有机分子系统中反饱和吸收向饱和吸收转化的条件

由多能级稳态速率方程导出反饱和喟收向饱少吸收转化的能级参数条件和阈值光强，并与动态理论导出的结果作了比较，讨论了阈值光强在光限幅材料设计中的应用。     

Measurement of Ultrashort Laser Pulse Width in a Wide Spectrum Range Using Dimethyl Sulfoxide by Optical Kerr Effect Technique

We illustrate that applying the optical Kerr effect technique to dimethyl sulfoxide （DMSO） can determine the width of laser pulses in a wide spectrum range that is transparent. Different from many other simple molecular liquids, such CS2, and toluene, DMSO responds to both 130 fs 800 nm laser pulses and 248 fs 400 nm laser pulses with electronic motions only. Therefore, the observed signal as a function of time reflects the temporal distribution of the intensity. We verify our illustration by both the autocorrelation technique and spectra analysis.     

EXCITED-STATE NONLINEAR ABSORPTION AND ITS APPLICATION IN PHOTONIC TECHNOLOGY

The main achievements in our research on the physical phenomena of the excited-state nonlinear absorption in a molecular system and its applications in photonic technology are described. In the first part of this paper, some energy-level models and rate-equations are used to explain various mechanisms of the excited-state nonlinear absorption under differ-ent conditions, such as reverse saturable absorption caused by the triplet and/or the singlet excited-state absorption; saturable absorption due to the first and/or the second singlet excited-state absorption; and the excited-state nonlinear absorption induced by two-photon absorption. The experimental results for metal-organic and C₆₀ materials irradiated by ps and ns laser pulses are consistent with the simulated curves of the transmittance versus flu-ences. In the second part, the applications of excited-state nonlinear absorption in photonic techniques including optical bistability, optical switching, optical limiting, optical modula-tion, optical logic and optical storage are introduced. The working principles of the photonic devices based on the excited-state nonlinear absorption are presented. The experimental characteristic curves are found in good agreement with the theoretical simulations for these devices.     

酞菁铜染料的反饱和吸收动力学

本文用速率方程研究了酞菁铜染料氯仿溶液的反饱和吸收的动力学过程,并用YAG倍频调Q脉冲激光入射该样品,验证了理论.通过理论曲线与实验结果的拟合,估算出酞菁铜三重态激发态的吸收截面为2.6×10~(-17)cm~2.     

基于激发态非线性折射效应的全光开关与光限幅

提出一种新型的光控光开关,以532nm脉冲激光入射金属-类卟啉有机材料,强激发态吸收导致瞬态透镜效应,使同时通过介质的632.8nm激光实现光开关,实验演示了开关特性,开启和关闭时间均为100ns.还演示了激发态吸收和非线性折射两种效应共同作用的单光束光限幅.对上述两种基于非线性折射效应的器件特性进行了理论分析.     

Transformation of Sign of Nonlinear Refraction between Mo（W）/S/Cu Planar Metal Clusters

Optical nonlinear refractive properties of a series of Mo（W）/S/Cu planar square clusters are investigated using the Z-scan technique with the ns laser pulses at the wavelength of 532 nm. The result shows that the planar metal clusters containing the halogen ligands demonstrate the self-focusing effect, and the other planar metal dusters demonstrate the self-defocusing effect. These facts indicate that the halogen ligands can act as crucial factors in determining the sign of the nonlinear refraction of the Mo（W）/S/Cu planar metal clusters. The analysis of the experimental data shows that the planar clusters with halogen ligands possess greater refraction volume of the excited state than that of the ground state, while the other planar clusters possess the smaller refraction volume of the excited state than that of the ground state.     

阳离子型聚氨酯泡沫载体的制备及对活性污泥的吸附性能

通过在聚氨酯泡沫塑料制备过程中加入不同用量的N-甲基二乙醇胺(简称N-MDA),并对聚氨酯泡沫进行酸化处理,得到了一系列阳离子型聚氨酯泡沫塑料(简称改性PUF),并对其结构和性能进行了研究.结果表明,以醋酸和磷酸(质量比为1∶1)作为N-MDA的催化抑制剂,可在较宽N-MDA用量范围内顺利合成改性PUF.随着N-MDA用量的增加,改性PUF的回弹率、拉伸强度及断裂伸长率均出现先增强后降低的趋势,而阳离子含量和亲水性不断增加.进一步将改性PUF作为固定化载体用于吸附活性污泥,结果显示,由于亲水性的增强和静电相互作用,改性PUF对活性污泥的吸附速度明显高于普通聚氨酯泡沫(简称对比PUF),其对活性污泥的单位体积吸附量最高可达180 g/L,是对比PUF(80 g/L)的2倍以上.     

啁啾脉冲频域干涉测量技术的扰动重构理论模拟研究

利用啁啾脉冲的频域干涉测量技术,可实现对超快光学瞬态过程的单发诊断,此方法的时间分辨率和单发时间测量范围分别与啁啾脉冲的谱宽和脉冲宽度及光谱仪的工作性能有关。当两束线性啁啾脉冲进入光谱仪后,相同的频谱成分会发生干涉形成频谱干涉条纹,如果其中一束脉冲受到外界扰动的影响,可根据干涉条纹的形状重构出扰动的具体形式。理论研究和数值模拟了由频谱干涉图重构外界附加扰动的过程,模拟结果显示重构出的扰动同附加的真实扰动符合得较好;在频谱记录面有限的情况下,重构出的扰动信号带有强烈的振荡,通过平滑处理有效地抑制了振荡。     

Nonlinear optical properties in double-sided nonlinear media with Z-scan technique based on the Huygens——Fresnel principle

We present a theoretical model to analyse the propagation of a Gaussian laser beam through double-sided nonlinear media. This model is based on the Huygens--Fresnel diffraction integral method. This theoretical model is not only consistent with the cascade structure model for a small nonlinear phase-shift but also can be used for a large nonlinear phase-shift. It has been verified that it is suitable to characterize the double-sided nonlinear media compared with the cascade structure model. A good agreement between the experimental data and the results from the theoretical model is obtained. It will be useful for the design of multi-sided nonlinear materials.     

有机铬富勒烯衍生物的激发态与光限幅特性

应用倍频ｎｓ／ｐｓＮｄ：ＹＡＧ脉冲激光系统,在波长为５３２ｎｍ,脉冲宽度为２１ｐｓ的条件下,研究了新型有机铬富勒烯衍生物的激发态吸收与光限幅特性,其光限幅特性优于富勒烯甲苯溶液;并应用单重态激发态吸收理论对实验结果进行了分析,实验结果与理论结果基本一致。