Hydrothermal Synthesis, Crystal Structure and Fluorescent Property of a New Zinc Carboxylate-phosphonate： [Zn3（O3PCH（CH3）COO）2（H2O）]

1 INTRODUCTION Many efforts have been devoted to the synthesis of metal organophosphonates during the past three decades because of their rich variety of structural chemistry as well as their practical or potential applications in the areas of adsorption/desorption[1, 2], catalysts[3, 4], meso-/microporous materials[5～7] and intercalation chemistry[8～16]. One encouraging deve- lopment direction is the use of phosphonic acids with bi- and trifunctional groups, such as amino, hydroxyl and…     

Application of PCA and HCA to the Structure-activity Relationship （SAR） Study of Fluoroquinolones

1 INTRODUCTION The earliest antibacterial agents used as chemo- therapeutic drugs in the 1920s were synthetic agents, such as sulponamides. Since the discovery of peni- cillin and its entry into clinical use in the 1940s, the field has been dominated over the past 50 years by natural products or their semi-synthetic derivatives. The fluoroquinolones are the only synthetic anti- bacterial agents to rival β-lactams for impact in clinical usage in the antibacterial field. In recent years, …     

Synthesis and Crystal Structure of Monochloridehepta(dimethyl sulfoxide)gadolinium(Ⅲ) di(tetraphenyl boron) Salt 〔Gd(dmso)_7Cl〕〔BPh_4〕_2

１　ＩＮＴＲＯＤＵＣＴＩＯＮＳｕｌｆｏｘｉｄｅｉｓｋｎｏｗｎｔｏｆｏｒｍｃｏｏｒｄｉｎａｔｉｏｎｃｏｍｐｏｕｎｄｓｗｉｔｈＬａｎｔｈａｎｉｄｅ（Ⅲ）ａｎｄｔｈｅｉｒｓｙｎｔｈｅｓｅｓ,ｐｒｏｐｅｒｔｉｅｓａｎｄｖａｒｉｏｕｓｐｈｙｓｉｃａｌｃｈａｒａｃｔｅｒｉｓｔｉｃｓｈａｖｅｂｅｅｎｒｅｐｏｒｔ－ｅｄ〔１～９〕．Ｈｏｗｅｖｅｒ,ｔｈｅｒｅａｒｅｓｏｍａｎｙｄｉｆｆｉｃｕｌｔｙｉｎｐｒｅｐａｒｉｎｇｔｈｅｋｉｎｄｏｆｌａｎｔｈａｎｉｄｅｃｏｍｐｌｅｘｅｓｂｅｃａｕｓｅｔｈｅａｎｉｏｎｓｕｓｅｄａ…     

Synthesis and Crystal Structure of (η~5 EtO(O)CC_5H_4)RuCoMo(μ_3-S)(CO)_8

１　ＩＮＴＲＯＤＵＣＴＩＯＮＩｎｔｈｅｄｅｖｅｌｏｐｍｅｎｔｏｆｔｒａｎｓｉｔｉｏｎｍｅｔａｌｃｌｕｓｔｅｒｓ,ａｇｒｅａｔｍａｎｙｔｅｔｒａｈｅｄｒｏｎ－ｔｙｐｅｃｈｉｒａｌｃｌｕｓｔｅｒｓｈａｖｅｂｅｅｎｓｙｎｔｈｅｓｉｚｅｄ．Ｏｎｅｉｍｐｏｒｔａｎｔｒｅａｓｏｎｉｓｔｈａｔｓｕｃｈｃｌｕｓｔｅｒｓｃａｎｂｅｐｏｔｅｎｔｉａｌｌｙｕｓｅｄａｓａｓｙｍｍｅｔｒｉｃｃａｔａｌｙｓｔｓｉｎｔｈｅｐｒｏｃｅｓｓｗｈｉｃｈｉｓｔｒｕｌｙｃｌｕｓｔｅｒ－ｃａｔ－ａｌｙｚｅｄ〔１,２〕．Ｈｏｗｅｖｅｒ,ｔ…     

Crystal Structure of Tris(2,2'-bipyridine)nickel(II) Tetrachlorozincate

1　INTRODUCTIONThe coordination chemistry oftransition metalcomplexeshasbecomeofremark able interestin recentyears.Sotoftetal.reported the structure of Ni( CH3CN) 6·Zn Cl4 〔1〕.Recently,Shyu etal.reported the structure of〔 Ni( bipy) 3〕〔 Fe( CN) 5 ( NO)〕· 3 H2 O〔2〕.Herein we reportthe structure oftitle complex〔 Ni( bipy) 3〕〔 Zn Cl4 〕 which issimilarto theformertwo complexes.Itisvery interesting to synthesizebimetallic compoundsfor both theoreticalstudy and practicalapp…     

Synthesis and Crystal Structure of α-( N-Protected a mino)β- lactam Derivative of 1 ,5-Benzothiazepine

１　ＩＮＴＲＯＤＵＣＴＩＯＮＲｅｃｅｎｔｌｙ,ａｎｕｍｂｅｒｏｆｄｅｒｉｖａｔｉｖｅｓｏｆｂｅｎｚｏｔｈｉａｚｅｐｉｎｅｈａｖｅｂｅｅｎｐｒｅｐａｒｅｄａｎｄｓｔｕｄｉｅｄｆｏｒｔｈｅｉｒｐｈａｒｍａｃｏｌｏｇｉｃａｌａｃｔｉｖｉｔｉｅｓ〔１５〕．Ｉｎｏｕｒｐｒｅｖｉｏｕｓｗｏｒｋ,ｗｅｈａｖｅｉｎｃｏｒｐｏｒａｔｅｄｔｈｅβｌａｃｔａｍｒｉｎｇｉｎｔｏ１,５ｂｅｎｚｏｔｈｉａｚｅｐｉｎｅｂｙｒｅａｃｔｉｏｎｏｆ１,５ｂｅｎｚｏｔｈｉａｚｅｐｉｎｅｗｉｔｈｓｏｍｅａｃｙｌｃｈｌｏｒｉｄ…     

Pitzer混合参数对HCl-KCl-H2O体系25 ℃时溶解度预测的影响

Pitzer混合参数对HCl-KCl-H2O体系25 ℃时溶解度预测的影响     

Synthesis and Crystal Structure of [La（BTC）（H2O）6]n

1 INTRODUCTION desired topologies owing to their rich coordination modes[8~12] and we have been exploring the chemi- The assembly of metal-organic infinite frame- stry of coordination polymers constructed by tran- works via coordination of metal ions with multifunc- sition metals and benzoic multicarboxylic acids[13~16]. tional organic ligands is a field of increasing inte- In addition, lanthanide ions have high affinity for rest[1~4]. A rational designed and predictable coor- hard donor a…     

Correlation between Chromatograph Capacity Factors and Structural Parameters of Indole Derivatives

1 INTRODUCTION thods with which the retention factor of a series of compounds could be predicted accurately[1, . In 2] The capacity factor of reversed phased high per- addition, indole and its derivatives have been widely formance liquid chromatograph (RP-HPLC) is a used in the synthesis of medical intermediate, co- basis for quantifying chromatograph peaks and se- loring agent and pesticide etc. Dai et al. have repor- parating compounds. And it has been universally ac- ted the relation…