水溶性磺酸钠苯基卟啉及其金属配合物共价与非共价修饰多壁碳纳米管的研究

合成了meso-四(4-磺酸钠苯基)卟啉及其Zn, Cu, Mn配合物, 通过共价与非共价的方法将其分别修饰到多壁碳纳米管上. 采用红外光谱对产物结构进行表征|通过透射电镜(TEM)考察了卟啉-多壁碳纳米管复合物的形貌特征|通过紫外光谱、荧光光谱对比分析了两类复合物, 发现在卟啉与多壁碳纳米管之间存在较强的电子效应, 同时发现非共价修饰的卟啉-碳纳米管复合物的荧光淬灭率更高|热重分析(TGA)表明非共价的卟啉-碳纳米管复合物中卟啉的含量比较高. 对修饰后的复合物进行了溶解性测试, 结果表明共价修饰的复合物在水中有较好的溶解性和分散性.     

基于虚拟仪器构建新型物理虚实结合教学模式

基于当前社会发展以及教育应用型和职业化的特点,物理教学应侧重于提高学生创新能力和动手能力,其中,将物理理论教学和实验教学相结合可作为途径之一.以此思路为基础,文章融合现代仪器技术和计算机技术,在调整物理理论和实验课程设置的基础上,以虚拟仿真实验为纽带,将物理理论教学与实验教学无缝衔接在一起,加深学生对物理原理及适用范围...     

Syntheses,Crystal Structures and Characterization of Two Coordination Polymers Based on Mixed Ligands

Two new coordination polymers,namely,{[Cd_(1.5)(bc)_2(HL)](13)H_2O}_(2n)(1) and [Mn(ip)(H_2L)(H_2O)]_n(2)(H_2L = 3-(1 H-pyrazol-4-yl)-5-(pyridin-2-yl)-1,2,4-triazole,Hbc = benzoic acid,H_2 ip = isophthalic acid) were constructed by solvothermal reaction.The compounds were characterized by elemental analysis,FT-IR spectroscopy,and single-crystal X-ray diffraction.Compound 1 displays a two-dimensional plane structure consisting of [Cd_3(bc)_2(HL)] subunits.Compound 2 possesses a one-dimensional chain structure and is further extended into a 3-D supramolecular architecture via hydrogen bonds.Moreover,photoluminescence studies showed compound 1 exhibits luminescent emissions with emission maxima at 375 nm.Magnetic susceptibility measurements of 2 indicate that domain antiferromagnetic interactions exist between Mn(Ⅱ) ions.In addition,thermogravimetric properties of 1 and 2 were also measured.     

中蒙边界区新发现的特大型推覆构造及伸展变质核杂岩

本文论述了内蒙古自治区海西-印支造山带内发现一特大型推覆构造和伸展变质核杂岩,两构造的时代均为中生代,但前者较早,推覆体走向近东西,中元古界白云岩自北向南推覆在寒武至三叠系地层上,直观推覆距70km,推测断距140km以上,变质核杂岩主要由糜棱岩组成,在推覆体范围内构成一北东向穹窿背斜并构成伸展拆离断层的下盘,糜棱岩面理平缓,拉伸线理总体向南南东倾伏,剪切指向标志表明为正断式运动,造山后推覆与伸展构造的共存提出一个重要的构造动力学问题。     

从数学发生发展的视角解读教材及其教学实践

以矩阵概念的发生发展为例,说明了从数学发生发展的视角解读教材的方法和作用.从解读教材中可以获得教育教学上的见解,用之于课堂教学,可以发展教师的教学能力,促进大学数学教育的发展.     

两均匀分布总体参数之比的估计

给出了两均匀分布的最大次序统计量的密度函数,并讨论了两均匀分布参数之比的通常区间估计、最短区间估计及假设检验方法.最后,根据实例求出了这两种区间估计及其区间长度,并得出了相应的结论.     

