高压下碱式聚苯胺的理论吸收谱

利用改进的Ginder-Epstein模型计算了碱式聚苯胺在参数V2,0不同取值下的自洽变分基态,结果表明芳环扭角和能隙随此参数的减小而缩减.据此,用这个参数的减小来表示垂直于主链方向加压,估算聚合物压强与芳环扭角的对应关系并对自洽变分基态作拟合,给出了V2.0与压强之间的经验公式.最后作出高压吸收谱:加压至饱和压强7.69 GPa时,π-π*吸收峰由2.17 eV蓝移至0.74 eV.此理论谱供压力定标参考.     

Yb:CaF2–YF3 transparent ceramics ultrafast laser at dual gain lines

Yb³⁺:CaF₂-YF₃ transparent ceramics with excellent optical quality was successfully fabricated by hot-pressed method. Pulsed laser properties of this ceramics were investigated for the first time. Laser diode (LD) was applied as the pump source to generate a dual-wavelength mode-locked (ML) laser. The maximum average output power was 310 mW, which represents the highest output power of ultrafast calcium fluoride ceramic laser. The spectrum separated at 1048.9 nm and 1049.7 nm with a total pulse duration of 8.9 ps. The interval period between the beating signals was about 4.3 ps, corresponding to a 0.23 THz beat pulse repetition rate. These results demonstrate its potential in producing dual-wavelength ultrashort pulses. These Yb³⁺:CaF₂-YF₃ ceramics with low-cost and short-preparation period are ideal candidate materials for ultrafast lasers.     

手征介质与陈绝缘体界面附近原子的自发辐射研究

对手征特异材料介质与陈绝缘体材料界面附近二能级原子的自发辐射特性进行了研究.推导计算了手征介质界面及其与陈绝缘体材料界面的反射系数矩阵,并根据并矢格林函数求得此环境下二能级原子自发衰减率的表达式.对手征介质和陈绝缘体材料特性参数影响下的原子自发辐射进行了数值计算,分别对平行和垂直于界面的偶极子自发衰减率进行讨论,并对辐射模式和消逝模式下的自发辐射进行了分析.结果表明,由于手征参量的存在,手征介质界面附近的原子自发衰减率与普通介质相比被增强.陈绝缘体则使得界面附近原子的自发辐射被明显抑制,且当手征参量较大时,陈绝缘体的抑制效应更加显著.     

Strategy to mitigate single event upset in 14-nm CMOS bulk FinFET technology

Three-dimensional (3D) TCAD simulations demonstrate that reducing the distance between the well boundary and N-channel metal-oxide semiconductor (NMOS) transistor or P-channel metal-oxide semiconductor (PMOS) transistor can mitigate the cross section of single event upset (SEU) in 14-nm complementary metal-oxide semiconductor (CMOS) bulk FinFET technology. The competition of charge collection between well boundary and sensitive nodes, the enhanced restoring currents and the change of bipolar effect are responsible for the decrease of SEU cross section. Unlike dual-interlock cell (DICE) design, this approach is more effective under heavy ion irradiation of higher LET, in the presence of enough taps to ensure the rapid recovery of well potential. Besides, the feasibility of this method and its effectiveness with feature size scaling down are discussed.     

Construction and application of carbon nanotube/polypyrrole-based bacterial surface imprinted sensorEI北大核心CSCD

A simple and fast "non-hole" bacteria surface imprinted (SPBIP) impedance sensor was constructed for ultrasensitive detection of Salmonella. The SPBIP sensor was prepared by one step electropolymerization of pyrrole (functional monomer), single-walled carbon nanotube (SWNT, nano-modulator), and Salmonella(template) onto a glassy carbon electrode. After removing the bacterial template, "non-hole" imprinted sites were formed on the surface of the polymer matrix, allowing the target bacteria to be specifically recognized. The resulting changes in the electrode surface impedance could be used to detect the target bacteria. The effects of the amount of SWNT, polymerization cycles, eluents, elution time and recognition time on the recognition ability of the sensor were investigated. Under the optimal conditions, the sensor could be used to detect 10~1×107 CFU/mLSalmonella with the limit of detection of 3.5 CFU/mL. The sensor could be used for the detection of salmonella in drinking water and orange juice samples with the recoveries ranging from 95.4% to 109.5%. © 2023, Youke Publishing Co.,Ltd. All rights reserved.     

