阴离子型表面活性剂组成的微乳热力学性质

采用加溶法研究了由阴离子型表面活性剂直链基磺酸钠ＣｎＨ２ｎ＋１ＳＯ３Ｎｎ（ｎ＝８,１０,１２,１４）－正烷烃－正已醇－水组成的四组分微乳液,探论了微乳液体系不同含水量时烷烃链长,表面活性剂链长和盐浓度对正已醇从油相转移至界面相对自由能－△Ｇ＾００→ｉ变化的影响,发现自由能－△Ｇ＾０ｏ→ｉ与烷烃 长有线性关系,但含水量不同,烷烃链长对自由能－△Ｇ＾０ｏ→ｉ的影响不同,含水量越高,烷烃链长影响越大,在     

Moderate heat treatment of CoFe Prussian blue analogues for enhanced oxygen evolution reaction performance

Prussian blue analogues(PBAs) with inherent ordered structures and abundant metal ion sites are widely explored as precursors for various electrochemical applications,including oxygen evolution reaction(OER).Using a range of characterization techniques including Fourier-transform infrared spectroscopy(FT-IR),X-ray photoelectron spectroscopy(XPS),X-ray diffraction(XRD) and energy dispersive spectroscopy(EDS),this work discloses the process of replacement of K⁺ by NH₄⁺     

Vertically aligned Ni/NiO nanocomposites with abundant oxygen deficient hetero-interfaces for enhanced overall water splitting

The design of heterostructured transition metal-based electrocatalysts with controlled composition and interfaces is key to increasing the efficiency of the water electrolysis and the elucidation of reaction mechanisms.In this work,we report the synthesis of well-controlled vertically aligned Ni/NiO nanocomposites consisting of Ni nanoclusters embedded in NiO,which result in highly efficient electrocatalysts for overall water splitting.We show that such a high catalytic efficiency toward both th...     

Double Subordination Preserving Properties for a New Generalized Srivastava-Attiya Integral Operator

The authors obtain subordination and superordination preserving properties for a new defined generalized operator involving the Srivastava-Attiya integral operator.Differential sandwich-type theorems f...     

Statistical Structures on Metric Path Spaces

The authors extend the notion of statistical structure from Riemannian geometry to the general framework of path spaces endowed with a nonlinear connection and a generalized metric. Two particular cases of statistical data are defined. The existence and uniqueness of a nonlinear connection corresponding to these classes is proved. Two Koszul tensors are introduced in accordance with the Riemannian approach. As applications, the authors treat the Finslerian (α, β)-metrics and the Beil metrics used in relativity and field theories while the support Riemannian metric is the Fisher-Rao metric of a statistical model.     

一类奇异p-Laplace方程无穷多解的存在性

讨论了一类具有奇异系数的p-Laplace问题-Δpu-μ|u|u|x|p=u|x|tu+λuq-2u,x∈Ω,u=0,x∈Ω无穷多解的存在性,其中N≥3,Ω是RN中一有界光滑区域,0∈Ω,Δpu=-div(|▽u|p-2▽u),0≤μ<μ=(N-p)ppp,10,1相似文献   

Formation of net-like patterns of gold nanoparticles in liquid crystal matrix at the air-water interface

Controlled patterning and formation of nanostructures on surfaces based on self-assembly is a promising area in the field of "bottom-up" nanomaterial engineering. We report formation of net-like structures of gold nanoparticles (Au NPs) in a matrix of liquid crystalline amphiphile 4'-n-octyl-4-cyanobiphenyl at the air-water interface. After initial compression to at least 18?mN?m(-1), decompression of a Langmuir film of a mixture containing both components results in formation of net-like structures. The average size of a unit cell of the net is easily adjustable by changing the surface pressure during the decompression of the film. The net-like patterns of different, desired average unit cell areas were transferred onto solid substrates (Langmuir-Blodgett method) and investigated with scanning electron microscopy and X-ray reflectivity (XRR). Uniform coverage over large areas was proved. XRR data revealed lifting of the Au NPs from the surface during the formation of the film. A molecular mechanism of formation of the net-like structures is discussed. ELECTRONIC SUPPLEMENTARY MATERIAL: The online version of this article (doi:10.1007/s11051-012-0826-4) contains supplementary material, which is available to authorized users.     

Size-controlled aerosol synthesis of silver nanoparticles for plasmonic materials

Aerosol techniques were used to synthesize spherical and monodisperse silver nanoparticles for plasmonic materials. The particles were generated with an evaporation-condensation technique followed by size selection and sintering with a differential mobility analyzer and a tube furnace, respectively. Finally, the nanoparticles were collected on a glass substrate with an electrostatic precipitator. The particle size distributions were measured with a scanning mobility particle sizer and verified with a transmission electron microscope. A spectrophotometer was used to measure the optical extinction spectra of the prepared samples, which contained particles with diameters of approximately 50, 90 and 130?nm. By controlling the particle size, the dipolar peak of the localized surface plasmon resonance was tuned between wavelengths of 398 and 448?nm. In addition, quadrupolar resonances were observed at shorter wavelengths as predicted by the simplified theoretical model used to characterize the measured spectra.     

科学技术名词规范化发展与现状

@@@@文章介绍了全国科学技术名词审定委员会的历史和成果,阐述了科技名词审定的原则和术语学研究的进展,还介绍了海峡两岸科技名词对照工作的成果与未来的两岸名词对照工作的计划。