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51.
Calculating the dielectric anisotropy of nematic liquid crystals: a reinvestigation of the Maier——Meier
theory
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This paper investigates the average dielectric permittivity
(\overline ε ) in the Maier--Meier theory for calculating
the dielectric anisotropy (Δε) of nematic liquid
crystals. For the reason that \overline ε of nematics
has the same expression as the dielectric permittivity of the isotropic
state, the Onsager equation for isotropic dielectric was used to
calculate it. The computed \overline ε shows reasonable
agreement with the results of the numerical methods used in the
literature. Molecular parameters, such as the polarizability and its
anisotropy, the dipole moment and its angle with the molecular long
axis, were taken from semi-empirical quantum chemistry (MOCPAC/AM1)
modeling. The calculated values of Δε according
to the Maier--Meier equation are in good agreement with the experimental
results for the investigated compounds having different core
structures and polar substituents. 相似文献
52.
采用溶胶-凝胶法制备了不同Pr掺杂量的Pr6O11-TiO2载体, 并以浸渍法制备了V2O5-MoO3/Pr6O11-TiO2催化剂. 活性评价结果表明, 该催化剂在220~400 ℃范围内具有良好的脱硝效率和N2选择性以及较强的抗SO2和H2O性能. 表征结果表明, 掺杂Pr可以提高V2O5-MoO3/TiO2催化剂的比表面积、 表面化学吸附氧物种浓度、 桥式硝酸盐物种和Brönsted酸位数量, 从而提高了催化剂上NOx的选择性催化还原(NH3-SCR)活性. 相似文献
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54.
基于X-pinch软X射线辐射点源对直径10μm钨丝单丝以及8μm钨丝双丝电爆发展过程进行了背光成像研究,实验平台为清华大学电机系研制的脉冲功率装置PPG-1(500kV/400kA/100ns)。成像光路安排为:作为X射线源的X-pinch和作为目标物的钨丝分别安装在装置的输出主电极阴阳极之间和回流导电杆处,成像胶片采用高分辨率、高灵敏度的X光胶片。利用自行设计的电流传感器和罗氏线圈对目标物实际流过的电流进行监测,从而计算得8μm钨丝丝爆过程中电导随时间变化的曲线。为了观测电爆金属丝质量密度分布的演变过程,设计了μm级厚度的阶梯光楔。通过大量成像实验,获取了丝芯膨胀、晕层等离子体形成及其向外扩张等过程的相关物理图像以及基于原始胶片绘制的质量密度分布图。 相似文献
55.
通过飞秒激光加工组装了CdTe量子点微纳结构,该微纳结构保留了量子点的特性.利用量子点表面的原子失配对金属离子进行还原,实现了多种金属如银、铜、锌、铂、铬和铁等微纳结构的制备.该微纳结构保留了金属的性质.其中,铜微钠结构的电导率约为2.7×105S/m. 相似文献
56.
We consider the Korteweg-de Vries (KdV) equation in the form ut+uux+uxxx=0(1) which is a nonlinear hyperbolic equation and has smooth solutions for all the time. There are a vast of results can be found in the literature for this equation, both theoretical and numerical. However, several good reasons account for needs of another numerical study of this equation are listed in[1]. Among them, the most convincing one might be that the wave equations have the multi-symplectic structure (cf. [2]), and the KdV equation is therefore a 相似文献
57.
Two 50-μm Mo wires in parallel used as a Z-pinch load are electrically exploded with a pulsed current rising to 275 kA in 125 ns and their explosion processes are backlighted using an X-pinch as an x-ray source.The backlighting images show clearly the processes similar to those occurring in the initial stages of a cylindrical wire-array Z-pinch,including the electric explosion of single wires characterised by the dense wire cores surrounded by a low-density coronal plasma,the expansion of the exploding wire,the sausage instability (m=0) in the coronal plasma around each wire,the motion of the coronal plasma as well as the wire core toward the current centroid,the formation of the precursor plasma column with a twist structure something like that of higher mode instability,especially the kink instability (m=1). 相似文献
58.
适量钠元素对铜铟镓硒薄膜生长具有促进作用,本文主要研究了掺钠钼电极特性及其对铜铟镓硒薄膜太阳能电池性能的影响。利用磁控溅射方法制备不同厚度的钼钠/钼(MoNa/Mo)薄膜作为背电极,并在(MoNa/Mo)薄膜电极上蒸镀铜铟镓硒(CIGS)薄膜,并利用单质硒源硒化处理后制备CIGS薄膜电池。SEM和XRD结果表明采用三层叠层Mo/Mo/MoNa薄膜做电极的MoNa容易被氧化,电阻率增加,采用四层叠层Mo/Mo/MoNa/Mo薄膜电极方式有效降低电阻率,阻止MoNa被氧化,CIGS晶粒较大且致密。在同一条件下,在不同MoNa/Mo厚度电极上制备CIGS薄膜电池,80nmMoNa厚度上的CIGS薄膜电池效率达6.54%。 相似文献
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