Bi2WO6/TiO2纳米管异质结构复合材料的多模式下的光催化活性比较

以TiO₂纳米管为模板,采用多组分自组装结合水热法制备Bi₂WO₆/TiO₂纳米管异质结构复合材料。通过多种技术如X射线衍射（XRD）,X射线光电子能谱（XPS）,N₂吸附脱附,扫描电镜（SEM）,高分辨透射电镜（HRTEM）和紫外可见漫反射吸收光谱（UV-Vis DRS）考察所制备样品的组成、结构、形貌、光吸收和电子性质。Bi₂WO₆纳米片或纳米粒子分布在TiO₂纳米管上,形成异质结构。随后,通过在紫外、可见和微波辅助光催化模式下降解染料罗丹明B（RhB）来评价复合催化剂的光催化活性。与TiO₂纳米管和Bi₂WO₆相比,Bi₂WO₆/TiO₂-35纳米管在多模式下表现出更优异的光催化活性。与紫外和可见降解模式相比,Bi₂WO₆/TiO₂-35纳米管在微波辅助光催化模式下对RhB的降解效率最高。这种增强的光催化活性源于适量Bi₂WO₆的引入、纳米管独特的形貌特征和降解模式所引起的增强的量子效率。降解过程中的活性物种被证明是h⁺,·OH和·O₂^-自由基。而且,在微波辅助光催化模式下,可产生更多的·OH和·O₂^-自由基。     

近红外光谱法应用于奥美拉唑含量分析

基于近红外光谱分析技术建立奥美拉唑定量分析方法.以高效液相色谱法作为参考方法,采用偏最小二乘法(PLS)对同一厂家不同批号的奥美拉唑肠溶胶囊建立校正模型,所建模型相关系数(R)为0.978,校正均方差(RMSEC)为0.0899,交叉验证均方差(RMSECV)为0.182,校正模型的预测均方差(RMSEP)为0.161...     

大气压微波等离子体射流装置放电特性研究

基于同轴传输线结构设计了两种不同喷嘴结构的大气压微波等离子体射流(MW-APPJ)装置,其工作频率2.45 GHz,工作气体为氩气,分别研究了两种不同喷嘴结构对等离子体放电特性产生的影响。仿真结果表明,MW-APPJ在气体喷嘴处会产生高强度的电场,经过优化结构,实现在频率2.45 GHz下,喷嘴处的场强满足氩气电离的击穿场强阈值要求。同时,利用多物理场耦合仿真软件对装置的气流分布进行了稳态模拟,并通过实验对比分析了两种喷嘴结构下大气压氩等离子体射流的基本特性。实验结果表明,不同的喷嘴结构会影响等离子体装置的反射系数随输入功率的变化规律,但并不影响等离子体射流长度随输入功率的变化规律和反射功率随进气流量的变化规律;同时,在大气压下,稳态微波等离子体射流呈现出类金属性,等离子体中的电子只能在很薄的区域中吸收微波能量,因而造成微波的反射功率较大。     

黑胡椒根萜类化合物的分析

报道了用蒸馏 萃取法提取黑胡椒根中挥发性物质,测得黑胡椒根挥发油的质量分数为3.1%,用GC/MS法从黑胡椒根挥发油中分离并确定出28种化学成分。其中主要成分为萜类化合物,占总检出量的82.48%。     

中国物理类期刊比较研究

从《中文核心期刊要目总览》和《中国科技期刊引证报告》出发,分析国内物理类的主要期刊．对这些期刊在SCI、EI的收录情况、影响因子等方面进行了比较研究,为我国的物理研究和期刊发展提供参考．     

In-situ growth of Ca/P salt on Ti surface induced by femtosecond lasers in hydroxyapatite suspension

Pure Ti plate surfaces are micro-ablated by femtosecond lasers in the ambience of hydroxyapatite suspension. It is found that three-stage hierarchical surface structures are produced with various laser energies. When the laser energy is 150 μJ, a lava-like structure with a distribution of nanoholes is dispersed evenly on the laser ablated surface. While in the case of 300 μJ, the grooves-and-islands micro-patterns covered with nanoparticles are generated on the surface. Remarkably, Ca/P based substances are revealed to firmly deposit on the micro-structured surfaces. More phosphate growth is seen for the higher laser energy. Discussions suggest that the additional elements deposition could be attributed to the chemical reaction of plasma related ions in the suspension and their subsequent crystallisation on the fresh surfaces of Ti plate due to the femtosecond laser ablation.     

Model and application of bidirectional pedestrian flows at signalized crosswalks

This research of bidirectional pedestrian flows at signalized crosswalks is divided into two parts: model and application. In the model part, a mixed survey including the questionnaire investigation and tracking investigation is conducted to gain the basic data about walking tendentiousness of a pedestrian crossing. Then, the forward, right-hand, outstripping,and influential coefficients are outlined to quantize walking tendentiousness of pedestrian crossing and estimate transition probabilities of pedestrians. At last, an improved cellular automation model is proposed to describe walking tendentiousness and crossing behaviors of pedestrians. In the application part, channelization research of bidirectional pedestrian flows is presented for real signalized crosswalk. In this process, the effects of right-side-walking and conformity behaviors on the efficiency of pedestrian crossing are thoroughly analyzed based on simulations and experiments to obtain a final channelization method to raise the efficiency of a pedestrian crossing at the crosswalk.     

太赫兹波斜入射到磁化等离子体的数值研究

针对“黑障”问题,借助于电磁波斜入射到磁化等离子体的传输模型,研究了太赫兹(THz)波在磁化、均匀等离子体中的传输特性,分析了太赫兹波在磁化等离子体中传播的反射、透射以及衰减。仿真结果表明,等离子体碰撞频率、电子密度、入射角度以及磁场强度,对衰减产生不同的影响。单纯的增加碰撞频率,衰减值呈现出先增大后减小的变化趋势;电子密度的增加,与衰减峰值的大小有关;外加磁场加入,衰减值降低。通过调节外加恒定磁场,可以有效地解决“黑障”问题。