Sizable Residual Quasiparticle Density of States Induced by Impurity Scattering Effect in Ba（Fe1-xCox）2As2 Single Crystals

Low-temperature specific heat Cp is measured on Ba（Fe1-xCox）2As2 single crystals in a wide doping region. A sizeable residual specific heat coefficient γo is observed in the low temperature limit of all samples. The specific heat jump near Tc, i.e. ΔCp/T／T_c, is also determined. It is found that -γo, ΔCp/T／T_c and Tc all share a similar evolution with doping. These can be well understood within the model of S± pairing symmetry when accounting for the cobalt-dopants as unitary scattering centers in the FeAs planes. Our results reveal a non-trivial impact of impurity scattering in FeAs-based.     

求解约束优化问题的记忆梯度Goldstein-Lavintin-Polyak投影算法

给求解无约束规划问题的记忆梯度算法中的参数一个特殊取法,得到目标函数的记忆梯度G o ldste in-L av in tin-Po lyak投影下降方向,从而对凸约束的非线性规划问题构造了一个记忆梯度G o ldste in-L av in tin-Po lyak投影算法,并在一维精确步长搜索和去掉迭代点列有界的条件下,分析了算法的全局收敛性,得到了一些较为深刻的收敛性结果.同时给出了结合FR,PR,HS共轭梯度算法的记忆梯度G o ldste in-L av in tin-Po lyak投影算法,从而将经典共轭梯度算法推广用于求解凸约束的非线性规划问题.数值例子表明新算法比梯度投影算法有效.     

Effects of longitudinal parasitic modes on the beam dynamics for the ADS driving linac in China

For the accelerator driven subcritical system (ADS) main linac in China, two families of superconducting elliptical radio frequency (RF) cavities will be used to accelerate the proton beam from 180 MeV to 1.5 GeV. When the proton beam traverses in the RF cavity, the excited parasitic modes, like high order modes (HOMs) and same order modes (SOMs), may drive the beam to become unstable and increase the cryogenic load, thus putting a limitation on the normal operation of the accelerator. In this paper, by using a numerical code SMD based on the ROOT environment, the effects of longitudinal parasitic modes on the beam dynamics for the ADS driving linac in China have been investigated systematically, while parasitic modes which increase cryogenic loss have not been included in this paper. Some conclusions concerning the beam energy ranging from 180 MeV to 1.5 GeV have been obtained.     

平抛运动教学设计

教学对象：工科类中专生。教学地点：多媒体教室。教学辅助物：平抛竖落仪 磁铁铁 球多 媒体课件。     

从“路边苦李”到“反证法”

有一则小学生读物中的推理故事《路边苦李》,其文言表述如下: 王戎七岁,尝与诸儿游,看道边李树多子折枝,诸儿竞走取之,唯戎不动.人问之.答日:“树在道边而多子,此必苦李”.取之,信然.     

Photothermal-chemical synthesis of P-S-H ternary hydride at high pressures

The recent discovery of room temperature superconductivity (283 K) in carbonaceous sulfur hydride (C-S-H) has attracted much interest in ternary hydrogen rich materials. In this report, ternary hydride P-S-H was synthesized through a photothermal-chemical reaction from elemental sulfur (S), phosphorus (P) and molecular hydrogen (H₂) at high pressures and room temperature. Raman spectroscopy under pressure shows that H₂S and PH₃ compounds are synthesized after laser heating at 0.9 GPa, and a ternary van der Waals compound P-S-H is synthesized with further compression to 4.6 GPa. The P-S-H compound is probably a mixed alloy of PH₃ and (H₂S)₂H₂ with a guest-host structure similar to the C-S-H system. The ternary hydride can persist up to 35.6 GPa at least and shows two phase transitions at approximately 23.6 GPa and 32.8 GPa, respectively.     

室温快速合成Ag基金属有机骨架材料用于电催化还原CO2

选择具有强给电子能力的1,2,4-三唑为配体,成功合成了银基金属有机骨架材料(Ag-MOF)并用于电催化还原CO₂反应(CO₂RR)。借助粉末X射线衍射、透射电子显微镜、扫描电子显微镜、计时电流法等表征手段对材料的晶体结构、形貌和电催化CO₂RR性能进行了系统的研究。与商品化的纳米Ag颗粒对比,Ag-MOF展现出更优异的电催化CO₂RR产物选择性、催化活性和稳定性,在-0.9 V (vs RHE)时,CO的法拉第效率高达96.1%。当电压为-1.1 V (vs RHE)时,电流密度可达17 mA·cm^-2,且电极可以稳定运行300 min。这说明通过选择合适的配体结构,可以改变催化位点周围的化学环境,从而高效将CO₂转化为目标产物。     

硅烯的化学功能化

硅烯是一种零能隙的狄拉克费米子材料,对其能带结构的有效调控进而打开带隙是硅烯进一步器件化的基础.而化学功能化是调控二维材料的结构和电子性质的一种有效方法.本文简要介绍了近几年在硅烯的化学功能化方面取得的进展,主要包括硅烯的氢化、氧化、氯化以及其他几种可能的化学修饰方法.     

氢水化合物中氢键对称化和预压作用下氢行为

氢水化合物作为潜在的环境友好型储氢含能材料引起了众多关注。结合金刚石对顶砧装置和原位拉曼光谱测量、同步辐射X射线衍射光谱测量两种表征手段,试图深入理解高压驱动下氢的特征行为,寻找可能的高压富氢相。结果显示,目前已知最高含氢比例1∶1的相C2在压力24.5 GPa时发生相变,更多的氢分子特征峰随相变出现。通过对理论预测结构的拟合,该相最终被确定为P41,氢水比例达到2∶1,且在卸压时能够稳定保存至8.6 GPa。考虑到冰中氢键对称化对压致相变和结构稳定性的重要作用,着重观测了氢键的行为,首次探测到水分子之间氢键对称化过程中完整的费米共振现象。通过对O-H对称伸缩振动模式软化行为的拟合,最终确定氢键对称化发生在55 GPa,同时拉曼光谱测量显示有更进一步相变伴随发生。氢水化合物中不同氢团簇对化学预压作用表现出截然不同的应激反应,这在此体系中也是首次被注意到,对含氢体系和纯氢中氢的金属化研究具有一定参考作用。     

弹性约束边界条件下拉索结构横向振动特性分析

在拉索两端引入线性约束弹簧和扭转约束弹簧,通过对弹簧设置相应的刚度系数,得到弹性边界条件包括经典边界条件下的拉索横向振动模型.振动位移采用切比雪夫级数展开,使得横向位移在整个求解域内足够光滑.对不同边界条件下的拉索横向振动进行了研究,研究结果与参考结果的良好吻合验证了所构造模型的正确性;并进一步对线性约束弹簧刚度和扭转约束弹簧刚度对拉索横向振动特性的影响进行了分析.研究结果表明,边界条件对拉索振动固有频率的影响不可忽略.