AN ENORMOUS THRUST NAPPE AND EXTENSIONAL METAMORPHIC CORE COMPLEX NEWLY DISCOVERED IN SINO-MONGOLIAN BOUNDARY AREA

An enormous thrust nappe and a metamorphic core complex of extensional origin have been recently discovered within the Hercynian-Indosinian orogen of Inner Mongolia. Both features are of the Mesozoic age, but the former is older. The thrust nappe strikes WNW-ESE and Proterozoic dolomite was thrust southwards atop strata ranging from the Cambrian to the Triassic in age. The visible displacement of the thrust is ca. 70 km and the deduced one is over 140 km. The metamorphic core complex (mainly mylonites) extends in an N-E direction, forming itself into a dome geometry and lying under an extensional detachment fault. The mylonitic foliation dips gently and the stretching mineral lineation, as a whole, plunges SSE. Various shear sense markers show a normal-sense shear movement. Some significant problems atise from the coexistence of nappe and extensional structures at a postoro-genic stage.     

A Cu(II) Complex with IM-MeImz-κ~2 N,O Mode in [Cu(IM-MeImz)_2]·(SCN)_2: Synthesis, Crystal Structure and Magnetic Properties

A new copper(II) compound with imino nitroxide radicals [Cu(IM-MeImz)2]?(SCN)2 (IM-meImz =2-(5-methylimidazol-4-yl)-4,4,5,5-tetramethyl-2-imidazoline-1-oxyl) has been synthesized and characterized structurally and magnetically. It crystallizes in monoclinic, space group P21/c with a = 9.3604(7), b = 10.3012(7), c = 16.6684(12) , β = 105.0290(10)o, V = 1552.25(19) 3, C24H34CuN10O2S2, Mr = 622.27, Z = 2, Dc = 1.331 g/cm3, μ(MoKα) = 0.876 mm-1, F(000) = 650, the final R = 0.0374 and wR = 0.1079. X-ray analysis demonstrates that the IM-MeImz ligand is coordinated to the copper(II) ion as an unusual didentate chelate with a κ2 N(MeImz),O(IM) mode in the complex. The square-planar coordination sites at Cu(II) are occupied by two O and two N atoms from the imino nitroxide radicals. The complex molecules are connected as a onedimensional polymer structure by intermolecular interactions. Magnetic measurements show that there are intramolecular antiferromagnetic interactions between the Cu(II) ion and radicals.     

Yb-C_(60)插入化合物的拉曼光谱研究

本文主要对 Ybx C6 0 插入化合物在室温下的拉曼散射的实验结果进行了分析和讨论。名义组分为 Yb3C6 0 的化合物是超导相 ,可观测到由电 -声子相互作用引起的拉曼谱线展宽。高Yb组分的 Ybx- C6 0 ( x≥ 4)的拉曼谱线的展宽则更为严重 ,这表明 C6 0 分子已发生了严重的畸变。当 Ybx C6 0 样品暴露于空气中时 ,虽然该样品已变成了非晶态 ,但 C6 0 分子的畸变已大大的减小了。     

A Novel Complex of Na（I）-Nitronyl Nitroxide [Na（NIT- 1＇-MeBzIm）3]ClO4： Synthesis and Crystal Structure

A novel complex [Na（NIT-1＇-MeBzIm）3]ClO4 （NIT-1＇-MeBzIm = 2-{2＇-[（1＇- methyl）benzimidazolyl]}-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide） has been prepared and structurally characterized by elemental analysis, IR spectra and X-ray diffraction methods. The title complex crystallizes in trigonal, space group P3 and Z = 2. Crystal data： C45H57ClN12NaO10, Mr = 984.47, a = 13.9411（8）, b = 13.9411（8）, c = 14.8622（16） A, γ= 120°, V= 2501.5（3） A^3, Dc = 1.307 g/cm^3, μ（MoKα） = 0.152 mm^-1, F（000） = 1038, R = 0.0637 and wR = 0.1813 for 1957 observed reflections with I 〉 2σ（I）. X-ray analysis reveals that the Na（I） ion is six-coordinated with three NIT-1＇-MeBzlm radicals. As we know, three radicals coordinating to the Na（I） ion in the main group by a chelate way is the first example. The Na（I） ion resides in a distorted octahedron with a facial configuration. Meanwhile, the intermolecular weak interactions result in a 2-D double layer conformation where the uncoordinated perchlorate anions are inserted in the packing space and take part in the H-bond interactions, and each complex is connected with six neighboring complexes and three perchlorate anions.