用线性规划研究混合物的吸收光谱——以电子计算机计算混合物中各稀土元素的含量

一、引言近年已有许多作者论述了计算机在分析化学中的应用,但是探讨多组分混合物吸光度法的文章尚不多见。目前应用吸光度法,是将过量的有机试剂与欲测元素生成有色络合物,根据比尔定律构筑校正曲线来测定欲测元素。但是有机试剂与络合物的吸收曲线互相重叠且吸收峰间相距越小,则产生的误差就越大;另外,当     

COMPUTERIZED PATTERN RECOGNITION APPLIED TO CHEMICAL BOND RESEARCH——SOME EMPIRICAL RULES OF INTERMETALLIC COMPOUNDS

In the bond-parametric space (Z_1, Z_2, R_1/R_2, Σφ, Δφ), experimental data of erystaltype of 2005 intermetallic compounds and the experimental thermodynamic functions ofliquid alloys are processed. Some empirical rules are obtained, and the physical meaning ofthese rules is discussed.     

中、小雷诺数下围绕渗透出可燃气体的圆柱强迫对流时火焰结构的数值分析

一、前言 气流中的扩散火焰结构的数学分析在理论和实践上都具有一定意义.前人曾提出“折算薄膜”,“边界层燃烧”,“厚交换层”等数学模型来分析中、小雷诺数下强迫对流中单燃料滴的燃烧,并与实验结果进行了对比.本文对围绕渗透出可燃气体的圆柱在强迫对流的空气气流中求解流场,并与扩散方程和能量方程联立,用松弛迭代求解浓度场和温度     

放电等离子烧结制备纳米Ni块体材料

 采用自悬浮定向流法制备纳米Ni粉体,利用放电等离子烧结技术制备出了直径10 mm、厚2 mm,致密度为96.8 %,显微硬度为4.17 GPa的纳米块体材料。用X射线衍射仪、扫描电子显微镜和显微硬度计分析了烧结块体样品的相组成、晶粒尺寸、微观形貌和显微硬度。研究表明：随烧结温度的升高,块体样品的致密度和晶粒尺寸增大,当烧结温度为650 ℃时,致密度最高,晶粒尺寸为44.8 nm;显微硬度随烧结温度的增高先增大后减小,当烧结温度为550 ℃时,显微硬度最大为4.33 GPa;较高烧结温度下,断口微观形貌的纳米级韧窝出现,显示了韧性断裂的特征。     

Preparation and Characterization of Polypyrrole Microbelt via Cotton Template

脱脂棉作为模板首次合成了聚吡咯微带. 聚吡咯微带的结构通过红外进行表征,微带的稳定性、形貌和电性能通过扫描电子显微镜、热重分析仪和四探针电导率仪进行检测. 提出了聚吡咯微带的形成机理,并且结合实验结果分析了吡咯的摩尔浓度对材料的电导率的影响.     

正交设计优选维药恰玛古总黄酮的提取工艺

确定恰玛古总黄酮的最佳提取工艺.以乙醇为溶剂,采用索氏提取,紫外-可见分光光度法测定恰玛古中总黄酮的含量,通过稳定性、精密度和回收率实验检验了该方法的可靠性和重现性.对照品溶液和供试品液均在510nm处有最大吸收.回归方程为A=0.02054C+0.07628,r=0.9998(0-24μg·mL-1);优选的提取工艺为30倍原料重、75％乙醇、提取时间120min.平均总黄酮的含量为2.805％,平均回收率为100.88％,精密度和加样回收率的RSD分别为0.46％和2.26％.本实验操作简便,灵敏度高,结果准确,可用于恰玛古总黄酮的含量测定.     

Design and fabrication of computer-generated holograms for testing optical freeform surfaces

Freeform optical surfaces (FOSs) will be the best elements in the design of compact optical systems in the future. However, it is extremely difficult to measure freeform surface with sufficient accuracy, which impedes the development of the freeform surface. The design and fabrication of computer-generated hologram (CGH) , which has been successfully applied to the tests for aspheric surfaces, cannot be directly adopted to test FOSs due to their non-rotational asymmetry. A novel ray tracing planning method combined with successively optimizing even and odd power coefficients of phase polynomials in turn is proposed, which can successfully design a non-rotational asymmetry CGH for the tests of FOSs with an F-θ lens. A new eight-step fabrication process is also presented aiming to solve the problem that the linewidth on the same circle of the CGH for testing freeform surface is not uniform. This problem cannot be solved in the original procedure of CGH fabrication. The test results of the step profiler show that the CGH fabricated in the new procedure meets the requirements.     

非线性恢复力耦合的振动系统广义同步与参数识别

对于一类非线性恢复力无法精确解析表达的简谐激励振动系统,建立了由原系统非线性恢复力激振的派生系统.证明了派生系统与原系统可以达到广义同步.派生系统可以自动与激励力频率、大小变化的原非线性振动系统保持广义同步.证明了由派生系统的广义同步,可以识别出原系统的阻尼系数、激振力幅值与频率.由Duffing系统的仿真计算结果可以看出,这种方法是有效的,而且识别精度较高. 关键词： 非线性恢复力 广义同步 混沌