环氧树脂中磷系阻燃剂协效体系的研究进展

近年来,出于环保等方面的考虑,一些卤系阻燃剂被逐渐淘汰,磷系阻燃剂作为卤系阻燃剂的替代品备受关注。然而,高效的磷系阻燃剂通常会在提高阻燃性能的同时产生更多的烟雾,因此需要与协效剂搭配使用。本文介绍了磷系阻燃剂在环氧树脂中的阻燃机理,综述了环氧树脂中磷系阻燃剂的协效体系的研究进展,包括无机协效剂、有机协效剂及有机-无机杂化协效剂等,并对环氧树脂体系中磷系阻燃剂的协效体系的未来发展趋势进行了展望。     

催化光度法时间程序测定土壤中痕量碘

碘是评价环境的重要元素之一,是地球化学勘察样品常测元素。本实验建立了艾斯卡试剂分解-热水提取样品,催化分光光度法时间程序测定碘的方法。详细讨论了艾斯卡试剂手工制作与行星球磨机制作的利弊;;参比液的选择;17℃-25℃不同环境温度条件对实验结果的影响;全程序空白溶液,与36g/L的碳酸钠溶液两种方法制作标准曲线及标准曲线线性范围;样品烧结时间及温度;乙酸用量对样品测试吸光度的影响。结果表明：利用行星球磨机制作艾斯卡试剂,选择试剂空白为参比液,在19℃的恒温环境下,采用36g/L的碳酸钠溶液制作0-8ug/mL标准曲线,样品采用0-300℃、300-500℃、500-750℃三阶段升温,750℃保持30min的烧结程序,乙酸用量为5mL时可以得到可靠的结果。该方法克服了艾斯卡试剂制作困难、样品烧结结块及实验反应速率过快等困难。通过方法学考察表明：基于所建方法碘元素校准曲线系数＞0.999;方法检出限为0.2 mg/kg;测定GSS36、GSS37、GSS38、GSS40、GSS47、GSS48、GSS49等9种国家一级标准物质,结果均在参考值范围内,相对标准偏差RSD＜5%。该方法测定的结果准确度及精密度高、 检出限低、减少碘记忆效应的存在,适用于地球化学勘察土壤样品中碘的测定。     

神光Ⅲ主机装置首次间接驱动内爆集成实验

基于新建成的神光Ⅲ主机装置开展了首次激光间接驱动内爆集成实验。国内首次采用多环脉冲整形激光注入黑腔产生X光辐射驱动内爆,通过优化激光打靶参数控制驱动不对称性,演示了以惯性压缩为主、收缩比约15倍的DT靶丸内爆实验能力, 实现了准一维的高静产额(YOC)和高中子产额的物理指标;其中,真空黑腔DT靶丸最高中子产额为1.91012,YOC达到60%;充气黑腔DT靶丸最高中子产额为2.41012,YOC大约70%。该实验为未来开展多台阶整形辐射驱动、更高倍数收缩比的高压缩内爆综合实验、验证点火靶物理设计和关键调控措施有效性奠定了基础。     

荷能离子在C60薄膜中引起的辐照效应

用 Raman散射和 XPS技术分析了能量为几百 ke V到几百 Me V的多种离子在 C60 薄膜中引起的辐照效应.分析结果表明 ,在低能重离子辐照的 C60 薄膜中 ,其晶态向非晶态的转变过程是由核碰撞主导的.在快离子 (1 2 0 ke V的 H离子和171.2 Me V的 S离子 )辐照的情况下,电子能损起主导作用.发现在H离子辐照过程中,电子能损有明显的退火效应 ,致使 C60 由晶态向非晶态转变的过程中,经历了一个石墨化的中间过程;而在 S离子辐照的情况下 ,电子能损的破坏作用超过了退火效应 ,因此 ,在C₆₀ 由晶态向非晶态转变的过程中,无石墨化的中间过程.Irradiation effecs (mainly including transformation from crystalline into amorphous state) of C 60 films induced by 120 keV H, He, N, Ar, Fe and Mo ions, 240 keV and 360 keV Ar ions, and 171.2 MeV, 125.3 MeV and 75.8 MeV S ions were analysed by means of Raman scattering and XPS technique. The analysis results indicate that amorphization process in the cases of N, Ar, Fe and Mo ions irradiation is dominated by nuclear collision, but in the case of H ion irradiation, the process is...     

固体表面能色散成分的测定

Tamai, Hamilton, Carre等曾通过测量烷烃-水双液参照体系在固体表面的接触角,采用基于界面非色散成份的均方关系, 计算了高表面能固体的表面能色散成份(γs^d)及非色散成份(γs^p), 对此计算方法, Fowkes曾给予批评, 提出界面能的非色散成份主要来源于酸碱配位作用, 基于非色散成份均方关系的计算不能正确反映实际情况, 本研究改进了由双液法接触角值计算γs^d值的方法。