碳纳米管/聚对甲基吡啶修饰电极测定硝基苯甲酸

采用滴涂法和循环伏安法在玻碳电极上电沉积一层稳定的单壁碳纳米管/聚对甲基吡啶纳米薄膜(SWNTs/POMP)。研究了邻、对硝基苯甲酸在此修饰电极上的电化学行为,建立了电化学同时测定邻、对硝基苯甲酸的新方法。实验结果表明:在0.1 mol/L HClO4溶液中,邻、对硝基苯甲酸在SWNTs/POMP电极上发生不可逆的还原反应,由于碳纳米管和聚合物薄膜的协同效应,SWNTs/POMP电极对邻、对硝基苯甲酸有很好的的电催化作用,并对其响应进行了定量分析。     

两亲性树形-线团大单体的合成及其丙烯酸共聚乳液的流变行为

将3,4,5-三(十六烷基氧基)苯甲酰氯先后与分子量为1000的聚乙二醇、甲基丙烯酰氯反应合成了一种新的可聚合两亲性树形-线团大单体——3,4,5-三(十六烷氧基)苯甲酰氧基聚氧乙烯甲基丙烯酸酯(6).通过核磁、红外、元素分析等对产物进行了表征.然后将其与甲基丙烯酸、丙烯酸乙酯进行乳液共聚合,制备了一种疏水树形侧链改性...     

InAIAs／GaSbAs／InPDHBT与InP／GaSbAs／InPDHBT性能比较分析

双异质结双极晶体管（DHBT）的性能与发射区-基区（E．B）异质结和基区．集电区（B．C）异质结的能带突变类型关系密切,本文基于热场发射．扩散模型,对两类不同能带结构类型的新型DHBT的性能做了比较分析．结论表明：与作为当今研究热点的E．B和B．C异质结构均为全交错II型能带结构的InP／GaSbAs／InPDHBT的性能相比,E．B异质结采用传统I型、B．C异质结采用交错II型的一类新型能带结构的InAlAs／GaSbAs／InPDHBT虽然在开启电压上更高,但具有更好的电流驱动能力、直流增益和高频性能．     

Suppressing entanglement sudden death by initial system-environment correlation

This paper studies the entanglement dynamics of the system S composed of two non-interactional qubits A and B. The third qubit C is its environment, E, which only interacts with the S qubit B by the Dzyaloshinskii-Moriya spin-orbit coupling. Considering the following states as the whole (S+E): the initially S-E correlated state and the separable one, the entanglement of S has no sudden death for the former case. This result sheds some light on the control of quantum entanglement, which will be helpful for quantum information processing.     

聚苯胺纳米颗粒的制备及其电化学性能

以乙醇和水为混合溶剂,采用氧化法制备了纳米尺度的聚苯胺颗粒。采用扫描电镜、红外光谱、循环伏安、恒流充放电及交流阻抗等测试手段对其结构和电化学性能进行了测试。研究了混合溶剂的比例对产物电化学性能的影响。结果表明：聚苯胺颗粒大小为50～100 nm;以制备的聚苯胺纳米颗粒为活性物质,在1 mol/L的H2SO4电解液中,当...     

操作探究型问题例析

《数学课程标准》指出":有效的数学学习活动不能单纯地依赖模仿与记忆,动手实践、自主探索与合作交流是学生学习数学的重要方式".课标还非常重视培养学生的动手操作能力,提倡让学生在操作中感受和体验数学知识的形成和发展.在近几年来各地的中考数学题中常有"操作探究型问题"的出现,考查的形式有选择题和解答题,经常与图形变换相结合,形式多样,体现了数学源于生活,用于生活,同时也启发学生动手动脑、     

谈谈动态探究型问题

探究几何图形在运动变化过程中与图形相关的某些量的变化规律或其中蕴含的结论,这类题目叫动态探究型问题.它主要有以下几种类型:动点问题、动直线问题、图形变换问题等.对于动态几何探究型问题,要注意用运动和变化的眼光去观察和研究几何图形,把握图形运动与变化的全过程,抓住其中的等量关     

三体系统中的Efimov态(英文)

通过求解Faddeev方程, 研究了量子三体系统中的Efimov效应。 改进了变分方法对于求解激发态的不足。 在不同的两体作用下得到了三体系统中的Efimov态。 讨论了在不同质量比的三体系统中出现Efimov态的条件。 并由三体计算的结果分析了具有两个价中子的核系统在两体存在束缚态时可能存在的Efimov效应。We studied the Efimov effect in a three body system by solving the Faddeev equations. Different models and interactions were considered. The occurrence of Efimov states was discussed. The possible Efimov state was clearly presented and its properties were investigated.     

多亚层柔性节点模型及其在双材料4ENF试件界面分析中的应用

提出了多亚层柔性节点模型用于分析双材料裂纹尖端的应力和变形。该模型考虑了胶层的变形,各亚层视为独立的剪切变形梁,采用两个界面柔度系数考虑界面应力对各亚层界面变形的影响,界面变形包括双材料界面和胶层的变形。通过对FRP-混凝土末端切口四点弯试件(Four-point bending end-notched flexure specimen,简称4ENF)进行界面分析,并与其他模型和有限元分析对比表明:刚性节点模型忽略了裂纹尖端的应力和变形集中,只能粗略地估计构件的整体变形和界面应力;半刚性节点容许裂纹尖端的转动,对裂纹尖端的变形估计优于刚性节点模型,但精度依然不高;多亚层柔性节点模型反映了裂纹尖端的应力和变形集中,与数值分析结果吻合很好,该研究对进行双材料结构的工程设计具有理论指导和参考价值。     

Adaptive local routing strategy on a scale-free network

Due to the heterogeneity of the structure on a scale-free network, making the betweennesses of all nodes become homogeneous by reassigning the weights of nodes or edges is very difficult. In order to take advantage of the important effect of high degree nodes on the shortest path communication and preferentially deliver packets by them to increase the probability to destination, an adaptive local routing strategy on a scale-free network is proposed, in which the node adjusts the forwarding probability with the dynamical traffic load (packet queue length) and the degree distribution of neighbouring nodes. The critical queue length of a node is set to be proportional to its degree, and the node with high degree has a larger critical queue length to store and forward more packets. When the queue length of a high degree node is shorter than its critical queue length, it has a higher probability to forward packets. After higher degree nodes are saturated (whose queue lengths are longer than their critical queue lengths), more packets will be delivered by the lower degree nodes around them. The adaptive local routing strategy increases the probability of a packet finding its destination quickly, and improves the transmission capacity on the scale-free network by reducing routing hops. The simulation results show that the transmission capacity of the adaptive local routing strategy is larger than that of three previous local routing strategies.