Hydrothermal Synthesis, Crystal Structure and Fluorescent Property of a New Zinc Carboxylate-phosphonate： [Zn3（O3PCH（CH3）COO）2（H2O）]

1 INTRODUCTION Many efforts have been devoted to the synthesis of metal organophosphonates during the past three decades because of their rich variety of structural chemistry as well as their practical or potential applications in the areas of adsorption/desorption[1, 2], catalysts[3, 4], meso-/microporous materials[5～7] and intercalation chemistry[8～16]. One encouraging deve- lopment direction is the use of phosphonic acids with bi- and trifunctional groups, such as amino, hydroxyl and…     

Structure of Non-stoichiometric Sr6Gd0.61Sc1.39（BO3）6 Crystal

1 INTRODUCTION With the increasing interest in diode-pumped solid state lasers, researches on more efficient new materials for diode pumping become more important. The double borates are a type of excellent laser gain media, for example, Nd3 -doped RAl…     

Changing Rules of Bonding Electron Pair Correlation Energies of CH3X （X = F, OH, NH2） Systems

1 INTRODUCTION It has been known that the electron correlation energy of molecular systems was, and still is, one of the most serious bottleneck problems to the chemis- try accuracy of computational quantum chemistry. Since L鰓din[1] gave the definition …     

Synthesis,Crystal Structure and Cytotoxicity Evaluation of 2-Phenoxy-4H-spiro{naphtho[2,3-e][1,4,2] oxazaphosphinane-5,10-dione,1'-cyclohexane} 2-Oxide

1 INTRODUCTION The quinone structure is common in numerous natural products that are associated with antitumor, antibacterial, antimalarial, and antifungal activities[1]. A variety of heterocyclic quinones containing dif- ferent heteroatom substituents could exhibit such activities through different actions and sometimes even improve the activities[2～5]. On the other hand, organophosphorus compounds continue to receive widespread attention due to their ubiquity in biological systems[6, 7]…     

Hydrothermal Synthesis,Crystal Structure and Magnetic Properties of a Cobalt(II) Coordination Polymer Assembled by 4-Sulfophthalate and 4,4'-Bipyridine

1 INTRUDUCTION The rational design and synthesis of metal-direc- ted supramolecular framework have received much attention in coordination chemistry because of their potential applications in catalysis, molecular selec- tion, non-linear optics, ion exchange and microelec- tronics[1～4]. During the lastdecade, many high-di- mensional coordination complexes have been de- signed and prepared through molecular self-as- sembly process[5～10]. The construction of open metal organic framework, s…     

High Temperature Phase Transitions in Na_xCoO_2 Materials

1 INTRODUCTION In recent years, much attention has been focused on the NaxCoO2 system due to its notable properties and potential technologic applications as a cathode material in high-energy density, reversible solid state battery systems[1, 2]. Recently, large thermoelectric power[3～6] in NaxCoO2 and superconductivity (～4 K) in hydrated NaxCoO2yH2O (x = 0.35, y = 1.33) ma- terial have been observed[7]. This hydrated layered phase is the first 3d-transition metal oxide with superco…     

Synthesis and Crystal Structure of (C_6N_3H_(18))_2Ti_4O_4(C_2O_4)_7·4H_2O

1 INTRODUCTION The open-framework inorganic materials have been synthesized before the early 1980s[1]. Parti- cularly, metal phosphates have been investigated widely during the past few years[2, 3]. In recent years, considerable efforts have been devote…     

Synthesis, Crystal Structure and Magnetic Properties of Cobalt(II) Complex Involving Imino Nitroxide Radicals

1 INTRODUCTION The synthesis and study of transition metal com-plexes incorporating organic free radicals have arou-sed great interest in the field of molecular magne-tism[1]. Nitronyl nitroxide radicals (NITR), stable or-ganic radicals, have been widely used as molecularunits in the design and construction of magnetic ma-terials[2～5]. These radicals are especially attractivedue to that their donor atoms can assemble an exten-ded coordination geometry with changing magneticcoupling. A…     

配合物[Co2(EGTB)Cl2]•(BF4)2•5H2O与DNA相互作用的研究

用紫外光谱法、荧光光谱法、黏度法、凝胶电泳法研究了双核钴(II)配合物[Co2(EGTB)Cl2]•(BF4)2•5H2O和DNA的相互作用, 在pH＝7.2的缓冲体系中, 求得配合物与DNA的结合常数. 结果表明, 配合物在接近生理条件下能有效地断裂pBR322DNA, 同时可使DNA的粘度增加, 使EB-DNA体系的荧光强度降低. 配合物与DNA的荧光光谱和紫外光谱表明, 配合物与DNA的作用既存在部分插入结合又存在静电结合模式.     

Ru膜上Pt层的自发沉积及其在电化学表面增强红外光谱中的应用

采用自发沉积法在Ru膜上生成超薄Pt层(简称Ru/Pt膜), 即在开路状态下将电化学还原后的Ru膜浸于除去氧的H2PtCl6溶液中进行自发沉积. 电化学伏安法测量表明, 随着电还原-自发沉积循环次数的增加, 该Ru/Pt膜电极所含Pt组分增加, 且CO吸附层的电氧化峰电位较Pt膜电极上的明显负移. 应用现场衰减全反射表面增强红外光谱法(ATR-SEIRAS)可轻易检测到在该膜电极Pt和Ru位上吸附CO的振动谱峰. 所制Ru/Pt膜电极不仅对CO的电催化氧化具有协同效应, 还可应用于现场ATR-SEIRAS的研究中.