设计可逆电池的简单方法

介绍了通过确定电解质溶液、确定电极、复核反应等步骤把化学反应(或物理变化)设计成可逆电池的简单方法。     

金刚石切割多晶硅片切割痕性质与消除方法研究

金刚石线锯切割多晶硅片表面存在两种尺度的切割痕纹:由锯线往复运动形成的周期在亚毫米尺度的往复纹,和由金刚石划出的宽度在微米尺度的划痕.金刚石切割硅片的微观粗糙度比砂浆切割硅片小～25;.金刚石切割硅片相对粗糙表观以及往复纹的呈现都来自于光滑划痕的视觉增强作用.酸刻蚀制绒不能消除金刚石切割硅片表面切割痕纹;碱刻蚀只能消除部分晶粒之上的切割痕纹.尝试了一种气相酸刻蚀方法,取得了彻底消除金刚石切割硅片表面切割痕纹的效果,同时获得了良好的制绒效果,但其均匀性有待改善.     

大型引射筒呼吸振动破坏机理的实验和模拟研究

针对某大型引射筒结构,通过有限元模拟分析,找到了对应于纵向裂纹的引射筒花瓣状呼吸振动模态及其频率;应用动应力分析,发现引起该引射筒破坏的频率主要集中在200～300 Hz的低频段.并进行了相关的模态试验,得到了典型的呼吸振动模态及频率,与计算结果进行了对比;结果表明计算与试验符合得很好,验证了数值建模与分析的合理性.     

纳米材料力学行为的原子尺度模拟研究

对几何尺寸极小的纳米材料而言,数值模拟是与实验测试同样有效的研究手段, 而且,当材料特征尺寸更小、缺乏可用的测试系统时,数值模拟可能是唯一的方法.介绍了近年来纳米材料力学行为的原子尺度数值模拟研究方面的若干新进展,重点综述了采用分子动力学模拟与第一原理计算对纳米材料的晶格不稳定性、理想强度、界面断裂、碳纳米管的力电特性和铁电纳米材料的力电特性等问题的研究结果.总结介绍了纳米材料原子尺度模拟中一些实用的计算策略和方法,并提出了若干需要进一步研究的问题.      

对甲氧基苯甲腈的单色共振双光子电离光谱

对甲氧基苯甲腈是一种重要的化学化工原料,本文采用超声分子束技术和共振多光子电离方法获得了对甲氧基苯甲腈的单色共振双光子电离光谱,基态S0到电子激发态S1的0←0跃迁被确定为(35549±2)cm~(-1),结合含时密度泛函理论计算结果对观察到的光谱进行了振动模式标识和描述.实验发现呼吸振动模非常易于激活,其基频和二次泛频光谱很强,三次泛频也可明确标识,观察到大量呼吸振动与其他正则模的结合振动,这是对甲氧基苯甲腈不同于常见的多原子分子的一个重要特性.这些结果为研究对甲氧基苯甲腈的里德堡态、动力学和零动能光谱等提供了重要的参考数据.     

Synthesis,Crystal Structure and Thermal Properties of Zn(NH_3)_3(AFT)_2

A new coordination compound of Zn(NH_3)_3(AFT)_2(1,ZnC_6H_(13)N_(17)O_2,AFT =4-amino-3-(5-tetrazolate)-furazan)was synthesized and characterized by elemental analysis and FT-IR spectrum.Its crystal structure was determined by X-ray single-crystal diffraction.This crystal belongs to the orthorhombic system,space group Pnma with a = 18.680(3),b = 6.9438(11),c =12.268(2)A,μ= 1.592 mm-1,V= 1591.3(4)A3,M,= 420.72,Dc=1.756 g·cm-3,Z= 4,F(000)= 860,the final R = 0.0480 and wR = 0.1262 for the observed reflections with I2σ(Ⅰ).The zinc(Ⅱ)ion is five-coordinated by N atoms from two AFT"ligands and three NH3 molecules.The thermal decomposition mechanism of compound 1 was tested by differential scanning calorimetry(DSC)and thermogravimetry-derivative thermogravimetry(TG-DTG)methods.The DSC curve exhibits two endothermic and one exothermic processes.In addition,the non-isothermal kinetics parameters were calculated by using the Kissinger s method and Ozawa-Doyle's method.Besides,the entropy of activation(ΔS≠),enthalpy of activation(ΔH≠),free energy of activation(ΔG≠)and impact sensitivity(IS)was also obtained.     

