排序方式: 共有105条查询结果,搜索用时 159 毫秒
41.
测试了不同掺杂浓度和不同厚度下Yb3+磷酸盐玻璃的吸收光谱、荧光光谱和荧 光寿命,计算了积分吸收截面、吸收截面、受激发射截面、自发辐射寿命以及荧光有效线宽等光谱参数,讨论了荧光俘获效应对Yb3+磷酸盐玻璃光谱性质的影响.结果表明荧光俘 获效应随样品厚度和掺杂浓度的增加而增大.由于荧光俘获效应的存在使得测量的Yb3+磷酸盐玻璃荧光寿命明显长于计算的荧光寿命,在0.2mol%Yb2O3低掺 杂浓度下
关键词:
荧光俘获
掺镱磷酸盐玻璃
荧光光谱 相似文献
42.
云南凤庆绿茶自溶液中对Ag^+的吸附 总被引:10,自引:0,他引:10
研究了凤庆绿茶自溶液中对Ag+的吸附特性。绘制了吸附速度曲线,并求出了Lang-muir和Freundlich方程中的有关参数。考察了温度、pH值对吸附的影响以及酸、碱和不同配合剂对Ag+的解吸附作用。结果表明,吸附具有以化学吸附为主的Langmuir单分子层吸附特征,0.1mol/LNa2S2O3溶液可定量地解吸Ag+ 相似文献
43.
制备了掺Er3+重金属氧氟硅酸盐玻璃,研究了玻璃的吸收光谱和荧光光谱性质,应用Judd Ofelt理论计算了强度参数Ωt(t=2,4,6)、Er3+离子的振子强度、自发辐射跃迁几率、荧光分支比和辐射寿命等光谱参数。应用McCumber理论,计算了能级4I13 2→4I15 2跃迁的受激发射截面。结果表明:掺Er3+重金属氧氟硅酸盐玻璃具有较宽的荧光半高宽和较大的受激发射截面。对Er3+离子在不同玻璃基质中带宽特性的比较发现,掺Er3+重金属氧氟硅酸盐玻璃的带宽特性与碲酸盐和铋酸盐玻璃相当,大于磷酸盐、锗酸盐和硅酸盐玻璃。 相似文献
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45.
Spectral properties of erbium-doped heavy metal oxyfluoride silicate glasses for broadband amplification 总被引:1,自引:0,他引:1
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Erbium-doped glasses showing a wide 1.55μm emission band are reported in a novel heavy metal oxyfluoride glass system SiO_2-PbO-PbF_2 and their optical properties such as emission spectra, fluorescence lifetime and the refractive index have been investigated. The broad and flat {}^4I_{13/2}→{}^4I_{15/2} emission of Er^{3+} ions around 1.55μm can be used as host materials for potential optical amplifiers in wavelength-division-multiplexing network system. We find that with increasing PbF_2 content in the glass composition, the fluorescence full width at half maximum and fluorescence lifetime of the {}^4I_{13/2} level of Er^{3+} increase, while refractive index and density decrease. 相似文献
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47.
玻璃的最大声子能量决定稀土离子的上转换发光强度,但本研究发现:Yb3+/Er 3+共掺锗碲酸盐玻璃在980nm LD抽运下,上转换荧光强度随着Bi2O 3对PbO的取代和碱 金属离子半径的增大而明显增强.而Raman光谱显示基质玻璃的最大声子能量并不随Bi 2O3对PbO的取代和碱金属离子半径的增大而变化,但玻璃的最大声子密 度随着Bi2O3对PbO 取代和碱金属离子半径的增大而降低.从玻璃无辐射跃迁概率的角度,通过分析表明,最大 声子密度的降低是玻璃上转换发光强度增强的主要原因. 相似文献
48.
Solid-state blue and green light sources are desirablefor high-density optical storage, color displays, optoelec-tronics, and medical diagnostics[1-4]. Tm3+ is the moststudied in rare-earth ions for blue laser operation basedupon upconversion[5,6]. One approach to improving theluminescence efficiency of Tm3+ is to co-dope it withother rare-earth ions[7]. The choice of host materials is avery important factor to obtain high efficient upconver-sion emission. In this case, the main goal of the c… 相似文献
49.
研究了Er3+掺杂重金属氧氟硅酸盐玻璃的吸收光谱、上转换光谱和拉曼光谱,分析了重金属氧氟硅酸盐玻璃中Er3+的上转换发光机理. 结果表明:通过975nm的激光二极管激发,在室温下同时观察到蓝光(411nmj)、绿光(525和543nm)和红光(655nm),分别是由于Er3+离子2H9/2→4I15/2, 2H11/2→4I15/2, 4S3/2→4I15/2, 和4F9/2→4I15/2跃迁. 随Er2O3浓度的增加,蓝光、绿光和红光的发光强度都增强,上转换发光机理主要涉及能量转移和激发态吸收,强烈的绿
关键词:
Er3+离子
重金属氧氟硅酸盐玻璃
上转换光谱
发光机理 相似文献
50.
Intense frequency upconversion fluorescence of Er~(3+)/Yb~(3+) co-doped lithium-strontium-lead-bismuth glasses 总被引:2,自引:0,他引:2
Infrared-to-visible upconversion fluorescence of Er3+/Yb3+ co-doped lithium-strontium-lead-bismuth (LSPB) glasses for developing potential upconversion lasers has been studied under 975-nm excitation. Based on the results of energy transfer efficiency and upconversion spectra, the optimal Yb3+-Er3+ concentration ratio is found to be 5:1. Intense green and red emissions centered at 525, 546, and 657 nm, corresponding to the transitions 2H11/2→4 I15/2, 4S3/2→4 I15/2, and 4F9/2→4 I15/2, respectively, were observed. The quadratic dependence of the 525-, 546-, and 657-nm emissions on excitation power indicates that a two-photon absorption process occurs under 975-nm excitation. The high-populated 4I11/2 level is supposed to serve as the intermediate state responsible for the upconversion processes. The intense upconversion luminescence of Er3+ /Yb3+ co-doped LSPB glasses may be a potentially useful material for developing upconversion optical devices. 相似文献