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Electron transport properties of TiO_2 shell on Al_2O_3 core in dye-sensitized solar cells 下载免费PDF全文
The performance of dye-sensitized solar cells(DSSCs)is strongly affected by the properties of semiconductor nanoparticles.In this work,we used TiO_2 particles prepared by TiCl_4 hydrolysis n times on Al_2O_3 films(A/T(n)),and investigated morphology,photoelectric,and electron transport properties of A/T(n).The TiO_2 shell was composed of 10-20 nm nanoparticles and the number of nanoparticles increased with increasing TiCl_4 treatment times.The highest photoelectric conversion efficiency of 3.23% was obtained as A/T(4).IMPS results indicated that electron transport rate was high enough to conduct current,and was not the dominating effect to limit the Jsc.Jsc was mainly determined by dye loading on TiO_2 and the interconnection of TiO_2.These may provide a new strategy for preparing semiconductor working electrodes for DSSC. 相似文献
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