X-90型荧光光谱仪在无机定性分析中的应用探讨

目前用于金、银、铂饰品检测的 X- 90荧光光谱仪 ,具有检测方法简便、快捷、准确、成本低、无损伤等优点 ,也可利用此仪器的特点 ,扩展测定范围。1　理论依据每一种物质都有其特定的原子结构。样品被某种激发源 (本机为2 4 1Am放射性同位素 )所发射的初级射线激发而自发地发射出其所含元素特征的荧光X射线。每个元素的特征荧光 X射线都具有特定的能量 ,探测这些特征荧光 X射线并识别其能量 ,就能识别出该被测样品中含有哪些主要元素。2　操作步骤按操作规程 ,打开仪器 ,以银、铜块校准峰位 (即谱峰尖顶所对应横座标的位置 ) ;将被测物放入…     

A theoretical study on the intermolecular interaction of energetic system-Nitromethane dimer

Three optimized geometries of nitromethane dimer have been obtained at the HF/6-31G level.Dimer binding energies have been corrected for the basis set superposition error (BSSE) and the zero point energy.Computed results indicate that the cyclic structure of (CH3NO2)2 is the most stable of three optimized geometries,whose corrected binding energyis 17.29 kJ mol-1 at the MP4SDTQ/6-31G//HF/6-31G level.In the optimized structures of nitromethane dimer,the inter-molecular hydrogen bond has not been found; and the charge-transfer interaction between CH3NO2 subsystems is weak; and the correlation interaction energy makes a little contribution to the intermolecular interaction energy of the dimer.     

Effect of micro-dimple patterns on capillary pull-off force and friction force of silicon surface

A microtribometer is used to measure and compare pull-off forces and friction forces exerted on (a) micro-dimpled silicon surfaces, (b) bare silicon surfaces, and (c) octadecyltrichlorosilane (OTS) treated silicon surfaces at different relative humidity (RH) levels separately. It is found that above a critical RH level, the capillary pull-off force increases abruptly and that the micro-dimple textured surface has a lower critical RH value as well as a higher pull-off force value than the other two surfaces. A micro topography parameter, namely sidewall area ratio, is found to play a major role in controlling the capillary pull-off force. Furthermore, micro-dimpled silicon surface is also proved to be not sensitive to variation in RH level, and can realize a stable and decreased friction coefficient compared with un-textured silicon surfaces. The reservoir-like function of micro dimples is considered to weaken or avoid the breakage effect of liquid bridges at different RH levels, thereby maintaining a stable frictional behaviour.     

Realization of an efficient coherent combination via Michelson cavity

An intracavity coherent coupling Michelson erbium-doped fibre (EDF) laser (MCEDFL) is proposed and demonstrated. By using this laser system, we find a means to obtain a maximum power output at the same pumping power level. From the experiment based on fibre Bragg gratings (FBGs) with different reflectivities from 6{\%} to 100{\%}, we find that the reflectivity of the FBG plays a vital role in improving the performance of the MCEDFL. At the same time, the MCEDFL with a polarizer can be coherently combined effectively. This type of system, in principle, is compatible with other more powerful pumping methods, such as cladding pumping, and brings some novel perspectives to the realization of high power lasers.     

双-锌卟啉对DABCO分子识别的立体构象及其热力学研究

合成了系列不同长度以柔性侧链相连的p/p型双-锌卟啉配合物,用¹H NMR和UV-Vis研究了不同温度下该系列配合物与刚性双齿配体DABCO(1,4-二氮杂双环)的轴向配位反应,考察了侧链长度对双-锌卟啉与配体的分子识别能力影响。结果表明,主体分子双-锌卟啉可以对客体分子BABCO进行分子识别,合适长度的柔韧烷氧链可以调节主体分子的构象,使DABCO嵌入双卟啉两个卟啉环间空位中,形成锌卟啉-DABCO-锌卟啉三元夹心式配合物构象。探讨了配位反应中立体构象的变化过程,并测定了热力学参数。     

