一种新型的蓝光发射材料δ-Alq3的制备与光谱分析

制备了一种新型的蓝光发射材料δ-Alq3,测试了其红外吸收光谱、X射线衍射谱、紫外-可见光吸收光谱、光致发光光谱和电致发光光谱,并通过与δ-Alq3的光谱性能的比较,研究了Alq3分子空间结构与光谱性能之间的关系.结果表明:δ-Alq3分子空间结构经过真空加热发生变化,生成对称性较差的δ-Alq3;分子空间结构的改变引起Alq3分子中酚环电子云密度的降低和相邻分子间的共轭效应的减弱,导致在紫外-可见吸收光谱中δ-Alq3长波段的π-π*电子跃迁吸收峰向短波方向的移动,在光致发光光谱中δ-Alq3的最大发射峰波长为480 nm,比α-Alq3的最大发射峰波长(515 nm)蓝移35 nm,在电致发光光谱中α-Alq3和δ-Alq3的最大发射峰波长都为520 nm.     

稳态和动态虚拟听觉重放对近场距离感知的影响*

虚拟听觉重放是研究距离感知的一种重要工具,它可分为传统的稳态虚拟听觉重放和动态虚拟听觉重放。然而,稳态虚拟听觉重放经常会产生头中定位而影响距离感知的判断,从而影响最终的实验结果。过去的实验大多采用稳态虚拟听觉重放,因此其结论也存在较大的争议性结论。本文对比研究稳态和动态的虚拟听觉重放对绝对距离感知效果的影响。实验采用非个性化HRTF进行双耳合成,将分布在水平面0.20 m至1.00 m的七个距离、0°至180°的七个方位角下的信号通过耳机进行虚拟重放。心理声学实验结果表明,在稳态虚拟听觉重放条件下,受试者不同程度地报告了存在头中定位。而动态虚拟听觉重放系统能够利用动态因素,从而产生头外化的听觉感知。统计分析表明动态虚拟听觉重放下的距离感知效果与稳态重放存在明显的差异。由于动态虚拟重放更接近真实声源的感知效果,应选用这种方法作为实验工具。同时,在实际的空间声应用中,也应该采用动态虚拟听觉重放产生不同的距离感知。     

Improved light extraction of organic light emitting diodes with a nanopillar pattering structure

We have investigated the properties of organic light emitting diodes(OLEDs)with a nanopillar patterning structure at organic–metal or organic–organic interfaces.The results demonstrate that the introduction of a nanopillar structure can improve the light extraction efficiency greatly.We also find that the number,height,and position of nanopillars all affect the light extraction of OLEDs.The maximum power efficiency of a device with an optimized nanopillar patterning mode can be improved to 2.47 times that of the reference device.This enhancement in light extraction originates from the improved injected carriers,the broadened charge recombination zone,and the intensified wave guiding effects.     

具有穿插界面结构的高效绿光有机电致磷光器件

以传统有机电致磷光器件ITO/NPB/CBP∶Ir(ppy)₃/BAlq/Alq₃/LiF/Al为研究对象,在NPB/CBP∶Ir(ppy)₃、CBP∶Ir(ppy)₃/BAlq及BAlq/Alq₃界面处构造交互穿插结构。器件的光电性能测试表明:交互穿插结构一方面能够降低电流密度,减少高电流密度下磷光猝灭中心的形成;另一方面能增加载流子复合界面面积,从而分散界面三线态激子,降低三线态-三线态激子的猝灭。此外,界面凸起的存在还有利于器件的光耦合输出。实验结果表明:当穿插厚度为10 nm,器件的最大电流效率达到34.0 cd/A,与传统器件的电流效率18.7 cd/A相比,提高了55%。     

Local Density of States Modulated by Strain in Marginally Twisted Bilayer Graphene

In marginally twisted bilayer graphene, the Moiré pattern consists of the maximized AB(BA) stacking regions,minimized AA stacking regions and triangular networks of domain walls. Here we realize the strain-modulated electronic structures of marginally twisted bilayer graphene by scanning tunneling microscopy/spectroscopy and density functional theory(DFT) calculations. The experimental data show four peaks near the Fermi energy at the AA regions. DFT calculations indicate that the two new peaks ...     

Three—Wave Resonant Interactions in Self—Defocusing Optical Media

A three-wave resonant interaction for nonlinear excitations created from a continuous-wave background is shownto be possible in an isotropic optical medium with a self-defocusing cubic nonlinearity. Under suitable phase-matching conditions the nonlinear envelope equations for the resonant interaction are derived by using a methodof multiple-scales. Some explicit three-wave solitary wave and lump solutions are discussed.     

Fibonacci光栅衍射频谱的自相似结构

本文设计并制作了一种按Ｆｉｂｏｎａｃｃｉ数列规则排列的准周期衍射光栅，从理论和实验两方面计算与显示了该光栅的自相似衍射频谱，这对准晶体光学中非周期的频率分析研究有一定的理论和实用价值。     

SOLITON EXCITATIONS INA DIATOMIC LATTICE WITH NONLINEAR ON-SITE POTENTIAL

We consider the soliton excitations in a diatomic chain with nonlinear on-site potential based on a quell-discreteness approximation, Different from the theoretical approach devel-oped before, our method is valid in the whole Brillouin zone of phonons. The gap solitons observed recently in a nonlinear diatomic pendulum lattice can be well explained qualita-tively. It is also shown that if the wave number of the carrier wave is near the edge of the Brillouin zone, the results coinside with that of Kivshar and Flytzanis about the gap solitons in diatomic lattices when the difference of mass between two kinds of atoms becomes small.     

(NH3CH2CHNH2CH3)2[WVIO2(OC6H4O)2]的合成、晶体结构及其与ATP相互作用的NMR性质研究

在室温下, 选用具有手性特征的1,2-丙二胺(1,2-propanediamine)为对阳离子, 由正四丁基铵十钨酸盐和邻苯二酚反应, 得到了钨酶活性结构因子仿生配合物(NH3CH2CHNH2CH3)2[WVIO2(OC6H4O)2], 用单晶X射线衍射测定了其晶体结构, 晶体属单斜晶系, 空间群为P21/n, a＝1.1099(3) nm, b＝1.0416(3) nm, c＝1.8874(6) nm, β＝96.492(6)°, V＝2.1679(11) nm3, z＝4, R1＝0.0445, wR2＝0.0682; 并对它进行了IR, 1H NMR和UV-Vis谱学表征. 利用NMR研究了其与三磷酸腺苷(ATP)的相互作用, 结果发现手性特征的1,2-丙二胺及邻苯二酚苯环的1H化学位移在与ATP混合前后均呈现出较大的差异, 分析得出: 配合物中的金属离子在D2O中大多数均以W(V)价态存在, 但在与ATP共存时转化为W(VI), 并与配体发生了解离.     

Landau Damping of Collective Modes in a Disc-Shaped Bose-Einstein Condensate

We investigate the Landau damping of collective modes in an anisotropic Bose Einstein condensate （BEC）, Based on divergence-free analytical solutions for the ground state wavefunction of the condensate and all eigenvalues and eigenfunctions for thermal excited quasiparticles, we make a detailed analytical calculation on coupling matrix elements. We evaluate the Landau damping of a quadrupole collective mode in the BEC with a disc-shaped trap and discuss its dependence on temperature and particle number of the system.