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901.
The spontaneous resolution of enantiomers is an intriguing and important phenomenon in a number of research areas. Non-covalent interactions can play a key role in the process which can now be observed not only in crystals, but in liquid crystals, self-assembled monolayers, self-assembled fibres, and supramolecules self-assembled in solution. The evidence gathered in all of these areas is important for explaining the transfer of chirality from molecule to bulk, and in particular the spontaneous resolution of enantiomers. 相似文献
902.
Corma A Díaz U García T Sastre G Velty A 《Journal of the American Chemical Society》2010,132(42):15011-15021
Novel layered zeolitic organic-inorganic materials (MWW-BTEB) have been synthesized by intercalation and stabilization of arylic silsesquioxane molecules between inorganic zeolitic MWW layers. The organic linkers are conformed by two condensed silyl-arylic groups from disilane molecules, such as 1,4-bis(triethoxysilyl)benzene (BTEB), which react with the external silanol groups of the zeolitic layers. The hybrids contain micropores within the inorganic layers and a well-defined mesoporous system in between the organic linkers. An amination post-treatment introduces basic groups in the organic linkers close to the acid sites present in the structural inorganic counterpart. Through this methodology it has been possible to prepare bifunctional acid-base catalysts where the acid sites are of zeolitic nature located in the inorganic building blocks and the basic sites are part of the organic structure. The resultant materials can act as bifunctional catalysts for performing a two-step cascade reaction that involves the catalytic conversion of benzaldehyde dimethylacetal into benzylidene malononitrile. 相似文献
903.
Tiznado W Oña OB Bazterra VE Caputo MC Facelli JC Ferraro MB Fuentealba P 《The Journal of chemical physics》2005,123(21):214302
A recently proposed local Fukui function is used to predict the binding site of atomic hydrogen on silicon clusters. To validate the predictions, an extensive search for the more stable SinH (n=3-10) clusters has been done using a modified genetic algorithm. In all cases, the isomer predicted by the Fukui function is found by the search, but it is not always the most stable one. It is discussed that in the cases where the geometrical structure of the bare silicon cluster suffers a considerable change due to the addition of one hydrogen atom, the situation is more complicated and the relaxation effects should be considered. 相似文献
904.
Martínez Galera M Barranco Martínez D Parrilla Vázquez P Gil García MD 《Journal of separation science》2005,28(17):2259-2267
The potential of online trace enrichment on a highly apolar short column in LC was evaluated for the determination of pyrethroids in river water. Twelve millilitres of water samples, modified with 8 mL ACN (ACN/water 40:60, v/v), were passed through 50 x 4.6 mm ID first separation column packed with 5 microm Hypersil Elite C18. Pesticides were preconcentrated in this column while the matrix background was eluted to waste. Separation of pesticides was performed on a 3.5 microm symmetric C18 column (250 x 4.6 mm ID) with an ACN step gradient as mobile phase and fluorescence detection was used after postcolumn derivatization by using UV light. The use of photochemically induced fluorescence for detection improved sensitivity and selectivity. Quantification limits ranged from 0.05 to 0.1 microg/L and pesticide recoveries at two concentration levels (0.1 and 0.5 microg/L) were between 93.1 and 118.6%, with RSD between 2.5 and 7.5% (n = 3) in river water samples. No matrix effect was detected. 相似文献
905.
