2,5-双{β-[对-(6-羟基己氧基)苯基]乙炔基}嘧啶的合成

以对溴苯酚、6-氯-1-己醇,甲基丁炔醇和5-溴-2-碘嘧啶为原料,通过Williamson反应、水解反应和Sono-gashina反应合成了2,5-双{β-[p-(6-羟基己氧基)苯基]乙炔基}嘧啶,其结构经1HNMR,IR和元素分析表征。     

连续流动法测定土壤中有机质

建立连续流动化学分析法测定土壤中有机质含量。采用自动凯氏消化器对样品进行加热，使有机质在硫酸作用下被重铬酸钾氧化成二氧化碳和水，过量的重铬酸钾在酸性条件下，与1,5-二苯基碳酰二肼反应生成紫红色络合物，用连续流动化学分析仪测定。该法线性范围为0.4～2.0 g/L，线性相关系数为0.999 0，测定结果的相对标准偏差为0.48%～2.85%(n=6)，土壤标准物质测定值与标准值吻合。该法与NY/T 1121.6—2006方法对土壤中有机质的测定结果无显著性差异。     

气流式喷嘴雾化过程的分形特征及液滴分裂模型

研究了在雾化等过程中液滴粒度分形特征，提出了—个液滴分裂服从均匀分布概率的数学模型，通过计算机模拟，计算出同代液滴的结构分维和特征分维，并用对异代液滴计算得到的结果，验证粒度分布中的结构分维，结果吻合很好．实验测定了液滴分裂的分形维数，与模拟结果相符。     

盐湖卤水协同萃取提锂及基础热力学性质

为了充分利用盐湖卤水中丰富的锂资源,提出了以磷酸三丁酯(TBP)-乙酸丁酯(BA)-FeCl3-260#磺化煤油体系协同萃取提锂的方法。针对该体系,考察了卤水酸度、nFe/nLi比以及温度对协同萃取过程的影响。根据锂离子及其它主要离子萃取率的变化,确定了最优萃取条件为:pH=2,nFe/nLi=3.0,T=20℃。在最优条件下,单级萃取率达到90%左右。同时,研究了萃取过程的热焓、吉布斯自由能及熵变等基础热力学性质。结果表明,在选定的萃取体系和条件下,锂的萃取反应为放热反应,萃取过程为熵减过程。     

基于Elman网络预测汇率短期发展趋势

采用神经网络Elman网络模型对汇率进行预测.处理过程对样本序列进行了分类,并对训练与测试样本进行了残差分析.预测结果表明:该方法对汇率涨落方向的预测准确度达到74.54%,对汇率预测值与实际值之间的偏差略为偏大的情况,并分析了产生误差的原因.     

Evaluation of polarization field in InGaN/GaN multiple quantum well structures by using electroluminescence spectra shift

In order to investigate the inherent polarization intensity in InGaN/GaN multiple quantum well(MQW) structures,the electroluminescence(EL) spectra of three samples with different GaN barrier thicknesses of 21.3 nm, 11.4 nm, and 6.5 nm are experimentally studied. All of the EL spectra present a similar blue-shift under the low-level current injection,and then turns to a red-shift tendency when the current increases to a specific value, which is defined as the turning point.The value of this turning point differs from one another for the three InGaN/GaN MQW samples. Sample A, which has the GaN barrier thickness of 21.3 nm, shows the highest current injection level at the turning point as well as the largest value of blue-shift. It indicates that sample A has the maximum intensity of the polarization field. The red-shift of the EL spectra results from the vertical electron leakage in InGaN/GaN MQWs and the corresponding self-heating effect under the high-level current injection. As a result, it is an effective approach to evaluate the polarization field in the InGaN/GaN MQW structures by using the injection current level at the turning point and the blue-shift of the EL spectra profiles.     

全息照相实验中各种振动对系统稳定性影响的研究

通过设计一个简单的马赫-曾德干涉光路,得到合适的干涉条纹。通过演示实验者倚靠实验平台、在光路附近说话、在平台附近走动以及楼层振动等干扰条件,利用光强传感器实时监控条纹的变化,表征了上述振动干扰对条纹漂移的影响。上述结果对于学生直观理解全息照相过程条纹漂移的干扰因素将有一定帮助,同时有利于学生在实验过程中避免上述问题,提高全息照相实验成功率。     

Observation of positive and small electron affinity of Si-doped AlN films grown by metalorganic chemical vapor deposition on n-type 6H–SiC

We have investigated the electron affinity of Si-doped AlN films(N_(Si)= 1.0 × 10~(18)–1.0 × 10_(19)cm~(-3)) with thicknesses of 50, 200, and 400 nm, synthesized by metalorganic chemical vapor deposition(MOCVD) under low pressure on the ntype(001)6H–SiC substrates. The positive and small electron affinity of AlN films was observed through the ultraviolet photoelectron spectroscopy(UPS) analysis, where an increase in electron affinity appears with the thickness of AlN films increasing, i.e., 0.36 eV for the 50-nm-thick one, 0.58 eV for the 200-nm-thick one, and 0.97 e V for the 400-nm-thick one.Accompanying the x-ray photoelectron spectroscopy(XPS) analysis on the surface contaminations, it suggests that the difference of electron affinity between our three samples may result from the discrepancy of surface impurity contaminations.     

G.P.汤姆孙对电子衍射的实验研究

介绍了G．P．汤姆孙完成电子衍射实验,证明了德布罗意提出的物质波理论的研究经历从中可以看到注意研究选题的先进性,注重理论的先导作用和科学的研究方法的重要性。     

圈上Moebius测度的Sobolev不等式（英文）

本文考虑单位圈上的Moebius测度的问题.利用文献[1]和[2]中的方法,把圈上的Moebius测度的估计转化为对一维扩散过程的相关估计上,得到了单位圈上的Moebius测度的Poincar不等式,对数Sobolev不等式和Sobolev不等式的最佳常数的双边估计.