三种重金属对鲤鱼幼鱼的毒性和积累

研究了铜、锌、镉三种重金属对鲤鱼幼鱼的毒性作用,以及铜和锌在鲤鱼幼鱼中的积累。结果表明三种重金属对鲤鱼幼鱼的毒性顺序为Cu>Cd>Zn,三种重金属对鲤鱼幼鱼的96h半致死浓度和安全浓度分别为Cu0.2mg/L,0.02mg/L;Zn7.05mg/L,0.7mg/L;Cd2.51mg/L,0.25mg/L。积累实验结果表明:铜和锌主要积累于鳃、肝脏和肾脏中,在肌肉和骨骼中有少量积累。积累程度随暴露时间的增加而增加,一定时间后达到动态平衡,随后有少量铜、锌转移或排出。     

铕(Ⅲ)-5-氟尿嘧啶-1-基乙酸-L-丝氨酸三元配合物的合成与性质

在乙醇介质60℃水浴加热的条件下,合成了铕(Ⅲ)-5-氟尿嘧啶-1-基乙酸(5-Fu-1-yl)-L-丝氨酸(L-ser)三元固体稀土配合物,对其进行了元素分析、络合滴定、摩尔电导、紫外光谱、红外光谱、荧光光谱和循环伏安等性质的测试,确定其化学组成为[Eu(Ⅲ)(5-Fu-1-yl)(L-ser)]C l3.2H2O,重点通过循环伏安测定此配合物在碳糊工作电极上的电化学行为,在HAc-NaAc缓冲溶液(pH≈6.5)中,[Eu(5-Fu-1-yl)(L-ser)]C l3.2H2O和EuC l3在(-0.2)~(-1.2)V(vs.SCE)电位均表现出电化学活性,稀土配合物的电化学活化中心是Eu3+,且配合物的还原峰电流与浓度和扫描速度的平方根呈现很好的线性关系,说明该体系为标准的可逆体系。     

离线k-服务器问题算法的改进

阐述了在k-服务器猜想的证明中改进经典的离线k-服务器问题算法的必要性,从而对经典算法进行了改进,设计了一种新算法,其复杂度由原来的O(m(nk)2)下降为O(mk2).     

Global Solution for Quasilinear Wave Equations with Viscosity and Nonlinear Perturbation

1 IntroductionIn this paper we study globaJ solutions to the initiaLboundary value prob1em for quasilinearwave equations with viscosity and a nonlinear perterbation of the fOrmwhere fl is a bounded domain in RN with smooth boundarY afl, and the norilineax termsa(vp), g(u) axe like a(vp) = (l + )vlP)--'/P(P > 1), g(u) =--ju1"u.This problem describes the motion of fixed membrane with strong viscosity. The globalexistence and stability Of smooth solutions fOr one space dimensional case N = 1…     

1,2,4,5-苯四甲酸根桥联镍(Ⅱ)与咪唑混配配位聚合物的合成与晶体结构

芳香多羧酸根阴离子作为一类多齿配位试剂能够在阴离子和阳离子之间形成一维,二维,和三维的无限连续^[1],从而通过这种方式构建链状,层状和网状结构的化合物^[2]。此类化合物不仅有独特的结构,而且有广泛的用途,从灭火剂,催化剂到分子磁体等都有文献报道^[3,4],因而成为近年来无机材料化学和配位化学研究的热点之一,1,2,4,5－苯四甲酸根阴离子（TCB）作为一种对称性芳香多羧酸根阴离子,已表现出很强的桥联能力和为顺磁金属离子提供磁交换路径的能力^[5],本文以TCB为桥联配体,以咪唑（Him)为协同配体,合成了一种镍（Ⅱ）配位聚合物{[Ni(Him)4][Ni(TCB)2/2(Him)2(H2O)2].6H2O}n,并表征了其结构。     

Crystal structure and fluorescence spectrum of the complex [Eu(Ⅲ)(TTA)_3(phen)]

The title complex Eu(Ⅲ)(TTA)3(phen) (where TTA= thenoyltrifluoroacetone monoanion; phen = 1,10-phenanthroline) has been synthesized in mixed solvents of acetone and ethanol (1:1 volume ratio) and its crystal structure has been determined by X-ray diffraction. The complex crystals are triclinic, space group P1(#2) with cell dimensions of a = 1.3241 (2) nm, 6 = 1.5278(4) nm, c = 0.9755(3) nm, α = 92.49 (2)°, β=102.57(2)°, γ = 91.62(2)°, V=1.9268(8) nm3, Z = 2, μ(Mo Kα) = 18.77 cm-1, Dx = 1.720 g/cm3. The coordination geometry of Eu atom is a distorted square antiprism, and the encapsulated structure that can meet the structural requirement of the typical europium luminescent sensor. The fluorescence spectrum suggests that the complex is a strong photoluminescent material.