Directed transport of coupled Brownian ratchets with time-delayed feedback

A time-delayed feedback ratchet consisting of two Brownian particles interacting through the elastic spring is consid ered. The model describes the directed transport of coupled Brownian particles in an asymmetric two-well ratchet potential which can be calculated theoretically and implemented experimentally. We explore how the centre-of-mass velocity is af fected by the time delay, natural length of the spring, amplitude strength, angular frequency, external force, and the structure of the potential. It is found that the enhancement of the current can be obtained by varying the coupling strength of the delayed feedback system. When the thermal fluctuation and the harmonic potential match appropriately, directed current evolves periodically with the natural length of the spring and can achieve a higher transport coherence. Moreover, the external force and the amplitude strength can enhance the directed transport of coupled Brownian particles under certain conditions. It is expected that the polymer of large biological molecules may demonstrate a variety of novel cooperative effects in real propelling devices.     

脂溶性CdSe/ZnS量子点脂质体复合物的制备及表征

在油相中成功合成了脂溶性CdSe/ZnS核壳量子点纳米粒,粒径平均为4.5 nm,量子产率达29%,发射波长为540 nm。通过薄膜分散法,以蛋黄卵磷脂、胆固醇为膜材,将脂溶性的CdSe/ZnS核壳量子点包覆于脂质体磷脂双分子层中,由于磷脂分子的两亲性,使得脂溶性的CdSe/ZnS核壳量子点同时又具有亲水性。通过透射电镜对脂质体形态进行了表征,倒置荧光显微镜证实了发光CdSe/ZnS核壳量子点成功包埋于脂质体双分子层中,包裹的发光CdSe/ZnS核壳量子点具有更稳定的发光及抗光漂白性质。     

A possible mechanism for magnetar soft X-ray/γ-ray emission

Once the energies of electrons near the Fermi surface obviously exceed the threshold energy of the inverse β decay,electron capture(EC) dominates inside the magnetar.Since the maximal binding energy of the 3 P 2 neutron Cooper pair is only about 0.048 MeV,the outgoing high-energy neutrons(E k(n) > 60 MeV) created by the EC can easily destroy the 3 P 2 neutron Cooper pairs through the interaction of nuclear force.In the anisotropic neutron superfluid,each 3 P 2 neutron Cooper pair has magnetic energy 2μ n B in the applied magnetic field B,where μ n = 0.966 × 10 23 erg.G 1 is the absolute value of the neutron abnormal magnetic moment.While being destroyed by the high-energy EC neutrons,the magnetic moments of the 3 P 2 Cooper pairs are no longer arranged in the paramagnetic direction,and the magnetic energy is released.This released energy can be transformed into thermal energy.Only a small fraction of the generated thermal energy is transported from the interior to the surface by conduction,and then it is radiated in the form of thermal photons from the surface.After highly efficient modulation within the star’s magnetosphere,the thermal surface emission is shaped into a spectrum of soft X-rays/γ-rays with the observed characteristics of magnetars.By introducing related parameters,we calculate the theoretical luminosities of magnetars.The calculation results agree well with the observed parameters of magnetars.     

氧化石墨烯如何猝灭罗丹明6G的荧光

考察了水相溶液中氧化石墨烯对罗丹明6G的高效荧光猝灭．借助稳态及时间分辨荧光光谱测量,结合对该二元体系线性吸收谱变化的细致分析,澄清了相关荧光猝灭机理,即动态猝灭与静态猝灭的联合猝灭机制．提出在静态猝灭过程中罗丹明6G与氧化石墨烯所形成的可能的基态复合物,并进一步讨论了二者之间的光致电子转移过程．     

二维势场中弹性耦合粒子的定向输运研究

建立了二维势场中弹性耦合粒子的输运模型, 其中一维上加交流驱动及噪声, 另一维上不加驱动及噪声, 分析讨论了过阻尼情形下系统和外部参量对定向流的影响. 结果表明, 粒子可以通过相互耦合使一个方向上输入的驱动能量转化到垂直方向上, 从而使无能量输入的方向产生定向流. 适当的弹簧自由长度及耦合强度可以使定向流达到极值, 特别是当耦合强度及噪声强度固定时, 定向流会随弹簧自由长度的变化而振荡, 出现多峰现象. 研究还发现, 定向流随噪声强度的变化出现随机共振现象. 当产生定向流方向上的势的不对称度达到一定程度时会出现流反转现象. 关键词： 弹性耦合 定向输运 随机共振 流反转     

基于中空氧化镍纳米微球和离子液体复合膜固定血红蛋白的NaNO2生物传感器

采用微波水热法合成了一种中空氧化镍纳米微球(NiO), 然后将其与1-丁基-3-甲基-咪唑四氟硼酸盐(BMIMBF4)的复合膜用于血红蛋白(Hb)在碳糊电极上的固定, 制备了NaNO2生物传感器. 通过扫描电子显微镜、 傅里叶变换红外光谱及紫外-可见光谱等分析表明, Hb已固定于NiO和BMIMBF4的复合膜中并能保持其生物活性; 进一步通过电化学阻抗法研究了修饰电极中混合物各组分的作用. 结果表明, 在NiO和BMIMBF4的复合膜中, Hb能实现有效的直接电子转移, 且修饰后的电极对NaNO2有良好响应, 响应时间小于5 s, 检出限为4.57 μmol/L(S/N=3), 灵敏度为46.2 μA·L·mmol-1, 线性范围为10~170 μmol/L, 表观米氏常数KM为2.4 mmol/L, 该方法的重现性和电极的稳定性良好.     

CPPαFP缩糠胺席夫碱铜配合物的合成及其与DNA相互作用

合成出一种新型酰基吡唑啉酮席夫碱试剂(HL):1-对氯苯基-3-苯基-4-(α-呋喃甲酰基)-吡唑啉酮-5缩糠胺席夫碱及其铜配合物。由元素分析、络合滴定法、红外光谱、热重谱、质谱和核磁共振氢谱对配体和配合物的结构进行了表征并推测出配合物组成为CuL2,同时对该配合物与小牛胸腺DNA之间的相互作用进行了研究。结果表明:在测试条件下,配体以酮式和烯醇式共存。配位时酮式结构可能转化为烯醇式结构,按去质子的方式以羟基上的氧负离子和亚胺基上的氮原子双齿形式与铜中心离子成键;与小牛胸腺DNA作用实验结果显示:配合物主要以插入方式与CT-DNA相互作用,嵌入CT-DNA的碱基对中。     

基于k阶二元关系的直觉模糊粗糙集

利用k阶二元关系定义直觉模糊粗糙集,讨论了分别为串行、自反、对称、传递关系时所对应的上、下近似算子的性质。在有限论域U中,研究了任一自反二元关系所诱导的直觉模糊拓扑空间中直觉模糊闭包、内部算子与相对应的上、下近似算子的关系。     

巧用二项式定理证明不等式

二项式定理在解决与自然数有关的幂不等式的证明中给我们提供了结构简明、思路清晰的证明方法,下面举例说明,供大家参考．     

含有BF—I函数的多目标变分问题的混合对偶性

在有效解的意义下,对一类含有BF—I函数的多目标变分问题给出了混合型对偶的强对偶定理、弱对偶定理和严格逆对偶定理。