Syntheses and Structural Characterizations of a Series of Capped Keggin Derivatives

Hydrothermal reactions of Na2 Mo O2·2H2O and NH4VO3(or V2O5) with appropriate reducing agents such as organic amines, NH2OH·HCl and Mo(CO)6 gave rise to the formation of a series of capped Keggin derivatives, [N(CH3)4]2Na3(NH4)2[(VVO4)MoVI8VIV4O36(VIVO)2]·-13H2O(1), [NH4]7[(VVO4)MoVI8VIV4O36(VIVO)2]·7H2O(2), [HN(CH2CH2)3NH][(PO4)MoV3MoVI9O36(VIVO)2]·-3[N(CH2CH2)3N]·(en)·4.5H2O(3) and [HNH2OH][NH4]2[(VVO4)MoVI8VIV4O36(VIVO)4]·24H2O(4). Single-crystal X-ray diffraction analysis revealed that the anions in 1~3 are two-capped Keggin derivatives with characteristic trans vanadium-oxygen caps, whereas the heteropoly anion in 4 is a tetra-capped α-Keggin derivative with characteristic vanadium-oxygen caps on the equatorial plane.     

18～19世纪材料试验机一瞥

最早的材料试验机只能测出载荷的大小,主要采用了杠杆原理,杠杆既是加载装置,也是测力装置。1833年德国应用力学学家Franz Joseph Ritter von Gerstner(1 756—1832)设计出了杠杆式应变计,实现了力与变形的同时测试,这在材料力学性能实验测定中具有重要意义。18～19世纪随着桥梁、铁路、锅炉、军工等工业水平的发展,人们迫切地需要材料试验机测定材料的力学性能,以确保工业产品的安全和质量。因此,建材厂、钢铁厂、设计、施工单位等根据自己的需求设计了各种各样的材料试验机,不过这一时期的试验机只是为了特定目的设计的,本身并不是产品。随着测试需求的扩大,1879年美籍（挪威移民）工程师Tinius Olsen(1845—1932)将拉伸、压缩以及横向加载集成在一台设备中,设计出了第一台通用试验机。随后,随着美国材料与试验协会（ASTM）的成立,材料测试走上了标准化道路。     

小波分析在圆柱壳结构损伤检测中的应用研究

为了检测出圆柱壳中的裂纹引起的损伤,利用sym4小波,对含裂纹圆柱壳的应变能曲线进行连续小波变换和多分辨分析,从小波系数出现局部模极大值来识别损伤的存在以及裂缝位置。通过分析和计算获得满意结果,表明此方法在圆柱壳结构损伤诊断中具有较高的应用价值。     

THE DYNAMIC BUCKLING PROBLEM CAUSED BY PROPAGATION OF STRESS WAVE IN ELASTIC

ＨａｎＱｉａｎｇ（韩强）；ＭａＨｏｎｇｗｅｉ（马宏伟）；ＺｈａｎｇＳｈａｎｙｕａｎ（张善元）；ＹａｎｇＧｕｉｔｏｎｇ（杨桂通）；ＷｕＪｉｋｅ（武际可）（ＲｅｃｅｉｖｅｄＮｏｖ．１８．１９９４）ＴＨＥＤＹＮＡＭＩＣＢＵＣＫＬＩＮＧＰＲＯＢＬＥＭＣＡＵＳ...     

轴流压气机转子叶尖泄漏涡和尾迹在静子尖区的传播

用三维激光多普勒测速系统测量了轴流压气机设计状态转子叶尖泄漏涡和尾迹在静子尖区的传播过程。结果表明,转子叶尖泄漏涡和转子尾迹周期地扫过静子通道尖区,导致该区出现周期性的流动阻塞和脉动。转子尾迹在静子通道内追赶上从前一转子叶片通道内下来的叶尖泄漏涡,二者的相互作用和掺混导致静子尖区更为复杂的二次流动。同转子尾迹相比,转子叶尖泄漏涡对静子尖区的影响更为明显和深远。静叶尾部吸力面出现流动分离,分离流同低能物质之间发生相互作用和掺混。     

木材干燥设备的质量评价

木材干燥设备的选择是一种决策过程,即对干燥设备质量的评价和排序,传统的选择方法只是依靠简单的分析比较,利用层次分析法(AHP)进行木材干燥设备的选择,建立了综合效果层次分析结构模型将决策人的思维过程数学化、系统化,从而使决策依据易于被人接受,并且更具科学性.     

聚苯乙烯的激光闪光光解

用１．０６μｍ激光对聚苯乙烯的光解进行了研究；用质谱法对激光离解碎片进行了在线检测，得到了碎片粒子的平均质量、量子要求量以及质荷比为１０４的粒子百分含量与时间关系曲线；对高分子化合物的激光离解质谱分析进行了探讨。     

Synthesis and Crystal Structure of Bis（barbiturato） triwater Complex of Copper（Ⅱ）

1 INTRODUCTION A variety of transition metal complexes with barbiturates have been prepared owing to their important roles in clinical detection and identi- fication of drug[1～5]. They have the general formula of M(Ⅱ)(barb)2L2, where M is a transition metal (Co, Cr, Zn, Cu etc), barb the anion of a substituted barbituratic acid and L an organic base, usually pyridine. In these complexes, the donor atom in the barbiturate anion is a deprotonated nitrogen atom and, the coordination …     

由氨基酸配位的铜修饰十二核钨单元构成的一维链状化合物(H3O)3{[Na3(H2O)13][(Cu(Gly)2)2(H2W12O42)]}·11H2O

The design and synthesis of organic-inorganichybrid compounds have aroused contemporary inter-est;not only owing to their diverse structures,but alsoto their potential applications in fields such as catal-ysis,medicine,analytical chemistry and photochem-i…     

A Novel Two-dimensional Layer Compound Built up by Hexapolyoxotungstates and Coordinated Sodium Chains

1 INTRODUCTION There has been extensive interest in the synthesis of heteroxometallates owing to their fascinating pro- perties and great potential applications in many fields, such as catalysis, material science, medicine and magnetochemistry as well as their unusual topo- logical properties[1～4]. Although various preparation methods have been proposed for the preparation of such materials, to find new synthetic method for novel compounds in this field is still one of the major chal- le…