气相色谱-电子捕获检测器快速测定水产品中多种农药及兽药残留

称取2.000g样品,加入含0.2%(φ)甲酸的乙腈(85+15)溶液10mL,涡旋混合30s,振荡提取30min,以10 000r·min-1转速离心5min,取上清液。用2mL的含0.2%(φ)甲酸的乙腈(85+15)溶液活化Oasis PRiME HLB小柱后,将上述上清液全部通过Oasis PRiME HLB小柱并收集滤液,于50℃水浴下氮吹至干,加入100μL衍生化试剂[N,O-双(三甲基硅烷基)三氟乙酰胺-三甲基氯硅烷(质量比为99∶1)],涡旋10s,于65℃恒温反应30min后,于50℃水浴下氮吹至干,用正己烷定容至1.0mL,以DB-5/DB-35色谱柱(30m×0.25mm,0.25μm)分离11种拟除虫菊酯类农药和3种氯霉素类兽药,采用电子捕获检测器。11种农药的线性范围为0.10~0.80mg·L-1,3种兽药的线性范围为5.0~40mg·L-1,检出限(3S/N)在0.000 1~0.008 0μg·g-1之间。加标回收率为85.6%~119%,测定值的相对标准偏差(n=6)不大于9.0%。     

UPLC-MS/MS结合SPSS研究多种β_2-受体激动剂的萃取效率及快速检测方法

研究了液液萃取提取,超高效液相色谱-串联质谱(UPLC-MS/MS)测定水中14种β_2-受体激动剂的方法。通过单因素与正交试验研究水的pH、有机溶剂种类、振荡时间、萃取温度等因素对水中β_2-受体激动剂萃取效率的影响,用SPSS对数据进行分析。该方法 14种β_2-受体激动剂的检出限为0.03~0.2 ng/mL,添加回收率为62.8%~88.3%,RSD为3.4%~13%。方法可用于β_2-受体激动剂的多残留检测研究。     

On buckling of cantilever rectangular plates under symmetrical edge loading

The stability of cantilever rectangular plates under the symmetrical edge loading will be studied in this paper by lite varialional calculus. We are going to find out the minimum critical loading for cantilever rectangular plates subjected to various edge loadings symmetrically on a pair of opposite free edges. We’ll discuss the least critical loadings when the buckling of rectangular plates acted on bv a pair of concentrated forces, uniformly distributed loads, locally uniform distributed loads, distributed loads in the form of triangle and a pair of concentrated couples occur respectively.     

Lateral instability of rectangular plates

This paper investigates the problems of lateral buckling of rectangular plates. In the text we discuss the minimum critical load of the lateral buckling occurring on under a concentrated force, uniformly distributed load and the concentrated couples, respectively. The energy method is used in this article.     

闭合圆柱壳在冲击荷载下的动力计算

本文讨论闭合圆柱形壳体在冲击荷载作用下的动力计算.文中分析冲击过程各阶段的动量及能量的变化,并计入冲击物和被冲击的闭合圆柱壳系统质量的影响;用相当质量法将整个圆柱形壳体的分布质量转化为只有一个集中的“相当质量”,从而导出闭合圆柱形壳体在冲击力作用下的动力因数.本文的特点是具有实用价值,计算比较简便.     

镍, 锌, 钴(II)-N-(间甲苯基)亚氨基二乙酸-氮三乙酸的量热研究

使用改进的RD-1型热导式量热计测量了镍(II), 锌(II),钴(II)-N-(间甲苯基)亚氨基二乙酸-氮三乙酸三元配合物的生成焓, 发现其大小按金属离子来说符合Irving-William序列。利用配体的多环水化结构等讨论了该三元配合物的生成焓和相应的二元配合物的生成焓, 同时求得了上述三元体系的热力学参数, 指出上述三元体系的生成熵是导致这些三元体系具有较大稳定性的根本原因。     

The bending stability and vibrations of cantilever rectangular plates

This paper discusses the problems of the bending, stability and vibrations of cantilever rectangular plates by means of the variational method. In the text a good many calculating examples are illustrated.     

On several problems for lateral instability of cantilever plates

The present article researches several problems about the lateral instability, of cantilever plates by means of the energy method, in which we discuss the minimum critical load of cantilever rectangular plates under a concentrated force, a uniformly distributed load, a distributed load in triangular form and a concentrated couple, respectively, when the lateral buckling takes place.     

汽化热量热计的建立及物质汽化潜热的测定

在J.H.Mathews仪器的基础上进行适当改进,本文建立了一种等温绝热型汽化热量热计,经对甲醇、乙醇、苯、甲苯和水等物质的测定,精度可达0.1-0.2%,与文献值对比,准确度在0.3%以内,在纯物质测定的基础上,对水+乙醇、苯+甲醇两个二元物系进行了等压积分汽化潜热的测定,文中对采用“差分-积分图”方法反映汽化过程中体系的焓变作了一些探讨,另外,本文还就我国石油轻馏分汽化热的测定进行了初步的探索和研究。     

在无定形二氧化钛上生长纳米钛硅分子筛催化剂

尺寸在1～100nm之间的材料称为纳米材料.纳米材料中表面分子占很大比例,由此产生了不同于常规材料的各种特殊性能.纳米材料在很多领域得到广泛的研究和应用.很多研究者发现纳米结构的催化剂有着与常规催化剂不同的催化活性和选择性.沸石分子筛催化剂是一种结晶的多孔物质,其孔径一般小于1 nm.