UPLC-MS/MS和主成分分析法判别海洛因原产地

建立了超高效液相色谱-串联四极杆质谱仪(UPLC-MS-MS)在电喷雾离子源正离子(ESI+)和多反应监测(MRM)模式下定量测定海洛因中9种生物碱的方法,并采用主成分分析法建立数学模型,实现了快速区分"东南亚"和"西南亚"地区海洛因样品的目的。样品使用甲醇超声提取,ACQUITY UPLC BEH C18(100 mm×2.1 mm i.d.,1.7μm)色谱柱,流动相为pH 9.66的10 mmol/L的碳酸氢铵和乙腈,在梯度条件下分析。结果表明,在5～500μg/kg添加水平下回收率范围为88%～118%,相对标准偏差为1.7%～10%。9种生物碱的检出限(LOD,以信噪比(S/N)>3计)和定量限(LOQ,以S/N>10计)分别为0.03～1.67 mg/kg和0.10～5.51 mg/kg。本方法在11 min内即可对缴获海洛因样品中的9种生物碱进行定量分析,可用于海洛因原产地的快速判别。     

认知无线电网络中利用FEC和DE的多节点频谱感知算法

针对认知无线电网络(CRN)中空闲频谱感知困难的问题,本文提出了基于前向纠错和差分进化算法的多节点频谱感知算法。首先,利用基于差分进化算法的协同检测完成信号感知;然后,研究了信道噪声对频谱感知性能的影响;最后,分析了前向纠错技术在信道存在噪声时对频谱感知性能的影响。仿真实验将纠错和无纠错控制信道的不同信噪比作为依据,采用三种不同的检测方法评估了本文算法。仿真实验结果表明,在存在噪声的认知无线电网络中,本文算法提高了系统的性能和检测概率,且协同感知算法的性能随着节点数目的增加而提高,该算法适合应用于实时性要求较高的应用程序。     

Quantum entanglement in the mode-mode competition system

Considering a two-level atom interacting with the competing two-mode field, this paper investigates the entanglement between the two-level atom and the two-mode field by using the quantum reduced entropy, and that between the two-mode field by using the quantum relative entropy of entanglement. It shows that the two kinds of entanglement are dependent on the relative coupling strength of atom-field and the atomic distribution, and exhibit the periodical evolution. The maximal atom-field entanglement state can be prepared via the appropriate selection of system parameters and interaction time.     

2，5－二取代1，3，4－噁二唑的合成及其电子轰击质谱

２，５－二取代１，３，４－噁二唑的合成及其电子轰击质谱徐东成，杨骏，周健民，张玉霞，花文廷（北京大学化学系，１００８７１）二唑类化合物大都具有消炎［１］，抗菌［２］，调节植物生长，杀虫等广泛的生物活性，有的还是很好的光敏物质［３］和高分子液晶等聚合物...     

Yb离子抽运动力学及脉冲储能特性研究

从准三能级Yb离子的能级结构出发，建立了Yb离子的抽运和激光速率方程，结合解析和数值方法，研究了Yb激光介质的抽运动力学过程，包括抽运激发效率、最低抽运强度、激光能量提取效率等关键参数.比较了三类典型的Yb激光介质性能：Yb:S-FAP,Yb:YAG以及Yb:FP-glass.以放大自发辐射(ASE)为设计判据，重点研究了脉冲储能型Yb激光器的设计准则，包括增益介质的厚度与掺杂浓度.最后利用此模型给出了基于Yb:S-FAP以及Yb:YAG的100J级二极管抽运固体激光器(DPSSL)的总体设计参数.将对基于Yb激光介质的脉冲储能型DPSSL的设计提供有益的参考. 关键词： Yb离子 速率方程 抽运动力学 二极管抽运固体激光器     

Atom-photon entanglement in the system with competing k-photon and l-photon transitions

We have investigated the evolution of the atomic quantum entropy and the entanglement of atom-photon in the system with competing k-photon and l-photon transitions by means of fully quantum theory, and examined the effects of competing photon numbers （k and l）, the relative coupling strength between the atom and the two-mode field （A/g）, and the initial photon number of the field on the atomic quantum entropy and the entanglement of atom-photon. The results show that the multiphoton competing transitions or the large relative coupling strength can lead to the strong entanglement between atoms and photons. The maximal atom-photon entanglement can be prepared via the appropriate selection of system parameters and interaction time.     

Density functional theory study on LaNi4.5Al0.5 hydride phase： electronic properties and sites occupation＊

In this paper the crystal structure, electronic structure and hydrogen site occupation of LaNi4.5Al0.5Hy hydride phase （y = 5.0, 6.0） have been investigated by using full-potential linearized augmented plane wave method. The hydrogen atoms were found to prefer the 6m, 12o and 12n sites, while no 4h sites were occupied. A narrowed Ni-d band is found due to the lattice expansion, the total density of states at EF increases with y, which indicates that the compounds become less stable. The interaction between Al and Ni, H plays a dominant role in the stability of LaNi4.5Al0.5 hydride phase. The smaller the shift of EF towards the higher energy region, the more stable the compounds will be. The obtained results are compared with experimental data and discussed in the light of previous works.     

脉冲激光诱导光纤损伤的测试方法

 针对传能光纤的高峰值功率激光损伤过程，研究了光纤损伤测试方法。实验装置搭建中增加了定位孔，有利于激光注入光纤对准；分别采用刀口法和CCD法对入射光束不同截面处光斑大小进行了测量，两种方法的测量结果基本一致。参考GJB1487-92激光光学元件测试方法和ISO11245光学表面的激光诱导损伤阈值测试方法，采用N-ON-1损伤测试和有效光斑面积计算方法对芯径为400 μm的石英包层阶跃折射率石英光纤进行了损伤阈值测试。实验发现：光纤损伤部位全部为入射端面，利用200倍显微镜观察光纤端面，出现明显永久性损伤点。最后采用统计学原理和线性拟合等方法得出测试光纤的端面零概率损伤阈值为3.85 GW/cm²。     

蒙药材肋柱花中盐酸小檗碱的反相高效液相色谱法分析

用高效液相色谱法测定蒙药材肋柱花中小檗碱的含量.色谱流动相为乙腈:水(V:V=30:70,每1000mL水中加入KH2PO43.4g),流速为0.8mL/min,紫外检测波长为345nm.结果表明,盐酸小檗碱在6.25-50μg/mL范围内具有良好的线性关系,相关系数为0.9992,实验测得平均回收率为97.7%,RSD=0.94%(n=6).方法操作简便,灵敏度高,结果准确可靠.