高速三维边界层的横流不稳定性

用两点四阶差分格式研究旋转圆锥超音速三维边界层的横流不稳定性和壁面冷却对稳定性的影响数值结果表明，与二维边界层相比横流使三维边界层第一模式增长率增大，对第二模式影响很小；Ｍｅ＜４３第一模式最不稳定，Ｍｅ＞４３第二模式最不稳定；三维边界层最不稳定第二模式是三维波，二维边界层则为二维波；壁面冷却对第一模式起稳定作用，对第二模式起不稳定作用     

晶化温度对SAPO-34结构稳定性的影响

用二乙胺结构导向剂, 分别在473和573 K水热晶化得到两种SAPO-34分子筛材料. SEM和XRD结果表明, 晶化温度升高, SAPO-34晶粒增大, 结晶度提高, 比表面积和孔径增大. 升高晶化温度, 提高了样品的最高焙烧和水蒸汽热处理承受温度.     

双帽羧桥三核钨(Ⅳ)原子簇化合物的结构研究

用新的合成途径,以Na_2WO_4·2H_2O为原料,Zn粉为还原剂,合成了三个簇合物(1)[W_3O_2(CH_3CO_2)_6(H_2O)_3]ZnBr_4·8H_2O,(2)H(W_3O_2(CH_3CO_2)_9]·5H_2O,(3)H_2Na_3[W_3O(CCH)_3(CH_3CO_2)_6(H_2)O][H_2W_(12)O_(40)]·13.5H_2O。在测定晶体结构和综合有关文献基础上,说明了反应过程,并进行了EHMO量化计算,探讨了该类型化合物的簇骼成键性质和相关的物理,化学性质。     

水溶性高分子链中磺酸盐基团含量的电导滴定测定法

研究了N ,N ,N 三甲基十六烷基溴化铵 (CTAB)与丙烯酰胺 (AM) 2 丙烯酰胺基 2 甲基丙磺酸钠盐(NaAMPS)二元共聚物P(AM co NaAMPS)的复合作用 .在复合作用过程中 ,由于不断释放出高导电性的无机盐小离子 ,故随着表面活性剂的加入 ,聚电解质水溶液的电导率不断增大 .当采用较低浓度 (0 0 0 1mol·L- 1 )且使二者的离子等摩尔量发生复合作用时 ,体系的电导率会发生明显的转折 .利用电导率的这一转折性变化 ,建立起了复合作用电导滴定法测定共聚物P(AM co NaAMPS)分子链中磺酸盐单体NaAMPS含量的新方法 .与元素分析进行比较的结果表明 ,上述复合作用电导滴定法可作为测定水溶性大分子链中磺酸盐单体含量的方便而又准确的方法 ,而且预计还可用作为测定水溶性大分子链中其它离子性基团含量的简捷方法     

Synthesis and Crystal Structure of a New Complex {[Co~(Ⅲ)L_2]·[Co~(Ⅱ)(H_2O)_6]_(0.5)·2.25H_2O}_4 (H_2L = N-(2-Hydroxyphenyl)salicylidenimine)

The reaction of Co(OAc)2·4H2O with the Schiff base H2L in a methanol solution affords the red crystals of {[CoIIIL2]·[CoII(H2O)6]0.5·2.25H2O}4 1 (H2L = N-(2-hydroxyphenyl) sali-cylidenimine). The molecular and crystal structures were determined by single-crystal X-ray diffraction. The crystal is of monoclinic, space group P21/n, C104H114Co6N8O37, Mr = 2421.61, a = 10.625(3), b = 16.335(4), c = 15.265(4) , β = 102.990(4)o, V = 2581.6(11) 3, Z = 1, Dc = 1.558 g/cm3, μ = 1.034 mm-1, F(000) = 1252, R = 0.0414 and wR = 0.1167 for 5889 reflections. The Co(III) atom is six-coordinated by two nitrogen atoms and four oxygen atoms of two tridentate L ligands. The abundant hydrogen bonding interactions extend the complex into a one-dimensional supra-molecular framework. The uncoordinated water molecules act as space-fillers and consolidate the whole architecture through the hydrogen bonding interactions.     

R-T不稳定性发展的二维和三维对比研究

 应用摄动方法研究不同密度流体交界面上的Rayleigh-Taylor（R-T）不稳定性问题，分别研究了二维（2D）与三维（3D）R-T不稳定性的线性与非线性增长，并进行了对比。得出的结论为：（1） 三维不稳定性的线性增长比二维情况要快，且同维度上相同的初始扰动波长，其时间增长指数受另一维度上的初始波长影响。（2） R-T不稳定性发展在考虑了非线性增长的影响之后，二维与三维扰动增长的图像也不一样。     

The Korteweg-de Vires equation for the bidirectional pedestrian flow model considering the next-nearest-neighbor effect

This paper focuses on a two-dimensional bidirectional pedestrian flow model which involves the next-nearest-neighbor effect. The stability condition and the Korteweg-de Vries （KdV） equation are derived to describe the density wave of pedestrian congestion by linear stability and nonlinear analysis. Through theoretical analysis, the soliton solution is obtained.     

基于光纤多狭缝的亚像元光谱采样及复原

光栅光谱仪的分辨率与其光通量之间存在折衷的关系。亚像元-反卷积序列光谱图复原方法可以在不降低光通量的前提下提高其分辨率。为使该方法能够应用在采用阵列探测器的小型便携式光谱仪上,提出了一种光纤多狭缝的设计方法,以获取亚像元重建所必须的序列光谱图。该方案的主要优点是无需微动机构,没有显著的像差变化,有利于简化算法。     

A double constrained robust capon beamforming based imaging method for early breast cancer detection

Ultra-wideband （UWB） microwave images are proposed for detecting small malignant breast tumors based on the large contrast of electric parameters between a malignant tumor and normal breast tissue. In this study, an antenna array composed of 9 antennas is applied to the detection. The double constrained robust capon beamforming （DCRCB） algorithm is used for reconstructing the breast image due to its better stability and high signal-to-interference-plus-noise ratio （SINR）. The successful detection of a tumor of 2 mm in diameter shown in the reconstruction demonstrates the robustness of the DCRCB beamforming algorithm. This study verifies the feasibility of detecting small breast tumors by using the DCRCB imaging algorithm.     

Synthesis and Crystal Structure of a New Tetracopper Complex [Cu(H_2O)_3Cu(HCDTA)]_2(ClO_4)_2·H_2O

A new tetracopper complex [Cu(H2O)3Cu(HCDTA)]2(ClO4)2·H2O (CDTA = transcyclohexane-1,2-diamine-N,N,N′,N′-tetraacetate) has been prepared and characterized by singlecrystal X-ray diffraction analysis. The crystal adopts space group C2/c with a = 16.990(10), b = 9.150(5), c = 29.318(17) , β = 104.289(9)°, V = 4417(4) 3, Z = 4, C28H52Cl2Cu4N4O31, Mr = 1265.80, Dc = 1.904 g/cm3, μ = 2.130 mm-1, F(000) = 2584, T = 293(2) K, the final R = 0.0328 and wR = 0.0809 for 4938 observed reflections (I 2σ(I)). The tetracopper units are interconnected by weak covalent bonds into a layered structure.