对氯偶氮氯膦与铝显色反应的研究及应用

3-(4-氯苯偶氮)-6-(4-氯-2-瞵酸基苯偶氮)-4.5-二羟基-2.7-萘二磺酸,简称对氯偶氮氯膦(CPA-PCl),是近年新合成的一种不对称变色酸双偶氮衍生物:利用该试剂光度特性测定钪、钇、铋、镱已有报道,本文研究了该试剂与铝显色反应的条件及配合物的吸光光度性质。发现在微酸性介质中,试剂与铝可以形成2:1的蓝色配合物,显色迅速,色泽稳定,配合     

光通过LiKSO_4单晶产生的衍射现象

观察光通过LiKSO_4单晶产生的衍射图像随温度的变化,结合偏光显微镜的观察,确定文献观察到的衍射现象是晶体内左右旋孪生畴排列成空间光栅状结构引起的,衍射图案在435℃、673℃、-71℃和-84℃发生突然变化,这是由于在相应温度处发生结构相变。     

CO 在 Ni/TiO_2、Ni/Nb_2O_5和 Ni/Al_2O_3催化剂上的氢化反应

镍对一氧化碳加氢反应的催化活性与选择性的影响往往因载体不同而异,据不少文献报道,这是由于金属镍与载体间的相互作用不同所致。本文探索负载型催化剂的镍晶粒大小、催化活性和产品分布与载体本身可还原性的关系。文献指出,载体TiO_2与Nb_2O_5中金属组分经氢气还原处理后其价数会降低,然而Al_2O_3则不能,因此本文选用TiO_2和Nb_2O_5作为可还原性载体,而Al_2O_3作为非还原性载体。另外,为阐明催化剂晶粒大小与反应活性的关系,测定了反应条件下的镍晶粒的变化。     

双变量部分theta函数的乘积公式与性质

本文研究一类新的双变量部分theta函数,它是经典部分theta函数的推广,主要围绕这类函数的乘积公式、递推关系、级数展开等性质展开讨论.作为主要结果,我们建立了任意两个双变量部分theta函数的乘积公式,推广了Andrews-Warnaar经典部分theta函数的乘积公式,发现了双变量部分theta函数所满足的二阶递...     

掺铒光纤环形激光器混沌带宽特性数值研究

利用掺铒光纤环形激光器非线性克尔效应模型,研究抽运功率和非线性系数对激光器输出混沌信号带宽的影响.研究表明：在非线性系数一定的情况下,混沌带宽随着抽运功率的增加先增大后减小;固定抽运功率为01 W,当非线性系数增加到45 W^-1km^-1时,掺铒光纤激光器输出的混沌带宽达到最大值（153 GHz）,非线性系数继续增加,输出混沌的带宽将逐渐减小. 关键词： 克尔效应 掺铒光纤激光器 混沌 带宽     

Chaotic dynamics of active optical fiber ring resonator with optical injection

We experimentally obtain the route from period doubling to chaos in an active optical fiber ring resonator （AOFRR） with optical injection. The results show that the AOFRR is sensitive to external optical injection and demonstrate various dynamic characteristics. Meanwhile, the change of the injection strength can cause the output of the AOFRR to become periodic or chaotic. It can be confirmed that all the dynamic characteristics of the system are due to the interaction of the semiconductor laser with the erbium-doped fiber amplifier （EDFA）.     

税收优惠、研发投入与企业绩效——基于中介效应的实证研究

基于"税收优惠-行为-经济后果"的研究范式,利用2012-2016年191家高新技术企业上市公司的面板数据,以研发投入为中介变量,研究税收优惠对企业绩效的影响关系,并探索研发投入的中介效应.实证结果显示:税收优惠对企业绩效和研发投入均产生显著正向影响;企业研发投入在税收优惠与企业绩效之间具有部分中介效应.因此,高新技术企业应当有效利用税收优惠政策,增大研发力度以提升绩效水平.     

关于合成矩阵的几个性质

利用合成矩阵的概念和翻转矩阵的技巧,结合矩阵的次转置、次自共轭,中心对称等相关情况给出合成矩阵的几个性质,并获得关于n阶翻转矩阵的第n-1个合成矩阵的表达式.     

DFT Study of Oxygenated Organic Pollutants Catalyzed by Molybdenum Oxides: Comparison of Reaction Mechanisms of MoO_x + HCHO(x = 1, 2, 3)

The reaction mechanisms between formaldehyde and MoO_x(x = 1, 2, 3) have been studied thoroughly in this paper. Five reaction pathways were found in three reactions(reactions Ⅰ to Ⅲ) through studying the mechanisms of MoO_x(x = 1, 2, 3) catalyzing formaldehyde. Different products were obtained from three reactions. Of all three reactions, the barrier energy of Route ⅡA is the lowest(4.70 kcal/mol), which means in MoO_x(x = 1, 2, 3), MoO_2 has the best catalytic effect. Compared with other similar non-toxic treatments of formaldehyde, our barrier energy is the lowest. In this research, there was no good leaving group of the compound, so the mechanisms are addition reaction. We speculate that there must be an addition reaction to the more complex reactions to molybdenum oxides and aldehydes. As a chemical reagent for removing formaldehyde, it only absorbs formaldehyde and does not emit other toxic substances outward. Molybdenum oxides retain its original structures of the final products, which means it has excellent stability in the reaction of MoO_x(x = 1, 2, 3) + HCHO. The mechanisms of all three reactions are addition reactions, but they are entirely different. As the number of oxygen atoms increases, the reaction mechanisms become simpler.     

高效液相色谱-串联质谱法同时测定儿童彩泥类造型玩具中3种异噻唑啉酮类防腐剂

建立了儿童彩泥类造型玩具中异噻唑啉酮类防腐剂(2-甲基-4-异噻唑啉-3-酮(MI)、5-氯-2-甲基-4-异噻唑啉-3-酮(CMI)和1,2-苯并异噻唑啉-3-酮(BIT))的高效液相色谱-串联质谱(HPLC-MS/MS)测定方法。样品经甲醇超声提取、离心、过滤后,采用Kinetex?C_(18)色谱柱(100 mm×3 mm,2.6μm)进行分离,流动相为甲醇-水,梯度洗脱,流速300μL/min。在多反应监测(MRM)模式下定性,外标法定量。结果表明,3种异噻唑啉酮类防腐剂在1.0～100.0μg/L质量浓度范围内线性关系良好(r≥0.999 0),3种化合物的平均回收率为80.2%～109%,相对标准偏差(RSD,n=5)为1.3%～7.0%。MI、CMI和BIT的检出限(LOD)分别为10、10、20μg/kg,定量下限(LOQ)分别为30、30、60μg/kg。