Research on the thermo-characteristics of surface plasmon resonance spectrum

Based on the configuration of surface plasmon resonance (SPR) sensor, the SPR sensor model is set up, and the thermo-properties of various parts in the model are discussed. The thermocharacteristics of SPR spectra in wavelength interrogation and angular interrogation are investigated. Results show that thermo-optic and dispersion effects in the model deteriorate the sensitivity of SPR sensor, especially the thermooptic effects. Mathematical expression is established to describe the resonance wavelength or angle, which is dependent of temperature. It demonstrates that the thermo-property of sensing medium excites the fluctuation of resonance wavelength or angle more intensely than that of the substrate or metal film in 1-2 orders. Our theoretical research is consistent with the previous experimental results.     

β晶型聚丙烯的力学性质

研究了主要含β晶型的聚丙烯在不同温度下的应力-应变性质,并与同一商品牌号得到的α晶型聚丙烯作了对比。发现,β晶型试样的屈服强度低于α晶型,而抗冲击强度则比α晶型试样高1—2倍。结合X射线衍射法对β晶型试样在拉伸过程中发生的晶型转变的研究及形变的分子机制解释了二种晶型试样在力学性质上的差异。     

Two-phase displacement of non-newtonian fluid

This paper considers the problem of non-Newtonian oil displa-cement by water in porous media.adopting the linear permea-tion law with initial pressure gradient.For one-dimensionalflow,the basic equation of non-Newtonian oil displacement bywater in sandstone reservoirs and fractured reservoirs is de-rived and numerical solutions are obtained.The results arecompared with the corresponding ones for Newtonian oil dis-placement to show the essential characteristics of non-Newto-nian oil displacement by water.     

A geometric factor calculation method based on the isotropic flux assumption

One of the instruments onboard the China Seismic Electromagnetic Satellite （CSES） is the Low Energy Particle Detector （LEPD）. The primary objective of LEPD is to provide measurements of the fluxes, energy spectra and pitch angles of 100 keV to 10 MeV electrons and protons from 2 to 50 MeV in the Earth＇s magnetosphere. The geometric factor is one of the principle parameters of a detector, which converts the physical quantity-count rate to the particle quantity-flux. In this paper, we calculated the geometric factor of LEPD via computer modeling of an isotropic radiation environment. It was first demonstrated that the radiation intensity related should obey a cosine-law, then a general sampling method of generating this distribution via GPS of GEANT4 was explained. Furthermore, combined with flux normalization, a comparison of the geometric factor calculation of a set of 2-layer detectors with different shapes （cylinder, truncated cone and rectangle） was performed. Results show a generally good agreement between simulation and analytical calculations for the cylinder and truncated cone detectors, and the result of the rectangular one, for which there is no accurate analytical formula, is consistent with the previous simulated results by others. As a practical instance of the 2-layer rectangle detector, the geometric factor of LEPD is 10.336±0.036 m cm2·sr for 10 MeV proton and 8.211±0.032 m cm2·sr for 8 MeV electron.     

(-)-龙脑手性离子液体的合成

以(-)-龙脑为手性源,与溴乙酰溴通过酯化反应合成溴代乙酸龙脑酯(2);2与4,4'-联吡啶发生取代反应引入两个手性中心制得新型手性离子液体——N,N'-双(龙脑氧甲酰亚甲基)联吡啶.二溴(3.2Br-);3.2Br-与四氟硼酸钾或六氟磷酸钾盐进行阴离子交换制得相应的手性离子液体3.2BF4-或3.PF6-.3.2Br...     

高灵敏宽温区吸附热测定装置的建立

 描述了一个适于气／固体系的宽温区、高灵敏的微分吸附热测定装置．在该装置中，吸附放热由Setaram公司热流式微量热量计测定，吸附量由MKS公司电容式压力传感器测定．此外，设计、制作了可在高真空和宽温区内进行吸附热测定的试样池以及对高活泼金属催化剂进行预处理的试样处理池．用标准物质对热量计进行了标定．为验证该装置对吸附热测定的可靠性，测定了H2在Pt／SiO2和γ－Mo2N上的吸附热，所得结果与文献值一致．数据的误差分析结果表明，吸附热测定的相对误差在4％以内．     

黄芩甙的线性扫描伏安法测定研究

研究了黄芩甙在多壁碳纳米管修饰电极上的伏安行为。结果表明 ,该修饰电极对黄芩甙产生较强的吸附催化作用 ,催化电流与黄芩甙浓度在 1 .0× 1 0 - 7～ 6.0×1 0 - 5mol·L- 1范围内呈线性关系。利用本法测定了中药黄芩中的黄芩甙的含量 ,效果良好     

β晶相聚丙烯的研究——Ⅲ. 乙丙嵌段共聚物

乙丙嵌段共聚物中的丙烯链段在β晶型成核剂存在下,可在20—140℃结晶成高纯度的β晶型。研究了结晶温度对试样中β晶型的相对含量及试样熔融行为的影响。发现依赖于结晶温度、形成了二类β晶型。在20—100℃淬火形成的β晶型、熔融后会重结晶成稳定的β晶型,在高于100℃结晶则形成稳定的β晶型。研究了β晶型试样的力学性质,发现其屈服强度低于而抗冲强度高于α晶型试样。     

毛细管气相色谱法测定油田水中短链有机酸

The evaporation of water phase has been used to remove a vast amount of inorganic salts and interferingorganic components. The distillate concentrated by rotary evaporator was directly analyzed by means of wide-bore capillary GC column, The coefficients of variation for C_2～C_5 organic acids were 1.9～6.4%. The recov-eries of the acids in the oilfield water were 81.0～106%.     

LnCl_3-KCl-NaCl体系粘度的研究

目前关于熔盐体系粘度的研究报道甚少,这是由于熔体粘度的测量,技术上难度较大,尤其是当温度超过773K以后。稀土金属及其合金的生产,国内外多采用KCl-LnCl_3熔盐电解法。近年来,科学工作者系统地研究了LnCl_3-KCl-NaCl(Ln=La、Ce、Pr、Nd、Sm)熔盐体系。这一体系在生产中可以降低电解温度,减少材料腐蚀,降低电解质的挥发损失。因此研究该体系的物理化学性质,将有重要的意义。本工作是通过对熔体粘度的研究,为稀土熔盐化学和生产实践提供基础数据。