Synthesis, Crystal Structure and Fungicidal Activity of (E)-2-[(4-tert-Butyl-5- (4-methoxybenzyl)thiazol-2-ylimino)methyl]phenol

The title compound(E)-2-(4-tert-butyl-5-(4-methoxybenzyl)thiazol-2-ylimino)me-thylphenol was synthesized by the reaction of 5-(4-methoxybenzyl)-4-tert-butylthiazol-2-amine with salicylaldehyde=and its crystal structure was determined by single-crystal X-ray diffraction.The crystal belongs to the monoclinic system=space group P21/c with a=5.9362(8)=b=11.5070(15)=c=29.460(4)=β=97.326(3)°=V=1995.9(5)3=Z=4=F(000)=808=C22H24N2O2S=Mr=380.49=Dc=1.266 g/cm3=S=1.031=μ=0.181 mm--1=the final R=0.0474 and wR=0.1441 for 4327 observed reflections(I > 2σ(I)).Intramolecular O-H…N hydrogen bond is observed in the crystal.The preliminary bioassay showed that the title compound exhibits 95% inhibition rate against Rhizoctonia solani at the test concentration of 500 mg/L.     

应用腙作为配体的铜催化二芳醚合成反应

一种简单易得的腙,2-吡啶醛 1-苯基腙 （1）,能够作为有效配体,极大地促进碘化铜催化的芳基溴与酚的C–O偶联反应。该偶联反应条件温和（二氧六环为溶剂、磷酸钾为碱、90–100 0C 的反应温度）,适用于各种芳基溴（电中性、贫电子和富电子）和酚（电中性和富电子）的底物,能够相容一些碱敏感官能团如酯基、醛基和羰基等。     

5-雄烯-3β, 7α, 17β-三醇和5-雄烯-3β, 7β, 17β-三醇的合成

以5-雄烯二醇为原料,用微生物转化的方法合成了两个重要的神经甾体5-雄烯-3β, 7α, 17β-三醇和5-雄烯-3β, 7β, 17β-三醇。所用菌种总枝毛霉为我们自己筛选,并首次应用于5-雄烯-3β, 7α, 17β-三醇和5-雄烯-3β, 7β, 17β-三醇的合成中。     

Synthesis and Characterization of a One-dimensional Chain Polymer{[Cu(4-CPOA)(3-PyOH)_2(H_2O)_2]·H_2O}_n

1 INTRODUCTION Molecular self-assembly of coordination architec- tures is a rapidly developing research area of supra- molecular chemistry in recent years[1～6]. 4-Carboxy- phenoxyacetic acid (4-CPOAH2) is a multidentate flexible and rigid ligand, which is capable of coor- dinating to metal centers in versatile binding fashi- ons and can also form regular hydrogen bonds as both hydrogen-bond donors and acceptors. To date, only Na(I), Ni(II), Mn(II) and Co(II) complexes con- taining…     

线上零售商销售策略差异性分析及策略组合优化模型

随着线上零售业的快速发展,线上零售策略优化研究对提高线上零售商决策水平,维持线上零售业继续健康发展具有积极意义.在概述关于线上零售策略优化已有研究成果的基础上,利用数学方法严格解析了两种常用销售策略之间的联系和差异,在考虑冲量(市场份额)对消费者线上购买行为和销售量的影响的条件下,建立了线上零售商销售策略组合优化问题的非线性混合整数规划模型,并基于模型分析了零售商应该采用的销售策略优化方案.     

基于主成分分析的广东省邮电业发展状况研究

通过主成分分析方法,选取2006、2011和2016年广东省各市邮电业务数据,对广东省21个地级市的邮政和通信事业发展状况进行分析和发展水平层次划分,从时间和地域空间两个维度对广东省各地区邮电业发展情况进行排名分组.结果表明,当前广东省各地区邮电业发展状况存在显著的地区差异.     

高效且环境友好的催化剂—CMC负载稀土催化剂在一锅法合成咪唑类衍生物中的应用

CMC负载稀土催化剂是由CMC和异丙氧基稀土制得。这种固体Lewis酸催化剂被用在比较温和的条件下合成取代的咪唑类化合物。相比于昂贵的稀土Lewis酸Ln(OTf)3，廉价的CMC负载稀土催化剂也显示出了很高的催化活性。此外，这种催化剂还具有易于回收和重复使用五次以上没有明显失活的优点。     

Hydrothermal Synthesis and Crystal Structure of a New Supramolecular Channel Framework Based on Cu Complexes and Polyoxovanadate:[Cu(I)(phen)_2]_5[HV_(15)O_(36)(Cl)]_(0.65)[H_3V_(16)O_(38)(Cl)]_(0.35)·2H_2O

1 INTRODUCTION In the past years, polyoxovanadates have attracted extensive interest in solid-state material chemistry owing to the formation of mixed-valence com- pounds that exhibit rich electronic and magnetic properties relevant to catalysis, medicine and ma- terials science[1～4]. The following polyoxovanadates have been found and structurally characterized: [V5O14]3-, [V6O19]8-, [V10O28]6-, [V12O32]4-, [V13- O34]3-, [V15O36]5-, [V15O42]9-, [V17O42]4-, [V18- O42]12-, [V16O38]7…     

Synthesis and Structure Characterization of Aqua-(μ_2-carbonato-O,O'''')-(2,2''''-bipyridyl)-copper(Ⅱ) Dihydrate

1 INTRODUCTION The class of materials of carbonato metal- organic compounds has received much attention as a consequence of their potential applications in biochemical and environmental protection[1～3]. Many carbonato compounds of Cu2+, Co3+ and Zn2+ etc. have been studied[4～6]. The carbonate anion is a versatile bridging ligand, which can bind metal cations in different modes to generate mononuclear, binuclear, trinuclear, tetranuclear and even 1D, 2D and 3D structures[4, 7, 8]. We…