爆轰法合成纳米CeO粉末*2

爆轰合成过程中采用Ce(NO₃)₃·6H₂O制备的可爆药剂,并利用X射线衍射仪(XRD)和透射电子显微镜(TEM)对合成的纳米CeO₂粉末进行了检测,研究了起爆方式对于合成产物结晶化度、粒径和形貌的影响。结果表明,采用Ce(NO₃)₃·6H₂O制备的可爆药剂,可以合成立方晶系的球形纳米CeO₂; 提高可爆药剂的爆速,可有效降低纳米CeO₂的粒径,得到球形化更好的纳米粒子。     

单轴、双轴应变Si拉曼谱应力模型

本文依据拉曼光谱原理, 基于Secular方程及拉曼选择定则分别获得了单轴、 双轴(001), (101), (111)应变Si材料应变张量与拉曼谱线移动的定量关系, 并在此基础上, 基于广义胡克定律最终建立了单轴、双轴(001), (101), (111)应变Si材料拉曼谱峰与应力的理论关系模型. 该模型建立过程详细、系统, 所得结果全面、量化, 可为应变Si材料应力的测试分析提供重要理论参考.     

基于CPV技术的LED路灯聚光器的研究

以120W大功率LED路灯太阳能电池板为研究对象,通过聚光光伏技术,利用光学透镜(聚光器)提高太阳能电池的光电转换效率。利用聚焦作用增大光照密度,有效地降低了太阳能光照面积,极大地减少了光电材料的使用量,大幅度降低了太阳能电池的成本。通过光学仿真软件TracePro进行仿真,验证了其可行性。     

原子荧光光谱法测定土壤中的砷

应用原子荧光光谱法测定砷的含量。以深层生土、地表熟土为样品,采用顺序注射氢化物发生-原子荧光光谱法进行测定。在最佳实验条件下,方法的线性范围在2—60μg/L以内,相关系数r=0.9993,检出限为0.16μg/L,测定标准溶液的RSD为1.6%(n=11),样品加标回收率为96.5%—103.5%,方法简单、快速,可测定土壤中的砷。     

应用群论分析甲烷的红外和拉曼光谱特征

应用群论的方法构造CH4的简正坐标从而组合它的9个简正振动模式,根据红外光谱和拉曼光谱的选择定则分析CH4简正振动模式得出CH4分子的红外和拉曼光谱特征,采用群论方法使我们的计算大大简化.     

A k·p analytical model for valence band of biaxial strained Ge on（001） Si1-xGex

In this paper,the dispersion relationship is derived by using the k·p method with the help of the perturbation theory,and we obtain the analytical expression in connection with the deformation potential.The calculation of the valence band of the biaxial strained Ge/（001）Si1-xGex is then performed.The results show that the first valence band edge moves up as Ge fraction x decreases,while the second valence band edge moves down.The band structures in the strained Ge/（001）Si 0.4 Ge 0.6 exhibit significant changes with x decreasing in the relaxed Ge along the [0,0,k] and the [k,0,0] directions.Furthermore,we employ a pseudo-potential total energy package（CASTEP） approach to calculate the band structure with the Ge fraction ranging from x = 0.6 to 1.Our analytical results of the splitting energy accord with the CASTEP-extracted results.The quantitative results obtained in this work can provide some theoretical references to the understanding of the strained Ge materials and the conduction channel design related to stress and orientation in the strained Ge pMOSFET.     

教材中一幅不正确的题图

现行高中物理课本第三册(选修)第65页,有一幅跳台滑雪运动员腾空飞跃的题图(题略),如图1所示.运动员的飞行是平抛运动,但题图中的轨迹反映出来的却是平行于斜面方向上最大距离中点处时运动员离开斜面最远,这显然是平行于斜面的"类斜抛运动"轨迹,在一些资料中也常出现类似的题图.由此看来,具有指导作用的教材再版时,应该把不科学的题图修正过来,否则会对学生分析问题产生误导.     

新型荧光化学敏感器的合成及性质研究

分子识别是超分子化学的一个重要方面.它是分子传递和酶催化的基础.以分子识别为基础,设计和合成了有光谱响应的荧光化学敏感器和离子显色试剂,在生物化学、临床医学、环境科学等与人类生命科学密切相关的领域中有着很强的应用背景.本论文系统总结了环糊精对有机分子的包结特征和包结作用对客体分子光物理性质的影响,以及用荧光发色团化学修饰的环糊精分子在识别研究中的发展状况.考虑到当前分子识别研究中的另一问题,即发展对阴离子物种有选择性响应的荧光化学敏感器和显色试剂,本论文还总结了目前在设计和合成阴离子接受体方面的发展状况和特点.本论文工作正是从以下两个方面进行了研究.     

Soliton Solutions,Bcklund Transformations and Lax Pair for a(3 + 1)-Dimensional Variable-Coefficient Kadomtsev–Petviashvili Equation in Fluids

Under investigation in this paper is a(3 + 1)-dimensional variable-coefficient Kadomtsev–Petviashvili equation, which describes the propagation of surface and internal water waves. By virtue of the binary Bell polynomials,symbolic computation and auxiliary independent variable, the bilinear forms, soliton solutions, B¨acklund transformations and Lax pair are obtained. Variable coefficients of the equation can affect the solitonic structure, when they are specially chosen, while curved and linear solitons are illustrated. Elastic collisions between/among two and three solitons are discussed, through which the solitons keep their original shapes invariant except for some phase shifts.     

Calculation of the reactor neutron time of flight spectrum by convolution technique

It is a very complex and time-consuming process to simulate the nuclear reactor neutron spectrum from the reactor core to the export channel by applying a Monte Carlo program. This paper presents a new method to calculate the neutron spectrum by using the convolution technique which considers the channel transportation as a linear system and the transportation scattering as the response function. It also applies Monte Carlo Neutron and Photon Transport Code （MCNP） to simulate the response function numerically. With the application of convolution technique to calculate the spectrum distribution from the core to the channel, the process is then much more convenient only with the simple numerical integral numeration. This saves computer time and reduces some trouble in re-writing of the MCNP program.