诺龙甲醇溶液标准物质的研制

利用色-质联用法和红外光谱法对诺龙纯品原料定性后,采用高效液相色谱多家定值方法对诺龙纯度进行定值,经重量法配制,制得了诺龙甲醇溶液标准物质,并对制备的溶液标准物质进行均匀性和稳定性检验.对定值不确定度进行了评定,当诺龙甲醇溶液标准物质的浓度为1.00 mg/mL时,相对扩展不确定度为1.0%,k=2.     

Development of afterglow time test system for nanosecond fluorescent screen of low-level-light image intensifier北大核心CSCD

The time characteristics of fluorescent screen is one of the important parameters to evaluate the performance of image intensifier. At present, there is no measurement method for the afterglow time of nanosecond fluorescent screen of low-level-light image intensifier. Based on the traditional test scheme of image intensifier afterglow time, a afterglow time test system for nanosecond fluorescent screen was developed. This system used a high-speed signal generator with the sampling rate of 250 MHz to complete the excitation of the laser diode light pulse, and a photomultiplier tube was used with the descending time of 0.57 ns to complete the photoelectric conversion of the fluorescent screen light signal. The weak photocurrent signal of μA magnitude was amplified and converted to a single-terminal differential circuit to complete the AD conversion in AD9684. Then the digital luminance information of the fluorescent screen was stored in the double data rate SDRAM (DDR) unit after field programmable gate array (FPGA), and the host computer sent instructions to read the DDR memory. The USB3.0 high-speed transmission protocol was used to transmit data to the host computer. In the data processing, the Kalman filtering and fast finding falling edge algorithm were used to realize the accurate measurement of noise filtering from collected data and afterglow time. The test results show that the proposed afterglow time test system for nanosecond fluorescent screen can effectively test the image intensifier with ultrafast optical characteristics. The afterglow test results of P47 phosphor reaches 118.094 4 ns, and the repeatability reaches 2.08%. © 2022 Editorial office of Journal of Applied Optics. All rights reserved.     

Effect of Al Doping on Properties of SiC Films

Undoped and Al-doped 3C-SiC films are deposited on Si（100） substrates by low-pressure chemical vapour deposition. Effects of aluminium incorporation on crystallinity, strain stress, surface morphology and growth rate of SiC films have been investigated. The x-ray diffraction patterns and rocking curves indicate that the crystallinity is improved with aluminium doping. Raman scatting patterns also demonstrate that the strain stress in SiC films is released due to the incorporation of Al ions and the increase of film thickness. Furthermore, due to the catalysis of surface reaction which is induced by trimethylaluminium, the growth rate is increased greatly and the growth process varies from three-dimensional island-growth mode to step-flow growth mode.     

Nd:YVO4复合腔激光器双波长激光输出及腔内和频研究

 采用两个重叠的共线支腔构成的三镜复合腔,实现LD泵浦的Nd:YVO₄激光器的1 064 nm和1 342 nm双波长激光运转。根据双波长振荡阈值相等条件,数值计算了1 064 nm支腔和1 342 nm支腔的腔长、支腔的输出耦合镜透过率之间的关系。合理选择两个支腔的参数,当泵浦功率13 W时,获得1 064 nm激光功率1.59 W,1 342 nm激光功率1.17 W的双波长激光输出。在满足腔内1 064 nm 和1 342 nm双波长光子数密度相等的条件下,计算了腔内和频的复合腔Nd:YVO4激光器的腔参数。采用Ⅱ类临界相位匹配KTP晶体作为和频器件,当808 nm泵浦光功率为12 W时,获得340 mW的和频593 nm激光输出。     

动力松弛法在应变软化类结构有限元静力分析中的应用

结构静力分析中常因材料应变软化使得相应定解问题失去适定性,从而导致有限元分析不收敛。为解决此问题,在已有的相关研究基础上,采用动力松弛法（DRM）求解结构非线性有限元静力分析的增量步,将其应用于损伤型本构所描述的结构软化问题。本文方法依据两个原理,其一是苏联《数学百科全书》论述的原理——定义于时间域的任何定解问题适定可解,其二是DRM所用的原理——质量系统静力解为相应动力解的稳态部分。且DRM无需进行隐式静力分析时的总体刚度矩阵组装和求逆计算。本文用加荷载增量求解静力平衡路径硬化段,用加位移增量求解极值点和软化段。数值试验表明,本文方法能完成应变软化类结构的静力平衡路径求解。     

