个肽段中确定可用于BSA蛋白定性检测的肽段为:HLVDEPQNLIK,定量检测的肽段为:ATEEQLK,方法的回收率为106%。该方法操作简便,检测快速,成本较低,专一性强,可用于蛋白特异性肽段的筛选及复杂生物样品中蛋白的检测。