(Zn_(1-x),Mg_x)_2GeO_4∶Mn~(2+)的荧光以及长余辉发光性能

采用高温固相法制备了一系列(Zn_(1-x),Mg_x)_2GeO_4∶Mn~(2+)(0≤x≤0.25)绿色荧光粉,并研究了Mg离子对(Zn_(1-x),Mg_x)_2GeO_4∶Mn~(2+)的结构、荧光以及长余辉发光性能的影响。Mg离子取代Zn进入Zn_2GeO_4晶格,形成(Zn_(1-x),Mg_x)_2GeO_4固溶体,并产生了晶格畸变。光谱分析结果表明,样品中位于533 nm的绿色荧光源于Mn~(2+)的~4T_1(~4G)→~6A_1(~6S)跃迁。随着Mg离子浓度的增加,(Zn_(1-x),Mg_x)_2GeO_4∶Mn~(2+)样品的激发光谱出现了蓝移现象,说明Mg离子进入到Zn_2GeO_4晶格中对其晶格结构产生了影响,导致(Zn_(1-x),Mg_x)_2GeO_4的带宽发生改变。发射光谱则表明Mg离子进入Zn_2GeO_4晶格引起Mn~(2+)的~4T_1(~4G)→~6A_1(~6S)跃迁绿色荧光发光强度的增强。Zn_2GeO_4基质中的氧空位缺陷陷阱深度由于基质带宽的变化而变深,样品具有良好的长余辉发光效果。通过热释光谱分析研究了材料中缺陷陷阱的特征,进一步证实了(Zn_(1-x),Mg_x)_2GeO_4中缺陷陷阱深度发生改变。根据光谱分析结果给出了(Zn_(1-x),Mg_x)_2GeO_4∶Mn~(2+)中荧光与余辉发光的产生机理。     

溶胶-凝胶法Er_2O_3薄膜的结构和光学特性

针对稀土Er掺杂Si光源中Er离子掺杂浓度低的问题,采用溶胶-凝胶(Sol-gel)法在Si(100)和SiO2/Si(100)基片上旋涂法制备Er2O3光学薄膜,Er离子浓度与以前掺杂方法相比提高了2个数量级.900℃热处理获得单一立方结构的Er2O3薄膜材料.光致发光(PL)特性研究表明在654nm波长的激光泵浦下,Er2O3薄膜材料获得了1.535μm的发光峰,并具有较小的温度猝灭1/5.在SiO2/Si(100)基体上制备的Er2O3薄膜材料的光致发光强度比Si(100)基体上制备的薄膜提高2-3倍.研究结果表明具有强光致发光特性的Er2O3薄膜是一种有前景的硅基光源和放大器材料.     

基于多光谱数据的湿地景观格局变化对越冬候鸟生境影响

安徽升金湖是典型的长江中下游自然通江湖泊湿地,是越冬候鸟尤其是珍稀鹤类的理想越冬地,水利设施的修建改变了升金湖的自然连通状况,使湖泊水位变化受人为控制,继而引起景观格局变化,从而影响越冬候鸟生境.为探究水位波动对越冬候鸟生境影响规律,基于Landsat-8(OLI)多光谱遥感影像对升金湖土地利用类型进行分类,结合水位数...     

利用部分相干光和同心角偏差透镜列阵实现二维靶面均匀辐照

提出利用部分相干光通过透镜列阵系统实现靶而的均匀辐照, 透镜列阵能获得边缘陡峭且顶部较平坦的准近场焦斑, 透镜列阵的适当同心度偏差又使各子束的斑纹相互稍微错开, 使干涉斑纹变密, 而入射的激光是空间相干性减少了的部分相干光, 可进一步抑制了透镜列阵系统焦斑的小尺度不均匀性. 使用广义衍射积分理论, 对高斯-谢尔光束通过透镜列阵光学系统的焦斑光强分布进行了详细的二维模拟研究, 比较了完全相干光与部分相干光经过透镜列阵的匀滑效果. 数值模拟表明, 应用同心度偏差和适当离焦时, 可实现焦斑均匀性和能量利用率同时达到最佳的效果.     

矩形靶标测试CCD相机调制传递函数的研究

利用矩形靶标测量CCD相机的整机调制传递函数时,由于靶标与CCD像元之间存在初始角度误差与初始位置误差,实验测得的调制传递函数小于CCD相机实际调制传递函数。根据调制传递函数的定义,模拟CCD对具有初始角度误差与初始位置误差的矩形靶标成像,推导出了CCD像元的亮度分布公式,从而给出了调制度与初始角度误差和初始位置误差的关系,并分别对具有初始角度差、初始位置差的情况进行分析。最后利用像元间的亮度差推导出计算初始角度误差的理论公式并进行了仿真验证。     

Yb3+掺杂对Er3+:NaYF4上转换发光的调制作用

采用溶胶-凝胶(Sol-gel)法制备了2 mol％ Er3+、0,20和80 mol％ Yb3+共掺杂NaYF4上转换发光粉末.Er3+:NaYF4为α-NaYF4相和β-NaYF4相的混合结构,Yb3+共掺杂促进了β相到a相的转变.在976 nm半导体激光器(LD)激发下获得了对应于Er3+的2 H11/2/4 S...     

