利用离子型Cd源制备ZnSe/CdSe核-壳结构纳米晶

在有机相体系中利用ZnSe前驱体纳米晶制备过程中的富Se环境,以引入Cd2+的方式在相对温和的环境下通过控制Cd2+离子的加入量及调节反应时间,成功制备了ZnSe/CdSe核-壳复合结构纳米晶.利用X射线衍射(XRD)、透射电镜(TEM)、紫外-可见吸收光谱(UV-vis)和荧光光谱(FL)对其结构形貌以及光学性质进行表征和分析的结果表明,CdSe以外延生长的方式包覆在ZnSe纳米晶表面从而形成具有良好结晶性的核-壳复合结构,其荧光发射始终保持良好单色性,同时实现了在500～620nm可见光范围内的连续可调.     

百合的化学成分研究

对百合干燥鳞茎95%乙醇提取得到乙醇提取浓缩部位A和药渣B,对乙醇提取浓缩部位A用石油醚、正丁醇、水萃取后得到水部位部位C,对B用60%丙酮提取物的水溶性部位D。把部位C和部位D合并,利用MCI gel CHP 20P、TSK gel Toyopearl HW-40F、Cosmosil 75 C18-OPN等现代分离技术对上述部分进行分离纯化,通过现代波普技术分析鉴定其化学结构。结果从中分离出3个化合物,分别是methylgroupO-β-D-glucopyranoside(1)、methylpropenylO-β-D-glucopyranoside(2)、phenylmethyl O-a-L-rhamnopyranosyl-(1”-6′)-β-D-glucopyranoside(3)。以上三个化合物均为首次从该属植物中分离得到。     

基于氢键识别的分子设计

利用ＡＭ１方法研究了３，４－二羰基苯乙胺与一系列双氨基化合物的分子识别作用。结果表明，双氢键的形成有利于体系能量的降低，并且具有亲疏水环境相一致的分子对有更稳定的能量状态。基于上述讨论，提出了微观环境匹配的识别分子设计原则。     

煤层气井气水两相分布不稳定试井模型

煤层气是一种高效清洁的非常规天然气资源,其开采过程是一个排水降压采气的过程. 由于煤层气主要是以吸附态的形式存在于煤层中,当煤层压力降低到临界解吸压力以下时煤层气从煤层中解吸出来并与水一起采出,因此煤层中流体是气水两相分布的. 本文根据煤层气藏排采过程中的解吸特征,通过考虑气水两相分布的渗透率关系,提出了一种与解吸区域大小相关的煤层气井不稳定试井模型. 该模型较好地描述了煤层气排采过程中煤层内气水的流动状态,采用分区模式对气水两相进行描述. 通过有限体积方法求解了所建立的试井模型,计算得到了煤层气井气水两相分布不稳定试井理论曲线,分析了煤层气解吸系数、解吸复合半径、气水饱和度分布等对试井理论曲线的影响.     

X射线在影象增强器中背向散射特性的研究

本文用蒙特卡罗方法模拟了轫致辐射Ｘ射线在影象增强器中的背向散射特性。针对Ｘ线源管电压为３０－１２０ｋＶ的轨致辐射入射，给出了背向散射光子的角分布及能谱分布；同时，还给出了背向散射光子的平均能量和平均出射角与管电压的关系以及吸收光子数和直透光子数与管电压的关系。     

一种新的昆虫神经网络预测预报方法

昆虫预测预报是植物保护中的一个困难问题．本文首先从系统的观点出发，分析了影响昆虫种群密度的主要因素；在研究传统时间序列模型共性的基础上，给出了广义时间序列模型；提出了一种新的昆虫预测模式—神经网络预测预报方法；用此方法对棉田害虫烟蓟马进行了预报，数值结果表明这是一种很好的预测预报方法，预测精度较其它方法都有很大提高．     

THE GENERALIZED GALERKIN’S EQUATION OF THE FINITE ELEMENT,THE BOUNDARY VARIATIONAL EQUATIONS AND THE BOUNDARY INTEGRAL EQUATIONS

Based on[1 ],we have further applied the variational princi-ple of the variable boundary to investigate the discretizationanalysis of the solid system and derived the generalized Ga-lerkin’s equations of the finite element.the boundary varia-tional equations and the boundary integral equations.These e-quations indicate that the unknown functions of the solid sys-tem must satisfy the conditions in the element S_a or on the boun-dariesГ_a.These equations are applied to establishing the discreti-zation equations in order to obtain the numerical solution ofthe unknown functions.At a time these equations can be usedas the basis for the simplified calculation in various corres-ponding cases.In this paper,the results of boundary integral equationsshow that the calculation of integration is not accurate alongthe surfaceГ_a of interior element S_a by J-integral suggestedby Rice[2].     

Effects of volume fraction condition on thermodynamic restrictions in mixture theory

Volume fraction condition is a true constraint that must be taken into consideration in deducing the thermodynamic restrictions of mixture theory applying the axiom of dissipation. For a process to be admissible, the constraints imposed by the volume fraction condition include not only the equation obtained by taking its material derivative with respect to the motion of a given phase, but also those by taking its spatial gradient. The thermodynamic restrictions are deduced under the complete constraints, the results obtained are consistent for the mixtures with or without a compressible phase, and in which the free energy of each phase depends on the densities of all phases.     

Photoluminescence of Self－Assembled InAs／GaAs Quantum Dots Covered by InAlAs and InGaAs Combination Strain－Reducing Layer

Self-assembled lnAs/GaAs quantum dots covered by the 1-nm InxAI(1-x)As (x = 0.2, 0.3) and 3-nm In0.2Ga0.8As combination strain-reducing layer are fabricated, whose height can take up to 30-46 nm. The luminescence emission at a long-wavelength of 1.33μm and the energy separation between the ground and the first-excited state of 86meV are observed at room temperature. Furthermore, comparative study proves that the energy separation can increase to 91 meV by multiple stacking.     

Deposition of TiN Films by Novel Filter Cathodic Arc Technique

A straight magnetic filtering arc source is used to deposit thin films of titanium nitride. The properties of the films depend strongly on the deposition process. TiN films can be deposited directly onto heated substrates in a nitrogen atmosphere or onto unbiased substrates by condensing the Ti^＋ ion beam in about 300 eV N2^＋ nitrogen ion bombardment. In the latter case, the film stoichiometry is varied from an N：Ti ratio of 0.6-1.1 by controlling the arrival rates of Ti and nitrogen ions. Meanwhile, simple models are used to describe the evolution of compressive stress as function of the arrival ratio and the composition of the ion-assisted TiN films.