HPLC-MS-MS法测定水体中残留的氨基甲酸酯类农药

应用高效液相色谱-串联质谱(HPLC-MS-MS)联用技术,建立了检测水体中氨基甲酸酯类农药残留的方法。水样经氨基柱固相萃取,二氯甲烷洗脱,梯度流动相洗脱,电喷雾正离子(ESI+)模式采集、选择反应性监测模式(SRM)对定性、定量离子进行MS/MS测定。5种氨基甲酸酯类农药在5～200ng/L范围内线性关系良好,回收率为80%～92%,相对标准偏差均小于10%,方法检出限分别为:异丙威和仲丁威为1.4ng/L,克百威和甲萘威为1.5ng/L,恶虫威为1.6ng/L。该方法适用于水体中氨基甲酸酯类农药残留的检测。     

基于测试线法的风轮近尾迹辐射噪声研究

在风洞开口实验段,针对不同尖速比应用BSWA VS302USB振动噪声采集分析系统对水平轴风力机叶尖下游4个角度的测试线进行噪声测试.叶尖辐射声中的主要成分是叶片的旋转谐波声,其向风轮下游传播的过程中迅速衰减.在各测试线上,随着测点向风轮下游移动,叶轮辐射声迅速衰减,并在一定距离之后低于背景声,尖速比越高,风轮下游辐射...     

Influences of SiO2 laser-induced protective layers and damage threshold of annealing on the Ta2O5 films

Ta2O5 films are prepared on BK7 substrates with conventional electron beam evaporation deposition. The effects of SiO2 protective layers and annealing on the laser-induced damage threshold （LIDT） of the films are investigated. The results show that SiO2 protective layers exert little influence on the electric field intensity （EFI） distribution, microstructure and microdefect density but increase the absorption slightly. Annealing is effective on decreasing the microdefect density and the absorption of the films. Both SiO2 protective layers and annealing are beneficial to the damage resistance of the films and the latter is more effective to improve the LIDT. Moreover, the maximal LIDT of Ta2O5 films is achieved by the combination of SiO2 protective layers and annealing.     

贴壁风对脱硫反应器内液滴粘壁的影响

反应器内液滴粘壁对半干法烟气脱硫效率和运行稳定性具有重要影响.本文采用数值方法研究了不同贴壁风风速和风口高度对反应器内液滴粘壁现象的影响规律.结果表明,贴壁风对减轻液滴粘壁具有一定作用.贴壁风风速越高,液滴贴壁数量越少.贴壁风衰减较快,其风口高度存在最佳值,贴壁风风口与液滴喷射口的高度距离是按照液滴直线运动粘壁时液滴高度行程的1.2倍.     

应用PTV技术对颗粒碰撞规律的研究

为了研究稠密气固两相流中颗粒团聚的形成和破碎现象,本文提出了采用可获得颗粒运动学参数的可视化测量技术一PTV技术间接测量颗粒碰撞过程中的作用力的新思路和方法。在建立双球碰撞的运动学参数与动力学参数相互关系的数学模型基础上,设计了微球颗粒的碰撞实验并利用上述模型推演出了颗粒间作用力和碰撞能量损失等参数。     

求解对流扩散方程的高阶ICT-MMOCAA差分方法

本文利用文[1,2]中的FCT思想，对于对流扩散问题，提出了通过插值较正传输（ICT）的高阶ICT－MMOCAA差分格式，此格式避免了[3]中基于高次（≥2）Lagrange插值的MMOCAA差分格式在解的大梯度附近产生的振荡。本文给出了格式的误差估计及数值例子。     

求解对流扩散方程的ICT-MMOCAA差分解法

Combing the ideas of FCT^[1,2]with the MMOCAA^[3],the ICT-MMOCAA difference method,in which the transport is corrected by interpolation,is established for convection diffusion problem in the paper,The new method possesses the property of general FCT schemes and it is free from oscillation,with which the large gradient problem is solved by the MMOCAA difference method based on high-order(≥2)Lagrange interpolation^[3].Because the analysis in [3]is only suit for the scheme based on linear interpolation,the analysis method difered form [3] is used for obaining the error estimates of the new method.The numerical example is given in the paper.     

THE RESEARCHES OF GLACIER LAKE OUTBURST FLOODS OF THE YARKANT RIVER IN XINJIANG

The Jokulhlaup of the Yarkant River (Yarkant He) is usually csused by the sudden discharge of the glacier-dammed lake and the mode of the discharge is the rapid expansion of the subglacial channel. Keyajir (Kyagar) Glacier and Telamukanli Glacier are on the upper reaches of the Keleqin (Shaksgam) River, the chief birthplaces of this kind of flood. Up to the end of this century, since the global climate has become warmer, the glaciers have accordingly shrunk and become thinner, with the result that the size and dimensions of the glacier-dammed lakes and their outburst floods have diminished. All these simply reveal the mystery of the Jokulhlaups of the Yarkant River in Xinjiang.     

N'-(2-羟基-5-甲氧基苯甲基)-4-二甲氨基苯甲酰肼及其氧钒(Ⅴ)配合物:合成、晶体结构和脲酶抑制活性

制备了一个苯甲酰腙化合物N'-(2-羟基-5-甲氧基苯甲基)-4-二甲氨基苯甲酰肼(H₂L)。利用H₂L、乙酰氧肟酸(HAHA)和VO(acac)₂在甲醇中反应得到了配合物[VOL(AHA)]。通过元素分析、红外和紫外光谱,以及单晶X-射线衍射对H₂L和其配合物进行了表征。苯甲酰腙配体作为二价阴离子,利用其酚羟基氧原子、亚胺基氮原子、以及烯醇氧原子与V原子进行配位。乙酰氧肟酸配体利用其羰基氧原子和去质子化的羟基氧原子进行配位。配合物中的V原子为八面体配位构型。测试了H₂L、HAHA和钒配合物的脲酶抑制活性。在浓度为100μmol·L^-1时,钒配合物对幽门螺旋杆菌脲酶的抑制率为63%,其IC₅₀值为45μmol·L^-1。还利用分子对接技术研究了配合物分子与脲酶的作用方式。