蓝舌病毒HbC3株S7基因5’非编码区序列分析

根据已发表的蓝舌病毒(bluetongue virus．BTV)10型标准株S7基因设计合成一对与其5'-NCR(noncoding region)序列同源的引物．经反转录-聚合酶链反应(RT-PCR)扩增出HbC3株和10型标准株长度分别为277bp和290bp的S7基因5’非编码区cDNA片段．以建立起dsRNA体外扩增系统．将扩增的BTV-HbC3毒株的S7基因5’非编码区片段通过粘端连接克隆到pUCm-T载体中．用PCR技术和限制性内切酶分析鉴定，表明获得重组质粒pUCm-T-BTV-HbC3-S7．通过核苷酸序列分析方法分别将2个毒株的S7基因5’非编码区与呼肠孤病毒-3(reovirus-3)型比对。发现BTV-HbC3株与呼肠孤病毒-3 L2基因5’非编码区基因具有完全的同源性．将BTV-HbC3毒株接种在不同细胞系如猴肾传代细胞(Vero)、人肝癌细胞(Hep-3B)和小鼠成纤维细胞(L929)等细胞株上，比较BTV-HbC3在不同种系细胞上的增殖特征，并且用双向免疫扩散试验证实BTV-HbC3和BTV-10型之间的血清学关系．结合本实验室的研究结果提示BTV-HbC3株可能是蓝舌病毒的一个新的基因型．     

爆磁压缩装置经组合功率调节系统产生高电压的实验研究

 介绍了以爆磁压缩装置为脉冲功率能源,经变压器和爆炸金属丝断路开关组合功率调节系统,在电阻负载上产生高电压的实验研究。实验结果为：在100W 水电阻负载两端得到了约800kV的高电压脉冲,脉宽约100ns。此项工作拓宽了爆磁压缩装置的应用范围。     

溶出伏安法同时测定水中痕量铀和镍

本文报道了同时测定钴和镍的一种方法.在 0.01mol/L NH_3·H_2O-0.01mol/LNH_4Cl-3.0×10~(-5)mol/L安息香缩氨基硫脲(BTSC)溶液中,钴(Ⅱ)和镍(Ⅱ)均产生非常灵敏的还原波,其峰电位分别是:-0.94和-0.75V(vs.SCE),峰电流与钴和镍的浓度分别在2.0×10~(-8)~1.0×10~(-6)和1.0×10~(-8)~8.0×10~(-7)mol/L范围内成直线关系,该方法用于测定水中痕量钴和镍,相对标准偏差分别为1.4~2.0%和2.1~2.5%,回收率分别在98.0%~101.8%和97.9%~102.1%之间.     

光电化学反应的催化 Ⅰ.大颗粒金岛对n-TiO_2电极上光电化学过程的催化作用

用溅射、光还原及电沉积法在n-TiO_2单晶电极表面上形成了大颗粒金岛.测量了这些电极和纯金电极在H_2SO_4溶液以及含有Fe~(3+)/Fe~(2+)的酸溶液中的光电化学极化行为.通过分析和比较这些曲线,确定了大颗粒金岛与n-TiO_2单晶的接触具有欧姆结性质.并借助于可换盘旋转环盘电极,在含Ce~(3+)的酸溶液中测量了裸TiO_2电极及载金的TiO_2电极上Ce~(3+)的竞争光电化学氧化.证实了以大岛形式在TiO_2电极表面上分布的催化剂只能催化暗反应,而不能催化光电化学反应.     

Cu-Zr-Ce-O催化剂上CO选择性氧化及再生研究

采用共沉淀法制备了一系列Cu-Zr-Ce-O复合氧化物催化剂，考察了ZrO2加入量、不同再生方法对催化剂CO选择性氧化反应性能的影响，并通过DSC-TPR、XRD和SEM手段对催化剂进行了表征。结果表明，添加ZrO2的Cu1Zr1Ce9Oδ催化剂在160 ℃～200 ℃，具有99％以上的CO转化率，并且催化剂的选择性相对较高。适量ZrO2的加入能够细化催化剂的颗粒，提高催化剂的热稳定性，改变催化剂的聚结方式。经氮气、氢气及氧气再生处理后的Cu1Zr1Ce9Oδ催化剂，催化活性有所不同，其中经氧气处理后的催化剂，表面吸附氧体积分数较高，活性恢复较好。