不良导体导热系数的测量与探讨

根据利用物体散热速率求传热速率的实验思想,给出了橡胶盘导热系数的实验结果。并对散热速率做了分析,给出了一个修正方案。     

Characteristics of Flow around an Impulsively Rotating Square Cylinder via LB-DF/FD Method

Flow around an impulsively rotating square cylinder in a viscous fluid in range of 1 ≤ Re ≤ 300 is numerically investigated by the previously developed LB-DF/FD method, which combines the lattilce Boltzmann method （LBM） and direct-forcing fictitious domain （DF/FD） scheme. Results show that in total three kinds of transient characteristics depending on Re are observed： 1 ≤ Re ≤ 20, four vortices arising from the corners of the square cylinder separate from the surfaces and gradually become stable without vortex integration or shedding; 20 ≤ Re 〈 100, vortices integration is observed when they grow long enough, then separated from each other; Re ≥ 100, vortex shedding takes place in this regime. The shedding vortex joins the downstream vortex to form a new one. It is also found that vortex shedding happens more than one time when Re ≥ 160. Furthermore, each vortex shedding induces a fluctuation in the torque exerted on the cylinder.     

Chiral lateral optical force near plasmonic ring induced by Laguerre-Gaussian beam

Owing to the good adjustability and the strong near-field enhancement, surface plasmons are widely used in optical force trap, thus the optical force trap can achieve excellent performance. Here, we use the Laguerre-Gaussian beam and a plasmonic gold ring to separate enantiomers by the chiral optical force. Along with the radial optical force that traps the particles, there is also a chirality-sign-sensitive lateral force arising from the optical spin angular momentum, which is caused by the interaction between optical orbit angular momentum and gold ring structure. By selecting a specific incident wavelength, the strong angular scattering and non-chiral related azimuthal optical force can be suppressed. Thus the chiral related azimuthal optical force can induce an opposite orbital rotation of the trapped particles with chirality of different sign near the gold ring. This work proposes an effective approach for catchingand separating chiral enantiomers.     

弹体对超高性能混凝土侵彻深度的研究

为了评估超高性能混凝土（UHPC）的抗侵彻性能,对UHPC靶板进行了侵彻试验与数值模拟。首先,利用Φ35 mm火炮对抗压强度为160 MPa的UHPC靶板开展了216～345 m/s速度下的弹体侵彻试验,结果表明：随着弹体速度的增加,侵彻深度与开坑直径皆有明显增加。随后在数值模拟过程中,确立了UHPC的RHT材料模型参数,为了验证材料模型的有效性,采用单轴压缩与霍普金森压杆试验结果对三维有限元模型进行了验证,模拟结果与实验结果吻合良好,表明参数选取科学合理。最后,对弹体侵彻UHPC的过程进行数值模拟,参数化分析了UHPC抗压强度、弹体质量、侵彻速度、弹径、弹头形状对UHPC侵彻深度的影响,并据此推导出弹体对UHPC侵彻深度计算公式。     

烷烃同系物气相色谱保留指数的分子拓扑研究

定义了分子中原子的平衡电负性,并用原子的平衡电负性对分子图进行着色,在距离矩阵的基础上结合分子中各原子的支化度构建了一种新的拓扑指数N1,N2和N3。该拓扑指数对分子结构实现惟一性表征,具有优良的结构选择性。将拓扑指数N1,N2和N3与烷烃在固定相角鲨烷(柱温50　℃)及SE-30(柱温80　℃)上的气相色谱保留指数进行多元线性回归,结果表明烷烃的气相色谱保留指数可分别定量描述为I(Squalane)=23.97842N1-3.86562N2+0.787379N3+42.33061,I(SE-30)=23.83937N1-3.5687N2+0.939876N3+22.11952。用上述回归方程对烷烃的气相色谱保留指数进行预测,结果表明预测值与实验值的平均相对误差均为1.31%,预测结果误差在实验误差范围内。     

双颗粒沉降的动力学分析

采用格子Boltzmann-虚拟区域方法对雷诺数范围为50≤Re≤200的双颗粒自由沉降进行了直接数值模拟。首先,研究发现双颗粒最终沉降的位置分别在通道的1/4和3/4位置附近,且与颗粒的初始间距、雷诺数以及通道宽度无关。其次,重点研究了颗粒沉降过程中所受的侧向力(与沉降方向垂直),首次揭示了侧向力的振动频率与雷诺数呈二次关系,且单颗粒的结果始终小于双颗粒的结果;研究还发现侧向力的振动频率与通道宽度近似呈幂律函数关系,且幂律指数与雷诺数有关,雷诺数越大,幂律指数的绝对值越小。最后还研究了雷诺数及通道宽度对侧向力振动振幅的影响。     

两个基于4-(1H-1,2,4-三氮唑)苯甲酸的稀土配位聚合物的合成、晶体结构及荧光性质(英文)

以4-(1H-1,2,4-三氮唑)苯甲酸为配体,采用水热法合成了2种稀土配位聚合物[Tb(tbc3)(H2O)3]n(1)和{[Nd(tbc3)(H2O)3]·H2O}n(2)(Htbc=4-(1H-1,2,4-三氮唑)苯甲酸)。运用X-射线单晶衍射法对该配位聚合物进行了结构测定,并对其进行了元素分析、红外光谱、TG及荧光光谱表征。单晶结构表明,配位聚合物1为三斜晶系,空间群P1,配位聚合物2属于单斜晶系,空间群为P21/c。配位聚合物1和2均为一维链结构,均通过非共价键作用形成三维超分子构造。     

端视ICP-AES法测定地质试料中的痕量稀土元素

本文采用萃取柱色层分离技术,用P507富集稀土元素,端视ICP-AES法测定地质样品中十五个痕量稀土元素,测定30—500微克总量范围,检测限分别为0.01—0.5ppm精密度为0.93—7.4%回收率达90—106%。对地球化学标准参考样进行了分析,批量生产表明,流程快速,准确度好,一次摄谱可同时测定十五个稀土元素,是地质试料中测定痕量稀土元素的有效方法。仪器及工作条件GP3.5-D_1型高频发生器,阳流0.73     

用非相干光进行图像微分

为了压抑相干噪声,本文采用单色非相干线光源进行图像微分。微分滤波器是利用光栅结构的微分函数制作其傅里叶变换全息滤波器来实现的。实验结果表明,利用非相干光进行图像微分大大提高了输出图像的信噪比。