Reaction of NaN(3) with the [Cu(II)(tn)](2+) ion (tn = 1,3-diaminopropane) in basic aqueous solution yields the azido-bridged complex of formula [Cu(2)(tn)(2)(N(3))(4)] (1), which is characterized by X-ray crystallography. The structure of 1 is made up of dinuclear neutral complexes, of formula [Cu(2)(tn)(2)(N(3))(4)], resulting from the assembling of two mononuclear units through two equivalent end-on azide bridges connecting asymmetrically two Cu(tn)(N(3))(2) entities. These dinuclear units are connected through two asymmetric end-to-end N(3) bridges to form a chain of dimers. Magnetic measurements for compound 1 show weak antiferromagnetic exchange interactions between the Cu(II) ions. The magnetic data were modeled using the susceptibility expression derived for an alternating AF S = 1/2 chain. A very satisfactory fit over the whole temperature range was obtained with g = 2.1438(4), J(1) = -3.71(2) cm(-1), and J(2) = -3.10(2) cm(-1) (J(1) and J(2) are the singlet-triplet separations). This magnetic behavior differs from those observed for similar examples which were reported as having alternating ferro- and antiferromagnetic exchange interactions; thus, DFT calculations were done to understand the nature of the magnetic coupling in such asymmetric end-on and end-to-end N(3) bridges. Theoretical results show that the double asymmetric end-on bridges produce antiferromagnetic coupling while the end-to-end ones can present ferro- or antiferromagnetic coupling depending on the copper coordination sphere. 相似文献
906.
Rodríguez JC Barciela J García S Herrero C Peña RM 《Journal of AOAC International》2005,88(4):1148-1154
Multivariate experimental design has been used to optimize 2 flow-injection spectrophotometric methods for the determination of indapamide in pharmaceutical dosage forms, both pure and commercial tablets. The methods are based on the oxidation of this drug with iron (III) in acidic medium and the subsequent formation of an intensive orange-red complex between the liberated iron (II) and 2,2'-bipyridyl or 1,10-phenanthroline reagents. Plackett-Burman designs were applied as a screening method to evaluate the most significant factors with few experiments. Central composite 2(3)+ star designs were performed to evaluate the response surfaces. The methods have been fully validated and were applied successfully to the determination of indapamide in pure and pharmaceutical forms with good accuracy and precision. Therefore, the 2 proposed procedures are simple, inexpensive, and rapid flow methods for the routine determination of indapamide in pharmaceutical preparations. 相似文献
907.
1 INTRODUCTION Great attention has been attracted to design novel heterometallic molecular materials with phosphorus- and sulfur-containing ligands, owing to their abundant optical and opto-electronic properties[1~4]. Self-assembly is an efficient ap- proach to obtain heterometallic assembly by the Incorporation of two different metal components[5, 6]. We are interested in investigating the reaction between Pd(diimine)(dithiolate) and metal dip- hosphine Cu2(μ-dppm)2(MeCN)42 , the fo… 相似文献
908.
1 INTRODUCTION Since Bedard et al. reported microporous tin(IV) sulfides synthesized by hydrothermal method in the presence of organic amine in 1989[1, 2], a number of thiostannates have been synthesized using hydro- or solvothermal techniques with organic amines as tem- plates. The structures of the resulting tin(IV) sulfi- des are related to the types of organic amines. Two- dimensional polyanions of the types of [Sn3S7]2- and [Sn4S9]2-, which are denoted as SnS-1 and SnS-3, respe… 相似文献
909.
Trimetazidine and internal standard [1-(2,4,5-trimethoxybenzyl)piperazine] were isolated from plasma by protein precipitation with trifluoroacetic acid. The neutralized supernatant was separated on a C(8) column with methanol-aqueous 0.11% triethylamine adjusted to pH 3.3 with formic acid (1:4, v/v) at a flow rate of 0.85 mL/min. The separation was achieved within 8 min and the column ef fluent was transferred into an ion trap analyzer via an atmospheric pressure chemical ionization interface. The mass analyzer was used in the selected reaction monitoring mode, to enhance detection selectivity. The method was fully validated with a quantitation limit for trimetazidine of 1.5 ng/mL. The method was successfully applied to assess bioequivalence of two immediate and two modified commercially available pharmaceutical formulations containing 20 and 35 mg of trimetazidine, respectively. 相似文献
910.
The dependence of the absorption and fluorescence spectra of 1-hydroxy-2-carboxy-anthraquinone on pH and Hammett acidity have been studied. This compound exhibits phototautomerism in its uncharged and its singly-charged anionic species in aqueous media. Its ground state (pK(a)) and lowest excited singlet-state (pK(a)( *)) dissociation constants have been determined by absorptiometric and fluorimetric titrations and the assignment of the pK(a) and pK( *)(a) values to the equilibria concerned has been carefully considered. 相似文献