Tribological properties of diamond-like carbon films deposited by pulsed laser arc deposition

A novel method, pulsed laser arc deposition combining the advantages of pulsed laser deposition and cathode vacuum arc techniques, was used to deposit the diamond-like carbon (DLC) nanofilms with different thicknesses. Spectroscopic ellipsometer, Auger electron spectroscopy, x-ray photoelectron spectroscopy, Raman spectroscopy, atomic force microscopy, scanning electron microscopy and multi-functional friction and wear tester were employed to investigate the physical and tribological properties of the deposited films. The results show that the deposited films are amorphous and the sp$^{2}$, sp$^{3}$ and C--O bonds at the top surface of the films are identified. The Raman peak intensity and surface roughness increase with increasing film thickness. Friction coefficients are about 0.1, 0.15, 0.18, when the film thicknesses are in the range of 17--21~nm, 30--57~nm, 67--123~nm, respectively. This is attributed to the united effects of substrate and surface roughness. The wear mechanism of DLC films is mainly abrasive wear when film thickness is in the range of 17--41~nm, while it transforms to abrasive and adhesive wear, when the film thickness lies between 72 and 123~nm.     

露天煤矿设备运载对采空区上覆岩体稳定性分析

在平朔东露天矿开采境界内存在大量小窑采空区,对露天矿设备的运行产生极大威胁.选取以探明5-27采空区,以东露天矿常用930E型卡车和WK-35型电铲为例,应用安全系数评价方法,计算出当采空区上覆岩体存在设备运载时的安全系数,并进行稳定性分析.露天矿设备运载对采空区上覆岩体的稳定性有一定影响,当有露天矿设备作业时采空区上覆岩体安全系数K_2=0.82,易发生整体性坍塌.因此,研究露天矿采设备运载对空区上覆岩体的影响,避免出现坍塌事故,有着重要的理论意义和实用价值.     

钌亚丙二烯基配合物与肼的反应性质:丙烯腈配合物的生成（英文）

以双齿P,N-配体8-(二苯基膦基)喹啉(DPPQ)为支撑配体的钌亚丙二烯基配合物[RuCl(=C=C=CR_2)(DPPQ)_2]-[BPh_4](3a:R=苯基;3b:CR_2=FN=亚芴基)可由双核钌配合物[Ru(μ-Cl)(DPPQ)_2]_2[BPh_4]_2(1)分别与过量的1,1-二苯基炔丙醇(2a)或9-乙炔-9-芴醇(2b)反应得到.配合物3易与肼在室温下反应生成丙烯腈的钌配合物[RuCl(N≡C—CH=CR)2)(DPPQ))2][BPh)4](4a:R=苯基;4b:CR)2=FN=亚芴基),该反应涉及肼对亚丙二烯基配体α-碳原子的分子间亲核进攻,是首例肼对金属亚丙二烯基加成生成丙烯腈的反应.配合物4与过量的丙炔醇2反应可释放出3,3-二苯基丙烯腈(5a)或3-芴基丙烯腈(5b),并再生亚丙二烯基配合物3.此外,初步考察了配合物1对端基炔丙醇与肼反应生成丙烯腈的催化活性,结果表明该催化反应的确可以进行,但是得到的丙烯腈产物的产率不高.尽管结果不是很理想,但是这些研究表明可望发展端基炔丙醇与肼经由过渡金属亚丙二烯基中间体转化为丙烯腈的新催化反应.     

大孔径静态干涉光谱仪图像压缩技术

从图像压缩的角度分析了大孔径静态干涉成像光谱仪成像原理，并提出了一种新的遥感多光谱图像压缩方案。新方案利用大孔径静态干涉成像光谱仪推扫成像特点提出了一种低存储量，帧间小波域匹配的图像序列压缩方法，提高图像质量3～4dB。为了保证图像的光谱信息在8倍压缩比下有效应用，系统采用了一种新的感兴趣区域(ROD编码技术。感兴趣区域编码时，由于方案中采用率失真优化斜率提升，而不是比特平面移位，从而使图像在相同的光谱分辨率下拥有更好的空间分辨率。实验结果表明，算法大大保护了图像的光谱特性，在8倍压缩比下，满足了该类干涉多光谱遥感图像的质量要求。     

Effect of the Initial Laser Phase on the Interaction Between Relativistic Electron and Ultra－Intense Laser Field in a Strong Uniform Magnetic Field

We investigate the influence of the initial laser phase on the interaction between relativistic electron and ultraintense linear polarized laser field in a strong uniform magnetic field. It is found that the dynamic behaviour of the relativistic electron and the emission spectrum varies dramatically with different initial laser field phases.The effect of changing initial phase is contrary in the two parameter regions divided by the resonance condition.The phase dependence of the electron energy and velocity components are also studied. Some beat structure is found when the initial laser phase is zero and this structure is absent when the initial laser phase is a quarter of a period.     

Studies Towards the Total Synthesis of Methyl Isosartortuoate： The Synthesis of a Cyclic Precusor of the Diene Unit

The preparation of the key intermediate 4 of the methyl isosartortuoate is described. The macrocyclization was completed through an intramolecular [ 2,3]-Wittig ring contraction. The four necessary stereogenic carbons were established by Sharpless asymmetric AE and AD reaction.     

Bredt规则和双环桥烯化合物

本文评述了Bredt规则和双烯化合物特征及合成发展。     

递推数列的通项

递推数列是数列中的一类非常重要的问题，一般地，可以通过给出数列的第一项（或前若干项），并给出数列的某一项（或前若干项）的关系式来表示数列，这种表示数列的方式叫做数列递推方式．     

微光CCD摄像器件灵敏阈研究

本文提出了视频信噪比转移函数概念,建立了摄像CCD微光图像灵敏(?)方程.实验证实了理论模型的合理性.根据这个方程用计算机模拟计算了几种条件下微光CCD摄像器件探测曲线.分析这个结果后提出了提高CCD微光图像探测能力的几种途径.