Optical parameters of Nd3＋：Er3＋：yb3＋ co-doped borosilicate glasses and their energy transfers at high temperature

This paper reports that a series of Nd³⁺:Er³⁺:Yb³⁺ co-doped borosilicate glasses have been prepared and their absorption spectra measured. The J--O intensity parameters Ω_k (k=2, 4, 6), spontaneous radiative lifetime τ_rad, spontaneous transition probability A, fluorescence branching ratio β and oscillator strength f_ed of the Nd³⁺ ions at room temperature are calculated based on Judd--Ofelt (J--O) theory. The temperature dependence of the up-conversion photoluminescence characteristics in a Nd³⁺:Er³⁺:Yb³⁺ co-doped sample is studied under a 978 nm semiconductor laser excitation, and the energy transfer mechanisms among Yb³⁺, Er³⁺ and Nd³⁺ ions are analysed. The results show that the J--O intensity parameters Ω₂ increase when the Nd³⁺ concentration of the Nd³⁺:Er³⁺:Yb³⁺ co-doped borosilicate glasses increases. The possibility of spontaneous transition is small and lifetimes are long at levels of ⁴F_5/2 and ⁴F_3/2. The intensity of Nd³⁺ emissions at 595, 691, 753, 813 and 887 nm are markedly enhanced when the sample temperature exceeds 400 K. The reasons being the cooperation of the secondary sensitization from Er³⁺ to Nd³⁺ and the contribution of a multi-phonon.     

溶胶-凝胶法Er2O3薄膜的结构和光学特性

针对稀土Er掺杂Si光源中Er离子掺杂浓度低的问题,采用溶胶-凝胶（Sol-gel）法在Si(100)和SiO2/Si(100)基片上旋涂法制备Er₂O₃光学薄膜,Er离子浓度与以前掺杂方法相比提高了2个数量级.900 ℃热处理获得单一立方结构的Er₂O₃薄膜材料.光致发光（PL）特性研究表明在654 nm波长的激光泵浦下,Er₂O₃薄膜材料获得了1.535 μm的发光峰,并具有较小的温度猝灭1/5.在SiO₂/Si(100)基体上制备的Er2O3薄膜材料的光致发光强度比Si(100)基体上制备的薄膜提高2-3倍.研究结果表明具有强光致发光特性的Er₂O₃薄膜是一种有前景的硅基光源和放大器材料.     

Selective enhancement of green upconversion luminescence of Er-Yb: NaYF_4 by surface plasmon resonance of W_(18)O_(49) nanoflowers and applications in temperature sensing

The W_(18)O_(49) nanoflowers with a diameter of 500 nm are prepared by a facile hydrothermal method. The Er-Yb:NaYF4 nanoparticles are adsorbed on the petals(the position of the strongest local electric field on W_(18)O_(49) nanoflowers).With a 976 nm laser diode(LD) as an excitation source, the selectively green upconversion luminescence(UCL) is observed to be enhanced by two orders of magnitude in Er-Yb: NaYF4/W_(18)O_(49) nanoflowers heterostructures. It suggests that the near infrared(NIR)-excited localized surface plasmon resonance(LSPR) of W_(18)O_(49) is primarily responsible for the enhanced UCL, which could be partly reabsorbed by the W_(18)O_(49), thus leading to the selective enhancement of green UCL for the Er-Yb: NaYF4. The fluorescence intensity ratio is investigated as a function of temperature based on the intense green UCL, which indicates that Er-Yb: NaYF_4/W_(18)O_(49) nanoflower heterostructures have good potential for developing into temperature sensors.     

动力调谐式双轴速率陀螺仪再平衡回路的分析与设计

本文分析了动力调谐式双轴速率陀螺仪再平衡回路的设计方法,指出了对于未解耦的双轴速率陀螺的再平衡回路是一个双输入双输出的控制系统,不但分析困难,实际运行也很困难,所以实现解耦控制是多变量过程控制系统分析的核心。通过对控制对象的若干简化,并运用现代控制中的多变量解耦理论,寻求一种简易的数字控制方案,并对其结构参数进行优化设计,最后用计算机数字仿真对其理论分析与设计给以检验。