荧光素与电子给体/受体LB膜的制备、表征和光电性质

本论文涉及的问题是功能材料的分子设计、合成和按预定分子顺序取向排列的薄膜制备,是当前科学技术的前沿课题之一。合成了一系列荧光素衍生物包括由荧光素和电子给体(葱、吩唾嗓)及电子受体(紫精)组成的模型化合物和二元化合物,其中九种是具有亲水基团和疏水基团的长链烷烃衍生物。并在此基础上制备了LB膜,详细地研究了它们的成膜特性。运用荧光显微镜、透射电子显微镜、原子力显微镜、反射椭圆偏振法、X-射线衍射法、转移折叠法和偏振红外光谱法等多种现代仪器和分析方法,研究了膜的均匀度、平均折射率和厚度、功能团取向与LB膜的结构问题,并讨论了分子结构和取向与性能的关系。     

学生学习高等数学的动机初探

高等数学（以下简称高数）是工科院校最重要的基础课之一,也是大学一年级学时数最多的一门课程．它不仅是学生学习后继课程的必要基础,而且对学生各种能力的培养有着重要作用．通过高数的教学,对于刚刚结束中学学习的一年级学生掌握大学阶段的学习方法,培养良好的学风,也有着重要的意义．因此,本门课程的教学质量、教学效果不仅关系到学生对该门课程的学习,而且将直接或间接地影响到后继课程的教学,最终影响到高质量人才的培养．那么,怎样才能找准提高教学质量的切入点呢？我认为：教师只有真正认清和掌握学生学习的兴趣、动机等心…     

基于Optisystem的光纤传感磁场测试系统性能仿真

利用Optisystem实现了FBG光纤传感磁场测试系统。基于马赫曾德干涉原理,搭建了光纤光栅仿真模型及模型中的参数设置,并通过探测光路与参考光路的对比实现了对模拟磁场的测试。仿真结果表明,建立的FBG光纤传感磁场测试系统具有良好的可靠性,Optisystem适合光纤传感系统课程实验。     

降幂不等式及其应用

一、发现问题 课堂上笔者讲授了这样一道练习：已知x、y、z均是正数,且x＋y＋z=1,求证：x^3＋y^3＋z^3≥1/3,当且仅当x=y=z时等号成立．     

基于棱镜结构的双波长M-Z干涉系统设计

为了便于光程差的调节,利用全反射棱镜结构改进了传统的M-Z干涉系统,并建立了基于双波长干涉原理的M-Z测量系统理论模型。利用Zemax建立了完整的光学系统模型,对整个系统进行仿真分析测试。系统像质评价结果表明:532 nm~632.8 nm波段范围内系统的能量集中度达85%、畸变值小于0.02%、截止频率10 lp/mm时调制传递函数在0.9以上,满足对透射型试样进行测量的成像要求,为高性能干涉系统实用化提供了理论依据和技术支持。     

First-Principles Study of Intrinsic Point Defects of Monolayer GeS

The properties of six kinds of intrinsic point defects in monolayer GeS are systematically investigated using the“transfer to real state”model,based on density functional theory.We find that Ge vacancy is the dominant intrinsic acceptor defect,due to its shallow acceptor transition energy level and lowest formation energy,which is primarily responsible for the intrinsic p-type conductivity of monolayer GeS,and effectively explains the native p-type conductivity of GeS observed in experiment.The shallow acceptor transition level derives from the local structural distortion induced by Coulomb repulsion between the charged vacancy center and its surrounding anions.Furthermore,with respect to growth conditions,Ge vacancies will be compensated by fewer n-type intrinsic defects under Ge-poor growth conditions.Our results have established the physical origin of the intrinsic p-type conductivity in monolayer GeS,as well as expanding the understanding of defect properties in lowdimensional semiconductor materials.     

金属离子对蛋白质的折叠、识别、自组装及功能的影响*

金属离子不仅影响金属蛋白的空间结构,还与生物大分子的识别、自组装等性质和生物功能密切相关。在很多蛋白质中,金属离子及其配合物可以诱导周围的肽段折叠成正确的结构,我们将其称为金属结合部位作为模板诱导的结构基序（Template-mediated structural motif,TMSM)。深入研究金属离子在蛋白质-核酸自组装体系中生物大分子交联及聚集体中的作用,对理解生命的无机化学基础具有重要意义。     

Photoinduced charge injection from excited triplet hypocrellin B into TiO_2 colloid in ethanol

Photosensitization of TiO2 colloid by hypocrellin B (HB),a natural photodynamic pigment with extremely high photosta-bility,has been studied by surface enhanced Raman spec-troscopy (SERS),laser flash photolysis and electron paramagnetic resonance (EPR) techniques.The photoseiisitization of TiO2 occurred practically from the excited triplet dye and the electron injection rate constant is 1.3×106 s-1.The influences of donor and acceptor on the electron injection were investigated.     

Numerical method of studying nonlinear interactions between long waves and multiple short waves

Although the nonlinear interactions between a single short gravity wave and a long wave can be solved analytically, the solution is less tractable in more general cases involving multiple short waves. In this work we present a numerical method of studying nonlinear interactions between a long wave and multiple short harmonic waves in infinitely deep water. Specifically, this method is applied to the calculation of the temporal and spatial evolutions of the surface elevations in which a given long wave interacts with several short harmonic waves. Another important application of our method is to quantitatively analyse the nonlinear interactions between an arbitrary short wave train and another short wave train. From simulation results, we obtain that the mechanism for the nonlinear interactions between one short wave train and another short wave train (expressed as wave train 2) leads to the energy focusing of the other short wave train (expressed as wave train 3). This mechanism occurs on wave components with a narrow frequency bandwidth, whose frequencies are near that of wave train 3.     

Pitch Shift in Exsomatized Cochlea Observed by Laser Interferometry

Pitch is one of the most important auditory perception characteristics of sound; however, the mechanism underlying the pitch perception of sound is unclear. Although theoretical researches have suggested that perception of virtual pitch is connected with physics in cochlea of inner ear, there is no direct experimental observation of virtual pitch processing in the cochlea. By laser interferometry, we observe shift phenomena of virtual pitch in basilar membrane vibration of exsomatized cochlea, which is consistent with perceptual pitch shift observed in psychoacoustic experiments. This means that the complex mechanical vibration of basilar membrane in cochlea plays an important role in pitch information processing during hearing.