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11.
The heteroleptic dmit complex [Et4N]2[Ni2(C2S4)(C3S5)2] has been prepared by the reaction of NiCl2.H2O with Na2dmit, NaSC2H4OH in the MeOH solution. The compound has been characterized by X-ray diffraction study, IR and UV-Vis spectroscopy. Crystallographic data : space group: P21/n, a=11.843(2), b=11.079(1), c = 15.404(1)(), β=110.33(1)°, V = 1895.1()3, Z=2, Dc=1.62 g/cm3, μ=17.6 cm-1, F(000)=956, R=0.052, Rw=0.061. In the structure of the title complex, the tto (tto=tetrathioxalato) ligand in bridging form is chelated to two nickel atoms and dmit (dmit=1,3-dithiole-2-thione-4,5-dithiolate) ligands coordinated to nickel atoms.  相似文献   
12.
A chiral salency complex,[Mn(Salency)(H2O)2](PF6)·2H2O 1(Salency =(R,R)-N,N'-bis(salicylidene)-1,2-cyclohexanediamine),has been prepared by the reaction of Mn(CH3COO)3·2H2O with Salency and NH4PF6,and was established by X-ray diffraction techniques.The complex crystallizes in triclinic,space group P1 with a=9.299(8),b=10.012(8),c=13.461(11),α=92.037(15),β=92.974(12),γ=93.530(18)°,V=1248.3(18)3,C20H28F6MnN2O6P,Mr = 592.35,Z=2,Dc=1.038 g/cm3,F(000)=608,μ=0.676 mm-1,the final R=0.0651 and wR=0.1880 for 5260 observed reflections with I 2σ(I).  相似文献   
13.
1 INTRODUCTION Transition-metal complexes supported by poly-dentate phosphine ligands have been widely studieddue to the unique photophysical properties andpotential applications as industrial catalysts, mole-cular sensors and drugs[1~3]. As known, oxidation ofphosphine ligands could happen in the synthesisreaction to result in novel complex with unexpectedstructure[4, 5]. For example, the structure of complexFe((OPPh2)2N)3[6] is an octahedral tris-chelate arrange-ment of the oxidized a…  相似文献   
14.
以二乙烯三胺为模板剂,通过溶剂热法制备了一种新型有机无机杂化锑硒化合物:[M1(C4H13N3)2]n[M2Sb2Se5]n(M1=Mn、Co,M2=Zn、Cd).相比传统的有机无机杂化锑硒化合物,过渡金属Zn和Cd参与了这种化合物主框架的构建,使化合物的主框架由传统的SbSex单元转变为Zn(Cd)SbSe5的配位单元.据我们所知,这是第一次合成出Zn和Cd参与SbSex骨架配位的有机无机杂化锑硒化合物.同时,由于结构中CdSe4和ZnSe4单元的存在,使得该化合物表现出荧光性质.这种化合物的出现,使得我们有可能通过相同的途径合成出一系列具有该类型结构特征,在发光领域有潜在应用前景的新型锑硒化合物.  相似文献   
15.
A new tetranuclear cyanide-bridged complex [PPh4]2[NiⅡ(CN)4CuⅠ(PPh3)2]2·2CH3OH ([PPh4]+ = tetraphenylphosphine cation, PPh3 = triphenylphosphine) 1 has been synthesized and characterized by IR spectroscopy, elemental analysis, electronic absorption spectra and single-crystal X-ray diffraction. This complex crystallizes in triclinic, space group Pí with a = 10.910(5), b = 15.777(7), c = 18.275(8), α = 68.752(12), β = 79.776(13), γ = 81.400(14)°, NiCuC65H50N4OP3, Mr = 1122.25, V = 2873(2)3 , Z = 2, Dc = 1.293 g/cm3, F(000) = 1156, μ = 0.826 mm-1, the final R = 0.0755 and wR = 0.2155 for 7324 observed reflections (I > 2σ(I)). The title compound exhibits a discrete square tetranuclear structure and a cubic order NLO property.  相似文献   
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