光谱法水质监测仪器和方法国内专利状况分析

水质动态数据可以为水环境可持续发展提供数据支撑,而水质监测仪器和方法的发展是获取准确水质数据和制定污染防治规划的关键. 目前光谱法水质监测仪器和方法相关专利的发展方向尚不明确. 基于万方数据知识服务平台的专利数据库,检索获得1993年至2022年在国内申请的光谱法水质监测相关仪器和方法的专利数据,对专利的申请情况、专利授权的仪器和方法所涉及的仪器类型、专利权申请主体及分布区域等方面进行比较分析,通过比较研究揭示当前国内光谱法水质监测仪器和方法的发展趋势,以期为政府、科研机构及企业相关人员制定光谱法水质监测仪器及方法的技术研发等提供决策依据.     

金属表面结构的变角XPS特征

采用仅改变阳极高压以获得不同激发光子流强的变角Ｘ光激发电子能谱（ＸＰＳ），研究Ａｌ、Ｆｅ、Ｃｕ、Ｔａ及Ｗ中光电子峰的表面结构效应。实验结果表明，在面心立方的Ａｌ及体心立方的Ｔａ和Ｗ中均显示表面结构产生的衍射效应，而在Ｆｅ和Ｃｕ中未出现表面结构效应；所出现表面结构效应的差异与阳极高压及光子流的能量有紧密的关系。同时，在实验高压范围内存在一个产生表面结构效应的阳极电压阈值。文中就观察到的表面结构效应之差异的可能机制进行了初步探讨。     

Vibration analysis of a rod with complex boundary conditions

This paper deals with the forced longitudinal vibration of a rod carrying a concentrated mass and supported by a spring at one end. The vibration of the rod is excited by the motion of the support point at the other end. Since the boundary conditions of the problem are complex and it is necessary to consider the damping, we determine only the steady state periodic solution. First the linear system is analysed; then the material nonlinearity is considered and the approximate analytic solution of nonlinear partial differential equation with nonlinear boundary conditions is obtained by the perturbation method.     

铝和铝氟病鸡模型全血骨元素和血清生化骨矿含量骨形态学的相关研究

复制了铝危害和铝氟病鸡模型。将100日龄84只雄性种鸡随机分为7个组,毒物加进配合饲料自由摄食,实验3个月。结果表明,高铝、高氟、高氟铝组在实验3周内全血多种元素和7周内的血清生化物质含量及其相关性便发生显著变化,实验13周性成熟后出现逆转并接近正常。均引骨骼元素含量、骨细胞、骨胶元、骨组织形态、骨矿代谢、骨塑形和骨骼力学机能的病理变化。性成熟后饲料加氟与未加氟各3个组的全血铁、磷、血清钙、GRT才出现分异,并与骨矿代谢动态参数的分异相吻合。表晨本实验性成熟前诸多病变主要是铝危害引起。铝可较长期使全血锌和和骨锌含量下降。全血元素含量和相关性的变化是受机体内环境影响较大的动态变化过程。骨代谢联系着广泛的生物无机化学基础。性成熟后高氟、高氟铝、高铝的危害尚有各自的特点。     

Analysis of the secondary stability of compressible boundary layer flows over a two-dimensional plate

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二维平板可压缩边界层的二次稳定性分析

本文在二维可压缩边界层中应用Floquet分析,建立了控制次谐波稳定性的方程组,研究在二维可压缩边界层转捩过程中二维有限振幅的T-S波对三维线性小扰动的作用,并计算了来流马赫数对次谐波的产生和发展情况的影响,从中可以看出二维和三维扰动波相互作用对二维可压缩流动边界层的发展过程所产生的影响.     

EFFECT OF ADSORPTION ON THE VISCOSITY OF DILUTE POLYMER SOLUTION*

Careful measurements of the dilute solution viscosities of polyethylene glycol and polyvinylalcohol in water were carried out. The reduced viscosities of both polymer solutions plot upward curves atextremely dilute concentration levels similar to the phenomena observed for many polymer solutions in theearly 1950's. Upon observation of the changes of the flow times of pure water in and the wall surfacewettability of the viscometer after measuring solution viscosity, a view was formed that the observed viscosityabnormality at extremely dilute concentration regions is solely due to the effect of adsorption of polymerchains onto the wall surface of viscometer. A theory of adsorption effect based on the Langmuir isothermswas proposed and a mathematical analysis for data treatment was performed. The theory could adequatelydescribe the existing viscosity data. It seems necessary to correct the viscosity result of dilute polymersolutions measured by glass capillary viscometer by taking into account the effect of adsorption in all cases.     

求强非线性自治振子同宿轨的广义Padé逼近方法

在经典Padé逼近理论的基础上进行了相应推广,提出了广义Padé逼近方法,并针对强非线性自治振子同宿轨的求解问题,利用双曲函数构造了一种新的广义Padé逼近式.首先,该广义Padé逼近式有着较简单的泰勒展开式,与现有的Padé逼近式相比,在计算同阶逼近时,计算量更少;其次,该方法在强非线性时,依然有着较高的精度;第三,该方法并不局限于某些特定的系统,而是有着较广的适用范围.因此对于广义Padé逼近方法的研究具有一定的实际意义和理论价值.