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1 INTRODUCTION The chemistry of lanthanide (Ⅲ) complexes has a considerable history. The stereochemistry of the lanthanide (Ⅲ) complexes with ethyleneamine- N, N, N, N-tetraacetate (Edta) has been investigated[1~10]. Up to now, many Ln-Edta complexes with the chemical formulae of M[Ln(Edta)(H2O)m]nH2O (M = Na+, K+, Cs+, NH4+, Guanium; m = 2, 3; n = 0, 1, 3, 5) have been reported and suggested that the coordination modes and crystal systems for the Ln-Edta complexes depend on … 相似文献
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标题化合物是反应体系 (NH4) 3VS4/CoCl2 (PPh3) 2 /NEt4Cl在CH2 Cl2 中反应而得到的 ,单晶X射线结构分析表明 :其晶体属于立方晶系 ,化学式为C2 6 H35 NCl3CoP ,空间群为Pa3 ,Mr=5 5 7.84,a =17.80 7(5 ) ,V =5 6 46 .4 3,Z =8,Dc=1.31g/cm3,F(0 0 0 ) =2 32 8,μ(MoKα) =9.6cm- 1 ,R =0 .0 6 2 ,Rw =0 .0 6 7。标题化合物分子结构具有结晶学三次轴对称性 ,Co(II)原子为四面体配位 ,键角Cl-Co -Cl(113 .4(2 )°)大于键角Cl-Co -P(10 5 .2 (2 )°)。同时也讨论了标题化合物的电子光谱和变温磁化率 相似文献
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The solution reactions of the metal salts with 2,2'-bipyfidine (2,2'-bipy) and ethyl tetrazole-5-carboxylate (Hetzc) afforded two new tetrazole-based complexes M(2,2'-bipy)2(etzc)2 (M=Mn 1, Zn 2), and their crystal structures were determined by single-crystal X-ray diffraction analyses. Crystallographic data for 1: C28H26MnN12O4, Mr = 649.55, monoclinic, space group C2/c, a= 19.326(15), b = 11.051(6), c = 16.388(13)А,β= 117.38(4)° V= 3108(4) А^3, Z= 4, Dc = 1.388 g/cm^3, F(000) = 1340, R = 0.0557 and wR = 0.1269; and those for 2: C28H26ZnN12O4, Mr = 659.98, monoclinic, space group C2/c, a = 19.173(4), b = 11.006(2), c = 16.266(4) А, β= 118.11(3)°, V= 3027.4(11) А^3, Z = 4, Dc=1.448 g/cm3, F(000) = 1360, R = 0.0428 and wR = 0.1000. The structures of 1 and 2 are isomorphic and consist of isolated neutral mononuclear units. The metal atoms have highly distorted octahedral coordination environments with two N atoms from two etzc ligands and four N atoms from two 2,2'-bipy molecules. The isolated mononuclear units are connected by π…π stacking interactions to generate one-dimensional chains. The thermal stability and photoluminescence have also been discussed. 相似文献
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A novel phosphonate-based chiral metal-organic framework 1 was synthesized from C_2-symmetric 1,1?-biphenol-based ligand and structurally characterized by single-crystal and powder X-ray diffraction, Fourier-transform infrared spectra(FTIR), circular dichroism(CD) and thermogravimetric analyses(TGA). Two neighboring Mn ions are linked by two carboxylate groups and one phosphate group to form a di-manganese unit [Mn_2] and each [Mn_2] cluster in 1 is linked by five ligands, generating a 3D network with fns topology. In addition, the photoluminescence properties of 1 and H_4 L were investigated. 相似文献
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通过2,2′-联吡啶取代的草酸铬化合物和氯化钆在水溶液中反应合成了草酸根桥联的钆-铬六核双金属配合物的晶体。本文着重讨论该配合物的红外光谱。. 相似文献
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1 INTRODUCTIONInthepastfew years ,anincreasinginteresthasbeen giventothemagnetic propertiesofmolecularcomplexescomprisingsimultaneouslylanthanideandtransitionmetalionswiththeaimofclarifyingtheroleoftheexchangeinteractionsbetween 3dand 4fmetalionsmodifying… 相似文献
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以(NH_4)_3VS_4为起始原料,用低温固相法合成了标题簇合物,并测定其晶体结构.晶体属空间群P(?),单胞参数a=1.3139(10),b=2.5113(17),c=1.1800(8)nm,α=93.04(6)β=114.86(5),γ=96.71(7),Z=2,μ=21.4cm~(-1),R=0.084.在簇合物中,VS_4~(3-)保持较严格的四面体构型,并螯合四个Cu(I)离子连同桥Br-离子形成具有额外面的立方烷簇骼[VS_4Cu_4Br]. 相似文献