调制n型掺杂ZnSe/BeTe Ⅱ型量子阱结构的发光特性

报道了调制n型掺杂ZnSe/BeTe/ZnSe Ⅱ型量子阱(type-II QW)在极低温至室温(14—296K)条件下的各种光学性质. 反射光谱显示了对于非掺杂样品,激子(X)的跃迁起着支配作用,而只有在掺杂样品的光谱里展示了一个典型的负的带电激子(X^-)的跃迁特征. PL光谱及其直线偏振度P_l都显著地依赖于n型掺杂量和平行于QW生长方向的外加电场. 这个特征被认为是由n型掺杂导致了内秉电场(built 关键词： 光致发光 二维电子气 带电激子 Ⅱ型量子阱     

First Beam Measurements of the S-Band photocathode Radio-Frequency Gun at Tsinghua University

During the last decades, photocathode rf gun has been proven to be successful in generating the high brightness electron beam （-lnC,-lπ mmmrad,-l ps） which is required by the ILC, XFEL, Thomson scattering x-ra y source, etc. A photocathode rf gun system is built to develop electron source for the Thomson scattering x-ray source at Accelerator Laboratory of Tsinghua University. The system consists of a BNL/ATF-type 1.6 cell S-band rf cavity, a solenoid for emittance compensation, a laser system and some simple equipments for beam diagnosis. The first beam measurements of the photocathode rf gun, including the dark current, transverse beam profile, charge and quantum efficiency, are reported.     

Determination of 15 polycyclic aromatic hydrocarbons in lotus root by QuEChERS-high performance liquid chromatographyEI北大核心CSCD

A method for the determination of 15 priority polycyclic aromatic hydrocarbonsPAHsin lotus root by QuEChERS technique combined with high performance liquid chromatography HPLC was established. Lotus root samples were extracted by acetonitrilefiltrated after salting out and purified by C18 and primary secondary aminePSAsorbent. Then the 15 kinds of PAHs were analyzed by HPLC with diode array detector or fluorescence detector after being separated by Athena PAHs column. When the 15 kinds of PAHs were analyzed by diode array detectorthe linear relationships were good between 0.02 and 1.0 mg/L with the correlation coefficients above 0.99 for all the 15 kinds of PAHs. The limits of quantitation were 0.02 mg/kg for allthe average recoveries of the 15 kinds of PAHs were 84.7%-117.1%and the relative standard deviations were 0.73%-11%. When the 14 kinds of PAHsexcept for acenaphthyleneanalyzed by fluorescence detectorthe linear relationships were good between 0.001 and 1.0 mg/L with the correlation coefficients above 0.99 for all the 14 kinds of PAHs except for acenaphthylene. The limits of quantitation were 5 μµg/kg for allthe average recoveries of the 14 kinds of PAHsexcept for acenaphthylenewere 69.1%-111.8%and the relative standard deviations were 0.18%-9.7%. Diode array detector and fluorescence detector are complementary. Diode array detector can analyze all the PAHsbut its sensitivity is relatively low. Fluorescence detector is not suitable for acenaphthylene with weak fluorescence signalbut its sensitivity is much higher than that of diode array detector. This method is suitable for simultaneously and quickly determination of 15 kinds of PAHs in lotus root. © 2022, Youke Publishing Co.,Ltd. All rights reserved.