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A new method for the study of ternary surface complexes at liquid-solid interface,the E(%)-pH curve method,was proposed.Four types of E(%)-pH curves,namely,phenomenon of left-right shifts of S-shaped curve,V-shaped curve,monodirection shift curve and X-shaped curve,were discovered.Correspondingly,apart fromtype (Ⅰ) ternary surface complex -S-O-M-L and type (Ⅱ) ternary surface complex -S-L-M,a newtype of ternary surface complex -S-O-L-M was discovered. 相似文献
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It is the first time in experiment that we have found that the ionic strength effects on E(%)-pH curves of the systems with clay minerals as solid particles and those systems with hydrous oxides as solid particles, are "right-left shift phenomenon" and "left monodirectional shift phenomenon", respectively.The corresponding ionic strength effects on isotherms are "downward-upward shift phenomenon" and "upward monodirectional shift phenomenon", respectively.All the four phenomena are consistent with each other.In order to explain the above phenomena, the composite model of interracial ion/coordination particle exchange-electrostatic exchange is put forward to make a unified explanation and quantitative treatment.From the structures of the two kinds of materials——clay minerals and hydrous oxides, we know that the former has two kinds of exchange actions, i.e. when one increases,the other decreases, which makes the position of curves shift didirectionally,while the latter only has interfacial stepwise ion 相似文献
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