磷酸钴修饰Cu3V2O8/ZnO光阳极的动力学特性及光电化学水分解研究

钒酸铜是一种新兴的应用前景广阔的光阳极材料.本工作首先制备了不同厚度的Cu₃V₂O₈光电极,通过强度调制光电流谱、电化学阻抗谱等手段深入探究了影响Cu₃V₂O₈光电性能的关键因素在于光生载流子扩散距离短造成的载流子体相复合严重以及缓慢的氧化动力学造成的表面复合严重.为解决该问题,本工作提出了将一维ZnO纳米棒阵列作为支撑骨架以及负载CoPi助催化剂的策略.一维ZnO纳米棒阵列可作为电子快速传输通道促进光生载流子的体相分离, CoPi助催化剂可提高光生载流子表面分离效率提升氧化动力学.     

羟基功能化3,4-聚2-芳基-1,3-丁二烯的合成

采用(C₁₃H₈CH₂CH₂(NCHCCHN)■)Lu(CH₂SiMe₃)₂ (1)、Ph₂P(=NDip)(NDip)Lu■(THF)(Dip=■)、Ph₂P(=NDip)(■)Lu(CH₂SiMe₃)₂(THF)(3)和Ph₂P(=NDip)(■)Sc(CH₂SiMe₃)₂(THF)(4) 4种稀土催化剂,催化2-对甲基苯基-1,3-丁二烯(2-MPBD)均聚合.通过核磁共振(NMR)、凝胶渗透色谱(GPC)和示差扫描量热法(DSC)等对聚合物的微观结构和热性能进行了表征.催化剂1对2-MPBD聚合活性低,3,4-选择性低(65.2%);催化剂2几乎无催化活性;催化剂3和4表现出非常高的催化活性(2 min转化率达100%)和3,4-选...     

大体积进样离子色谱法检测饮用水中六价铬

建立了离子色谱检测饮用水中的六价铬的分析方法。以AS23柱分离,20mmol／L NaOH为淋洗液,1．0mL／min流量,1mL大体积进样,电导检测。结果表明,方法检测限为0．8μg／L,水样加标回收率在96．0％-102．0％之间,相对标准偏差为4．09％-1．40％;与标准方法二苯碳酰二肼分光光度法结果比对表明,该法检测限低、操作简便、准确快捷,适用于饮用水中六价铬的检测。     

吸收性海水中气泡光散射特性的理论研究

 给出了一种适合于吸收性介质内粒子散射的Mie级数新的表示形式。利用Mie理论研究了吸收性海水中气泡的单散射特性和气泡群的相位函数。与非吸收性海水中气泡的光散射特性相比,分析了海水折射率虚部对气泡光散射的影响。结果表明：180°后向散射的增强是气泡固有的光学性质,与所处介质无关,可以利用后向散射的增强来探测气泡。     

双硫腙包覆钛酸锶钡粉体对水中镉的吸附性能

用草酸盐化学共沉淀法合成钛酸锶钡粉体,用双硫腙对该粉体表面进行包覆修饰,制成新型有机包覆吸附剂。用傅里叶变换红外光谱对包覆粉体进行了表征;以火焰原子吸收为检测手段,研究了该吸附剂对水中Cd2+ 的吸附性能,考察了洗脱条件;通过红外光谱,初步探讨了包覆和吸附作用机理。结果表明,双硫腙以氢键作用牢固地包覆于钛酸锶钡粉体上;该包覆粉体对水中的Cd2+具有较高的选择性吸附能力,其吸附量受介质的pH值影响,当pH值小于3时,该吸附剂对水中的Cd2+几乎不吸附,当pH值大于6时,吸附量达到最大;常温下,20 min内吸附达到平衡;吸附在双硫腙包覆钛酸锶钡粉体上的Cd2+,可用5% EDTA溶液完全洗脱。建立了吸附富集,火焰原子吸收法测定水中Cd2+的新方法,方法检出限为0.2 μg·L-1,相对标准偏差为2.9%。应用于自来水和地表水中Cd2+的测定,结果满意。