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在干燥氮气氛中,以乙醇为溶剂制备出稀土与二乙氨基荒酸二乙铵形成的十五个配合物,测定了它们的红外及紫外光谱、热谱和电导,确定该类配合物组成为Et~2NH~2[RE9S~2CNEt~2)~4](RE=La-Lu,Y;Pm除外)。镧配合物的X射线结构分析表明,在该配合物中四个二乙氨基荒酸根各通过两个硫原子与镧离子成键,从而形成八配位的十二面体阴离子,并与二乙铵阳离子形成离子缔合型的配合物分子。 相似文献
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The complexes of rare earth picrate with N,N,N',N'-tetraphenyl-3,6-dioxaoctanediamide(TDD),Eu(picc(TDD)] 2CH3CN and [ Y(pic)3(TDD)],have been synthesized.The crystal structures reveal that TDD at is as n tetradentate ligand,forming a ring-like coordination structure with its oxygen atoms together with one oxygen atom of the bidentate pterate In the Eu(Ⅲ) complex,the europium ion with a larger ionic radius lies out of the ring,while in the Y(Ⅲ) complex,the yttrium ion with a smaller ionic radius enters the cavity of the ligand.The structures of the complexes are greatly affected by the ionic radii due to participation of the picrates in coordination. 相似文献
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这篇报导是陈雪燕、谭民裕两同志刚从民主德国来比锡寄来的。他们是留德研究生,因为这个会议我国没有代表参加,而作者又非常关心祖国的大跃进,能及时寄来供国内读者参考,这是十分令人感激的。 相似文献
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The title complex, [CuL][CuCl2(NO3)2] [L=N,N,N′,N′,N″,N″-Hexaisopropyl-2, 2′, 2″-Nitrilotris(2,1-ethoxy)triacetamide], has been synthesized by using an amide-type tripodal ligand with Cu(NO3)2 and then characterized by X-ray single crystal structure analysis. It belongs to monoclinic,space group P21/c with a=1.522 7(2) nm,b=1.277 8(2) nm, c=2.184 5(4) nm, β=93.680(10)°, V=4.241 6(12) nm3, Z=4, Dc=1.401 Mg·m-3, μ=1.189 mm-1, F(000)=1 880, and final R1=0.050 9, wR2=0.125 3. The results show a Cu(Ⅱ) ion was encapsulated by the three chains of the cup-like heptadentate ligand and four-coordinated by the central nitrogen atom and three oxygen atoms from the ligand. CCDC: 648900. 相似文献
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The crystal structure of the title compound (C27H38N4O7S3, Mr = 626.79) has been determined by single-crystal X-ray diffraction. The crystal is of triclinic, space group Pīwith a = 9.411(1), b = 11.645(2), c = 14.672(2) (A。), α = 91.80(1), β = 95.36(1), γ =104.56(1)o, V = 1547.0 (A。)3, Z = 2, Dc = 1.346 g/cm3, λ = 0.71073 (A。), μ(MoKα) = 0.289 mm-1 and F(000) = 664. The structure was refined to R = 0.0406 and wR = 0.1177 for 4103 observed reflections with I > 2σ(I). X-ray diffraction analysis reveals that the title compound is a practically distorted tetrahedron and each molecule contains one lattice H2O by hydrogen bond. The antitumor activity of the title compound against HL-60 human leukemia cells has also been studied by MTT method. 相似文献