青蒿素及其一类物的结构和合成 XXI: 青蒿酸的全合成

青蒿酸与抗疟新药青蒿素共存于植物青蒿中, 具有显著的抗菌活性, 它的结构和立体化学已经确定, 并被用作合成青蒿素及其一类物的原料, 本文报导以R-(+)-香草醛为原料合成青蒿酸。     

Multilayer-based soft X-ray polarimeter at the Beijing Synchrotron Radiation Facility

A compact high precision eight-axis automatism and two-axis manual soft-ray polarimeter with a multilayer has been designed, constructed, and installed in 3W1B at the Beijing Synchrotron Radiation Facility (BSRF). Four operational modes in the same device, which are double-reflection, double-transmission, front-reflection-behind-transmission and front-transmission-behind-reflection, have been realized. It can be used for the polarization analysis of synchrotron radiation. It also can be used to characterize the polarization properties of the optical elements in the soft X-ray energy range. Some experiments with Mo/Si and Cr/C multilayers have been performed by using this polarimeter with good results obtained.     

VUV/EUV标准探测器装置和传输标准探测器的标定

对研制的安装在合肥国家同步辐射实验室(NSRL)计量光束线上的VUV/EUV标准探测器装置进行了传输标准探测器的首次标定工作.实验选取了3个能点17.625nm,6.8nm和92nm,在这3个能点处分别标定光电二极管,得到其相应的量子效率.结果表明在同一能点多次标定结果的重复一致性很好,相对标准偏差在1%—14%的水平;但是与美国国家标准计量局(NIST)标定过的光电二极管的量子效率比较,短波17.625nm的标定结果较好,而6.8nm和92nm波长的结果差距偏大.偏差主要来自光源稳定性和光谱纯净度的影响.     

Nanoscale carbon tubules deposited in anodic aluminium oxide template： a study of soft x-ray transmission

Well-aligned, catalyst-free nanoscale carbon tubules array was prepared by organic compound vapour deposition method using anodic aluminium oxide (AAO) as a template. The experiment of soft x-ray channelling in such carbon tubules array deposited in AAO template was performed at Beijing Synchrotron Radiation Facility. The transmission of x-rays in carbon tubules array with AAO template support was found even higher than that in bare AAO template at high-energy part of energy spectrum though the porous area of the former was smaller than that of the latter. A qualitative explanation is presented to interpret our results.     

Bifurcation and stability of an improved time-delayed fluid flow model in internet congestion control

Based on the fluid flow time-delayed model proposed by Misra et al in internet congestion control, one modified time-delayed model is presented, where the influence of the communication delay on the router queue length is investigated in detail. The main advantage of the new model is that its stability domain is larger even without an extra controller. By linear stability analysis and numerical simulation, the effectiveness and feasibility of the novel model in internet congestion control are verified.     

生物物理新技术在ATP合成酶超分子结构中的应用

现代物理技术与方法的发展为腺苷三磷酸(ATP)合成酶分子的研究提供了丰富而有效的手段。 介绍了ATP合成酶研究中常用的物理技术与方法如质谱技术、 核磁共振技术、 X射线衍射技术、 红外光谱和紫外光谱技术的物理原理及其在ATP合成酶研究中的应用, 并重点介绍了新兴非常规手段如原子力显微镜、 荧光共振能量转移技术在ATP合成酶研究中的最新研究成果; 通过对比诸多技术与方法近年来在国内外研究中的进展情况, 对各种技术与方法的优缺点进行了阐述。     

Controlling projective synchronization in coupled chaotic systems

In this paper, a new method for controlling projective synchronization in coupled chaotic systems is presented. The control method is based on a partially linear decomposition and negative feedback of state errors. Firstly, the synchronizability of the proposed projective synchronization control method is proved mathematically. Then, three different representative examples are discussed to verify the correctness and effectiveness of the proposed control method.     

一次加料法合成有机硅复合乳液

采用一次加料法合成了含氢聚甲基硅氧烷／丙烯酸丁酯／羟甲丙烯酰胺复合乳液,探讨了ＰＨＭＳ,引发剂用量和反应温度对反应速率,聚合稳定性、乳液粒长和成膜性的影响,得到了该反应的表观活化能Ｅａ＝１３２．７７Ｋｊ／ｍｏｌ及Ｒｐ∝「ＰＨＭＳ」＾１．３９「ＡＰＳ」＾０．８３,所得乳液具有优良的性能。     

DNA分子链的初始高度及其压弹性的原子力显微镜研究

用接触和轻敲两种模式下的原子力显微术研究了空气中的DNA分子,探讨了成像模式对高度测量的影响,考证了DNA的初始高度.结果表明:文中所得DNA初始高度与理论值较接近.在参照DNA初始高度的基础上,通过检测DNA双链的弹性形变量,研究了DNA分子在直径方向的压缩性质.结果表明:空气中固定在云母表面的DNA分子具有很好的压弹性,在外力作用下DNA的径向形变可达到60%以上;当外力撤销后,其形变可以不同程度地恢复.分析了25段DNA分子上125个点的高度与成像力的关系,并由此初步估算了DNA分子的弹性常数.     

低亚表面损伤的YCOB晶体超精密抛光

通过选择合适的研磨剂、抛光垫以及抛光材料,采用机械抛光与CMP抛光相结合的方法对应用于高激光损伤阈值的薄膜基体材料YCOB晶体进行表面加工.通过优化研磨抛光工艺后得到超光滑晶体表面,样品表面在125μm×94μm的范围内粗糙度RMS值达到0.6 nm,同时具有非常低的亚表面损伤层,经过超声清洗和有机溶剂刻蚀后,在高倍显微镜下无明显划痕.