Hydrothermal Syntheses,Crystal Structures and Luminescence Properties of Cu(Ⅱ) and Cd(Ⅱ) Complexes Assembled by 6-Hydroxypicolinic Acid and 1,10-Phenanthroline

Two new complexes based on 6-hydroxypicolinic acid(H_2picO) and 1,10-phenanthroline(phen), such as [Cu_4(picO)_4(phen)_4]·12 H_2O(1) and {[Cd_4(picO)_4(phen)_4(H_2O)_2]·5H_2O}_n(2), have been synthesized and characterized by IR, elemental analyses, thermogravimetric analyses and X-ray diffraction technique. Single-crystal X-ray diffraction analyses revealed that the two complexes both crystallize in the triclinic system, space group P(16)-. For complex 1, the picO ligands adopt a tridentate coordination mode to link copper(Ⅱ) ions into dimmers. PicO ligands also adopt a tridentate mode in complex 2, which connects the cadmium(Ⅱ) to form a one-dimensional chain. Moreover, luminescent properties of 1 and 2 were also investigated.     

磷酸铵与多聚磷酸铵插层可膨胀石墨的制备

Expandable graphite intercalated by ammonium phosphate (AP) or ammonium polyphosphate (APP) was prepared by direct intercalation and two-step method, respectively. The products from two-step method show higher expansion volume, more weight increase and more weight loss after expansion, suggesting that the two-step method is a favorable method for preparation of APP intercalated EG. XRD provides convincing evidence for successful formation of APP-EG by showing strong diffraction peak at much lower 2θ angle. Scanning electron microscopy (SEM) with energy dispersive X-ray Spectroscopy (EDS) gives more evidence for intercalation of APP in the graphite layers.     

单光子探测器量子效率的自绝对标定

单光子探测器日益广泛地应用于科学研究的各个领域，精确地标定其量子效率成为应用的先决条件。我们首次实现了单光子探测器量子效率自绝对标定的原理性实验，即只利用待测探测器本身就可以对其量子效率进行绝对标定，而不需要第二个探测器或任何参考标准。该方法基于自发参量下转换产生的纠缠光子对的时间关联性，在信号光子和闲散光子之间引入延时，由单光子计数率和符合计数率测得探测器的量子效率。     

Equation of state for solids considering cohesive energy and anharmonic effect and its application to MgO

A simple equation of state(EOS) in wide ranges of pressure and temperature is constructed within the MieGrneisen-Debye framework.Instead of the popular Birch-Murnaghan and Vinet EOS,we employ a five-parameter cold energy expression to represent the static EOS term,which can correctly produce cohesive energy without any spurious oscillations in the extreme compression and expansion regions.We developed a Pad’e approximation-based analytic Debye quasiharmonic model with high accuracy which improves the performance of EOS in the low temperature region.The anharmonic effect is taken into account by using a semi-empirical approach.Its reasonability is verified by the fact that the total thermal pressure tends to the lowest-order anharmonic expansion in the literature at low temperature,and tends to ideal-gas limitation at high temperature,which is physically correct.Besides,based on this approach,the anharmonic thermal pressure can be expressed in the Gru¨neisen form,which is convenient for applications.The proposed EOS is used to study the thermodynamic properties of MgO including static and shock compression conditions,and the results are very satisfactory as compared with the experimental data.     

La-O小团簇上超氧物种与过氧物种间的连接途径

采用密度泛函理论方法考察了La-O团簇上超氧物种与过氧物种间转化的连接途径. 单重态下, 团簇上单个超氧物种可通过一系列臭氧物种转化为过氧物种, 且转化能垒较高;三重态下, 单个超氧物种则并无与过氧物种间连接的途径. 然而, La-O团簇上两超氧物种间的相互作用及其转化也具单重态和三重态两条途径. 三重态下, 超氧物种可很容易地转化为过氧物种(O₂^- + O₂^-↔O₂^2- + O₂), 超氧物种与过氧物种处于快速的交换状态之中;单重态下, 超氧物种转化为过氧物种则需较高的活化能垒, 表明在单重态下这些氧物种具有较高的稳定性.     

浅谈实验教学在高分子材料与工程专业本科教学中的地位北大核心CSCD

根据我校作为应用型本科院校的办学特色,联系我校高分子材料与工程专业的人才培养模式以及在实验教学中存在的问题,通过转变教育思想和观念、加强双师型教师的引进与培养,更新实验教学内容与方式,采用双向选择式市场机制等改革模式,搭建了校内全开放实验教学平台,校企合作式创新研究性平台与质量控制平台,手段上采用软件、硬件同步并进,彻底改变了传统的本科教学思维——实验教学附属于理论教学。通过实验参悟理论之精髓,真正地做到理论应用于现实生产及科学研究。以此为工科院校的实验教学改革提供借鉴。     

A Random Number Generator Based on Quantum Entangled Photon Pairs

A new scheme for a random number generator based on quantum entangled photon pairs is demonstrated.Signal photons produced by optical parametric down-conversion are detected at two single-photon detectors after transmission or reflection at a 50/50% beamsplitter, to form a truly random binary sequence. Their arrival is signalled by their twin idler photons, so that a cw laser source may be used instead of attenuated laser pulses.Coincidence measurement is employed to obtain the bit sequences, which are shown to fully satisfy the standard tests for randomness.     

Reed-Muller型通用逻辑组件的逻辑综合

本文提出了使用Reed-Muller型通用逻辑组件综合函数的方法.文中引用了表示Reed-Muller展开系数b^j的图形方法(简称b_j系数图),这种图形方法具有适合基于积之异或关系的逻辑网络的综合特点,此外,还指出了在积之和型数据选择器实现及积之异或实现之间的相似之处。     

在BEPCⅡ/BESⅢ上寻找η′c和1P1的Monte Carlo研究

使用SimBes(探测器模拟软件)和UGNT(物理事例产生器)模拟了在即将建造的BEPCⅡ/BESⅢ上寻找η′c和1P1的过程. 初步结论是如果收集到3×109ψ(2S)事例,就有能力寻找这两个粒子,而且,寻找η′c比寻找1P1需要更少的ψ(2S)事例.     

近代Raman光谱技术

介绍几种近代拉曼（Raman）光谱技术及其在科学中的应用。